NASICON结构钠离子固体电解质及固态钠电池应用研究进展

杨菁, 刘高瞻, 沈麟, 姚霞银

Research progress on NASICON-structured sodium solid electrolytes and their derived solid state sodium batteries

Jing YANG, Gaozhan LIU, Lin SHEN, Xiayin YAO

表1 NASICON结构固体电解质中取代离子种类

Table 1 Types of substituted ions used in NASICON-structured solid electrolyte

被取代骨架离子 取代离子 Zr4+ Ca2+[33]，Co2+[39]，Cu2+[42]，Mg2+[34,38]，Ni2+[34,39]，Zn2+[39,43]，Al3+[44]，B3+[45]，Cr3+[46]，Dy3+[27]，Er3+[27]，Fe3+[39]，Ga3+[46]，Gd3+[47]，La3+[40]，Nd3+[40]，Sc3+[35,37]，In3+[46]，Y3+[48,49]，Yb3+[47]，Ce4+[47]，Ge4+[50]，Hf4+[41,51]，Mo4+[52]，Sn4+[53]，Nb5+[43]，Ta5+[54]，Ti4+[43]，V5+[54]等 P5+ Si4+[44,55]，As5+[56]等