共价有机框架材料（COFs）在氧电极电催化中的研究进展

邹文午, 蒋国星, 杜丽

Recent advances in covalent organic frameworks （COFs） for electrocatalysis of oxygen electrodes

Wenwu ZOU, Guoxing JIANG, Li DU

表2 近期报道的COF基OER电催化剂的比较

Table 2 Comparison of recently reported COF-based OER electrocatalysts

COF基电催化剂 电解液 η10 (vs. RHE)/mV 塔菲尔斜率/(mV/dec) 参考文献 PD-CTF/GC 0.1 mol/L KOH 610 (j=13 mA/cm) 87 [48] C4-SHz COF 1.0 mol/L KOH 320 39 [49] (CoP)n-MWCNTs 1.0 mol/L KOH 290(j=1 mA/cm) 60.8 [20] Co-TpBpy 0.1 mol/L PBS (pH 7.0) 400(j=1 mA/cm) 59 [50] IISERP-COF2/CoxNiy(OH)2 0.1 mol/L KOH 258 38.9 [51] macro-TpBpy-Co 0.1 mol/L KOH 380 54 [52] Ni3N-IISERP-COF3 1.0 mol/L KOH 230 79 [53] Co3O4/NPC 1.0 mol/L KOH 330 79 [54] Fe2P/Fe4N@N-doped carbon 0.5 mol/L H2SO4 232 130 [55] Co0.5V0.5@COF-SO3 1.0 mol/L KOH 318 62 [56] Ni0.5Fe0.5@COF-SO3 1.0 mol/L KOH 308 83 [57] COF-C4N 1.0 mol/L KOH 349 64 [58] CoP-2ph-CMP-800 1.0 mol/L KOH 370 86 [59]