电极材料储锂行为及其机制的原位透射电镜研究进展
柯承志, 肖本胜, 李苗, 陆敬予, 何洋, 张力, 张桥保

Research progress in understanding of lithium storage behavior and reaction mechanism of electrode materials through in situ transmission electron microscopy
Chengzhi KE, Bensheng XIAO, Miao LI, Jingyu LU, Yang HE, Li ZHANG, Qiaobao ZHANG
图7 (a)(e) 620 nm Si纳米颗粒在嵌锂过程逐渐膨胀破裂的TEM图;(f) 嵌锂后的电子衍射图,对应的产物为Li15Si4(g)(j) 80 nm Si纳米颗粒在嵌锂过程中的结构变化图,锂化后没有破裂;(k) Si纳米颗粒嵌锂破裂的临界尺寸统计数据图[58]
Fig. 7 (a)(e) TEM images showing fast fracture of 620 nm Si nanoparticle during lithiation process. (f) Electron diffraction pattern of broken Si nanoparticle after lithiation, indicating formation of Li15Si4. (g)(j) TEM images of a 80 nm Si nanoparticle without cracking during lithiation. (k) Statistics showing critical size of Si nanoparticles without cracking during lithiation process[58]