电极材料储锂行为及其机制的原位透射电镜研究进展 |
柯承志, 肖本胜, 李苗, 陆敬予, 何洋, 张力, 张桥保 |
Research progress in understanding of lithium storage behavior and reaction mechanism of electrode materials through in situ transmission electron microscopy |
Chengzhi KE, Bensheng XIAO, Miao LI, Jingyu LU, Yang HE, Li ZHANG, Qiaobao ZHANG |
图7 (a)~(e) 620 nm Si纳米颗粒在嵌锂过程逐渐膨胀破裂的TEM图;(f) 嵌锂后的电子衍射图,对应的产物为Li15Si4;(g)~(j) 80 nm Si纳米颗粒在嵌锂过程中的结构变化图,锂化后没有破裂;(k) Si纳米颗粒嵌锂破裂的临界尺寸统计数据图[ |
Fig. 7 (a)~(e) TEM images showing fast fracture of 620 nm Si nanoparticle during lithiation process. (f) Electron diffraction pattern of broken Si nanoparticle after lithiation, indicating formation of Li15Si4. (g)~(j) TEM images of a 80 nm Si nanoparticle without cracking during lithiation. (k) Statistics showing critical size of Si nanoparticles without cracking during lithiation process[ |
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