高能量密度锂电池开发策略 |
李文俊, 徐航宇, 杨琪, 李久铭, 张振宇, 王胜彬, 彭佳悦, 张斌, 陈相雷, 张臻, 杨萌, 赵言, 耿瑶瑶, 黄文师, 丁泽鹏, 张雷, 田启友, 俞会根, 李泓 |
Development of strategies for high-energy-density lithium batteries |
Wenjun LI, Hangyu XU, Qi YANG, Jiuming LI, Zhenyu ZHANG, Shengbin WANG, Jiayue PENG, Bin ZHANG, Xianglei CHEN, Zhen ZHANG, Meng YANG, Yan ZHAO, Yaoyao GENG, Wenshi HUANG, Zepeng DING, Lei ZHANG, Qiyou TIAN, Huigen YU, Hong LI |
图27 常规PP隔膜(a)和含CGF层的Janus隔膜(b)示意图。没有CGF层的隔膜,飞梭回来的LiPSs堆积在隔膜/正极界面并形成一个固态、没有活性、绝缘的钝化层。有CGF层的隔膜,LiPSs被还原并沉积在导电骨架上,阻止绝缘膜的形成并且可以使LiPSs进一步穿透到正极里[ |
Fig.27 Schematic illustration of (a) a routine PP separator and (b) a Janus separator with a CGF layer. Without a CGF layer, the LiPSs that shuttled back accumulated at the separator/cathode interface to form a solid, nonactive, insulating passivation layer. With a CGF layer, the LiPSs were reduced and deposited on the conductive scaffolds, preventing the formation of the insulating film and enabling the further penetration of LiPSs into the cathode [ |
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