钠离子电池标准制定的必要性

doi:10.19799/j.cnki.2095-4239.2020.0085

储能科学与技术 ›› 2020, Vol. 9 ›› Issue (5): 1225-1233.doi: 10.19799/j.cnki.2095-4239.2020.0085

钠离子电池标准制定的必要性

周权^1,²(), 戚兴国², 陆雅翔¹, 容晓晖¹, 汤菲², 孔维和², 唐堃², 陈立泉¹, 胡勇胜^1,²()

^1.中国科学院物理研究所，北京 100190
^2.中科海钠科技有限责任公司，北京 100194

收稿日期:2020-03-01 修回日期:2020-04-02 出版日期:2020-09-05 发布日期:2020-09-08
通讯作者: 胡勇胜 E-mail:zhouquan@hinabattery.com;yshu@iphy.ac.cn
作者简介:周权（1987—），男，博士研究生，研究方向为钠离子电池及其失效分析，E-mail：zhouquan@hinabattery.com；
基金资助:
国家自然科学基金项目(51725206);中国科学院战略性先导科技专项(XDA21070500);北京自然科学基金-海淀原创创新联合基金(L182056)

The necessity of establishing Na-ion battery standards

Quan ZHOU^1,²(), Xingguo QI², Yaxiang LU¹, Xiaohui RONG¹, Fei TANG², Weihe KONG², Kun TANG², Liquan CHEN¹, Yongsheng HU^1,²()

^1.Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
^2.HiNa Battery Technology Co. Ltd. , Beijing 100194, China

Received:2020-03-01 Revised:2020-04-02 Online:2020-09-05 Published:2020-09-08
Contact: Yongsheng HU E-mail:zhouquan@hinabattery.com;yshu@iphy.ac.cn

摘要/Abstract

摘要：

钠离子电池具有资源丰富、成本低廉、能量转换效率高、循环寿命长、维护费用低、安全性好等诸多独特的优势，能够满足新能源电池领域高性价比和高安全性等应用的要求。然而钠离子电池作为一种全新的化学电源体系，在当前产业化和推向市场之际，国内外无任何可供使用的产品标准或规范，这将会严重制约钠离子电池技术和产业的发展，迫切需要制定相关的国家和行业标准，实现钠离子电池产品的检验规范化和质量标准化，规范市场秩序和推动技术进步。本文首先介绍了全球范围内锂资源和钠资源的形势；其次，对钠离子电池所具有的特性和优势、国内外的技术及产业化发展现状、存在的问题和未来的发展趋势进行了详细说明，并分析了目前全球范围内钠离子电池标准的现状及可供其参考的其他电池体系已有的标准或规范，指出了钠离子电池标准制定的必要性。最后概括了锂离子电池标准化工作的发展历程及借鉴意义，提出了在制定钠离子电池的标准时可结合其产品特点并借鉴锂离子电池标准化建设工作的具体建议。

关键词: 钠离子电池, 标准, 产业化

Abstract:

Na-ion batteries can meet the application requirements of being cost effective and having high safety in the field of energy storage due to the abundance of resources and their low cost, high energy conversion efficiency, long cycle life, low maintenance cost, and high level of safety. However, as a new chemical power system, Na-ion batteries have no related standard or specifications for their industrialization and marketing, which will seriously restrict the development of Na-ion battery technology. It is important to establish relevant national or industrial standards to standardize the inspection and quality of Na-ion batteries，regulate the market, and promote technological progress. In this article, we first introduce the situation concerning the global lithium and sodium resources. Then, we specify the characteristics and advantages, industrialization status, problems, and future development trends of Na-ion batteries， analyzing the current status of Na-ion battery standards worldwide and the reference standards or specifications of other batteries to point out the necessity of this exercise. Finally, we summarize the development history and reference significance of the standardization work done on lithium-ion batteries and suggest that the standard for Na-ion battery can be based on that of lithium-ion batteries, taking the characteristics of Na-ion batteries into account.

Key words: Na-ion batteries, standards, industrialization

中图分类号:

TM 911

周权, 戚兴国, 陆雅翔, 容晓晖, 汤菲, 孔维和, 唐堃, 陈立泉, 胡勇胜. 钠离子电池标准制定的必要性[J]. 储能科学与技术, 2020, 9(5): 1225-1233.

Quan ZHOU, Xingguo QI, Yaxiang LU, Xiaohui RONG, Fei TANG, Weihe KONG, Kun TANG, Liquan CHEN, Yongsheng HU. The necessity of establishing Na-ion battery standards[J]. Energy Storage Science and Technology, 2020, 9(5): 1225-1233.

图/表 4

参考文献 22

1	LI Y M, LU Y X, ZHAO C L, et al. Recent advances of electrode materials for low-cost sodium-ion batteries towards practical application for grid energy storage[J]. Energy Storage Materials, 2017, 7: 130-151.
2	PAN H L, HU Y S, CHEN L Q. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage[J]. Energy & Environmental Science, 2013, 6(8): 2338-2360.
3	Geological Survey U.S. Mineral commodity summaries[R]. 2019: 98-99.
4	LI Y Q, LU Y X, PHILIPP A, et al. Intercalation chemistry of graphite: Alkali metal ons and beyond[J]. Chem. Soc. Rev., 2019, 48: 4655-4687.
5	NAYAK P K, YANG L, BREHM W, et al. From lithium-ion to sodium-ion batteries: Advantages, challenges, and surprises[J]. Angew. Chem. Int. Edit., 2018, 57(1): 102-120.
6	YANG S, GUO S H, ZHOU H S. Adverse effects of interlayer-gliding in layered transition-metal oxides on electrochemical sodium-ion storage[J]. Energy & Environmental Science, 2019, 12(3): 825-840.
7	WANG Y S, YU X Q, XU S Y, et al. A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries[J]. Nat. Mater., 2013, 4: doi: 10.1038/ncomms3365.
8	WANG Y S, RONG X H, HU Y S, et al. P2-Na_0.6[Cr_0.6Ti_0.4]O₂ cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries[J]. Nat. Mater., 2015, 6: doi: 10.1038/ncomms6954.
9	LI Y Q, YANG Y, LU Y X, et al. Ultralow-concentration electrolyte for Na-ion batteries[J]. ACS Energy Letters, 2020, 5: 1156-1158.
10	ZHAO C L, LU Y X, CHEN L Q, et al. Flexible Na batteries[J]. InfoMat., 2019, 2(1): 126-138.
11	XU S Y, WU X Y, LI Y M, et al. Novel copper redox-based cathode materials for room-temperature sodium-ion batteries[J]. Chinese Physics B, 2014, 23(11)： doi: 10.1088/1674-1056/23/11/118202.
12	MU L Q, XU S Y, LI Y M, et al. Prototype sodium-ion batteries using an air-stable and Co/Ni-free O3-layered metal oxide cathode[J]. Advanced Materials, 2015, 27(43): 6928-6933.
13	王红, 廖小珍, 颉莹莹, 等. 新型移动式钠离子电池储能系统设计与研究[J]. 储能科学与技术, 2016, 5(1): 65-68.
	WANG H, LIAO X Z, XIE Y Y, et al. Design and investigation on portable energy storage device based on sodium-ion batteries[J]. Energy Storage Science and Technology, 2016, 5(1): 65-68.
14	QI Y R, ZHAO J M, YANG C, et al. Comprehensive studies on the hydrothermal strategy for the synthesis of Na₃(VO_1-_xPO₄)₂F₁₊₂_x(0≤x≤1) and their Na-storage performance[J]. Small Methods, 2018, doi: 10.1002/smtd.201800111. doi: 10.1002/smtd.201800111
15	LU Y H, WANG L, CHENG J G, et al. Prussian blue: A new framework of electrode materials for sodium batteries[J]. Chemical Communications, 2012, 48(52): 6544-6546.
16	FU L J, TANG K, SONG K P, et al. Nitrogen doped porous carbon fibres as anode materials for sodium ion batteries with excellent rate performance[J]. Nanoscale, 2014, 6(3): 1384-1389.
17	LI Y M, HU Y S, LI H, et al. A superior low-cost amorphous carbon anode made from pitch and lignin for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2016, 4(1): 96-104.
18	MENG Q S, LU Y Q, DING F X, et al. Tuning the closed pore structure of hard carbons with the highest Na storage capacity[J]. ACS Energy Letters, 2019, 4(11): 2608-2612.
19	LI Y M, HU Y S, QI X G, et al. Advanced sodium-ion batteries using superior low cost pyrolyzed anthracite anode: Towards practical applications[J]. Energy Storage Materials, 2016, 5: 191-197.
20	LU Y X, RONG X H, HU Y S, et al. Research and development of advanced battery materials in China[J]. Energy Storage Materials, 2019, 23: 144-153.
21	HU Y S, LU Y X. 2019 Nobel prize for the Li-ion batteries and new opportunities and challenges in Na-ion batteries[J]. ACS Energy Letters, 2019, 4: 2689-2690.
22	方铮, 曹余良, 胡勇胜, 等. 室温钠离子电池技术经济性分析[J]. 储能科学与技术, 2016, 5(2): 149-158.
	FANG Z, CAO Y L, HU Y S, et al. Economic analysis for room-temperature sodium-ion battery technologies[J]. Energy Storage Science and Technology, 2016, 5(2): 149-158.

[1]	徐雄文, 聂阳, 涂健, 许峥, 谢健, 赵新兵. 普鲁士蓝正极软包钠离子电池的滥用性能[J]. 储能科学与技术, 2022, 11(7): 2030-2039.
[2]	张平, 康利斌, 王明菊, 赵广, 罗振华, 唐堃, 陆雅翔, 胡勇胜. 钠离子电池储能技术及经济性分析[J]. 储能科学与技术, 2022, 11(6): 1892-1901.
[3]	张浩然, 车海英, 郭凯强, 申展, 张云龙, 陈航达, 周煌, 廖建平, 刘海梅, 马紫峰. Sn掺杂NaNi_1/3Fe_1/3Mn_1/3-_x Sn _x O₂ 正极材料制备及其电化学性能[J]. 储能科学与技术, 2022, 11(6): 1874-1882.
[4]	赵易飞, 杨振东, 李凤, 谢召军, 周震. 氮掺杂碳包覆Na₃V₂ （PO₄ ） ₂F₃ 钠离子电池正极材料的制备与性能[J]. 储能科学与技术, 2022, 11(6): 1883-1891.
[5]	胡振恺, 雷博, 李勇琦, 史尤杰, 雷旗开, 何智鹏. 储能用锂离子电池安全性测试与评估方法比较[J]. 储能科学与技术, 2022, 11(5): 1650-1656.
[6]	刘倩楠, 胡伟平, 轷喆. 钠离子电池磷基负极材料研究进展[J]. 储能科学与技术, 2022, 11(4): 1201-1210.
[7]	胡海燕, 侴术雷, 肖遥. 基于分子轨道杂化的高电压钠离子电池层状氧化物正极材料[J]. 储能科学与技术, 2022, 11(4): 1093-1102.
[8]	孙畅, 邓泽荣, 江宁波, 张露露, FANG Hui, 杨学林. 钠离子电池正极材料氟磷酸钒钠研究进展[J]. 储能科学与技术, 2022, 11(4): 1184-1200.
[9]	赵志强, 刘恒均, 徐熙祥, 潘圆圆, 李庆浩, 李洪森, 胡涵, 李强. 储能科学中的磁性表征技术[J]. 储能科学与技术, 2022, 11(3): 818-833.
[10]	胡建, 林春景, 郝维健, 郑天雷. 动力电池标准体系建设现状及建议[J]. 储能科学与技术, 2022, 11(1): 313-320.
[11]	冯一峰, 沈佳妮, 车海英, 马紫峰, 贺益君, 谈文, 杨庆亨. 钠离子电池健康状态预测[J]. 储能科学与技术, 2021, 10(4): 1407-1415.
[12]	刘当玲, 王诗敏, 高智慧, 徐露富, 夏书标, 郭洪. 三维NZSPO/PAN-［PEO-NaTFST］复合钠离子电池固体电解质[J]. 储能科学与技术, 2021, 10(3): 931-937.
[13]	周琳, 杨佯, 胡勇胜. 合金电极失效机制：体积膨胀？电解液分解？[J]. 储能科学与技术, 2021, 10(3): 813-820.
[14]	张鹏, 赖兴强, 沈俊荣, 张东海, 阎永恒, 张锐, 盛军, 代康伟. 固态锂电池研究及产业化进展[J]. 储能科学与技术, 2021, 10(3): 896-904.
[15]	聂雪娇, 郭晋芝, 王美怡, 谷振一, 赵欣欣, 杨旭, 梁皓杰, 吴兴隆. 以废旧锰酸锂正极为原料制备Li_0.25Na_0.6MnO₂钠离子电池正极材料的研究[J]. 储能科学与技术, 2020, 9(5): 1402-1409.

钠离子电池标准制定的必要性

The necessity of establishing Na-ion battery standards

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 4

参考文献 22

相关文章 15

编辑推荐

Metrics

本文评价