锌铁液流电池研究现状及展望
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姚祯, 王锐, 阳雪, 张琦, 刘庆华, 王保国, 缪平
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Current situations and prospects of zinc-iron flow battery
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Zhen YAO, Rui WANG, Xue YANG, Qi ZHANG, Qinghua LIU, Baoguo WANG, Ping MIAO
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表1 碱性[18]、酸性[19]和中性[20]锌铁液流电池
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Table 1 Alkaline[18], acidic[19] and neutral[20] zinc iron flow battery
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| 项目 | 碱性锌铁液流电池 | 酸性锌铁液流电池 | 中性锌铁液流电池 |
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| 正极 | Fe(CN)64-?Fe(CN)63-+e- φ=+0.33 V vs. Hg/HgO | Fe2+?Fe3++e- φ=+0.77 V vs. SHE | Fe(Glycine)22+?Fe(Glycine)23++e- φ=+0.549 V vs. Ag/AgCl | | 负极 | Zn(OH)42-+2e-?Zn+4OH- φ=-1.41 V vs. Hg/HgO | Zn2-+2e-?Zn φ=-0.76 V vs. SHE | Zn2-+2e-?Zn φ=-0.883 V vs. Ag/AgCl | | 总电势 | Ecell=1.74 V | Ecell=1.53 V | Ecell=1.432 V |
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