钠离子无机固体电解质研究进展
孙歌, 魏芷宣, 张馨元, 陈楠, 陈岗, 杜菲

Recent progress of sodium-based inorganic solid electrolytes
Ge SUN, Zhixuan WEI, Xinyuan ZHANG, Nan CHEN, Gang CHEN, Fei DU
表1 NASICON型固态电解质的离子电导率和活化能
Table 1 Conductivity and activation energy of NASICON-type electrolytes
化学式离子电导率/S·cm-1温度/oC活化能/eV参考文献

Na3Zr2PSi2O12

Na3.08Zr1.96Mg0.04Si2PO12

Na2.96Zr1.96Nb0.04Si2PO12

Na2.96Zr1.96V0.04Si2PO12

Na2.96Zr1.96Ta0.04Si2PO12

Na3.1Zr1.55Si2.3P0.7O11

Na3.2Hf2Si2.2P0.8O12

Na2.5Hf1.8Ti0.2Si1.5P1.5O12

Na3Zr1.7Nb0.24Si2PO12

Na1.9Ti1.1Al0.9(PO4)3

Na3Zr1.9Yb0.1Si2PO12

Na3Zr1.9Gd0.1Si2PO12

Na3Zr1.9Ce0.1Si2PO12

Na3.4Sc0.4Zr1.6Si2PO12

Na3.1Zr1.95Mg0.05Si2PO12

Na3.3Zr1.7La0.3Si2PO12

Na3.1Zr1.9La0.1Si2PO12

Na3.1Zr1.9Nd0.1Si2PO12

Na3.1Zr1.9Y0.1Si2PO12

Na3.2Zr1.9Ca0.1Si2PO12

Na3.2Zr2Si2.2P0.8O12-0.5NaF

Na3Zr2Si2PO12+4.8%Na3BO3

Na3Zr2Si2PO12+5%Na2O-Nb2O5-P2O5

Na3.256Mg0.128Zr1.872Si2PO12+1.1%Bi2O3

Na3Zr2Si2PO12+5%Na2SiO3

Na3Zr2Si2PO12+5%ATO(antimony tin oxide)

0.2

3.7×10-4

4.95×10-3

1.2×10-3

9.4×10-4

3.0×10-3

2.3×10-3

3.36×10-4

2.258×10-4

1.3×10-7

1.7×10-4

6.0×10-4

9.0×10-4

4.0×10-3

3.5×10-3

3.4×10-3

1.1×10-3

6.89×10-4

6.28×10-4

1.67×10-3

3.6×10-3

1.4×10-3

1.0×10-3

1.522×10-3

1.28×10-3

1.43×10-3

300

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25

RT

25

25

25

25

25

25

RT

25

RT

RT

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25

25

RT

25

25

RT

RT

0.29

0.36

0.21

0.21

0.17

0.26

0.36

0.245

0.31

0.51

0.37

0.30

0.29

0.26

0.25

0.291

—

—

—

0.29

0.25

0.29

0.32

—

0.241(Grain)

—

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