锂电池电解液电导率模型研究进展
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周思飞, 李骏, 王小飞, 张道明, 薛浩亮
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Research progress in the conductivity model of lithium battery electrolytes
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Sifei ZHOU, Jun LI, Xiaofei WANG, Daoming ZHANG, Haoliang XUE
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表2 电解液电导率统计热力学模型
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Table 2 Statistical thermodynamic model of electrolyte conductivity
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| 方法 | 溶质 | 溶剂 | 温度/℃ | 盐浓度/(mol/kg) | 平均相对误差/% | 引用文献 |
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| AEM | 常用锂盐 | 碳酸酯、羧酸酯、醚类、砜类 | 0～40 | 0.5～3 | 10 | [1] | | LiPF6 | PC，PC+EC+DMC，PC+DEC+DMC EC+EMC，EC+DEC+DMC+EP | -40～80 | 0～3.5 | 5 | [43] | | LiBOB | PC+EA，EC+EMC | | LiTFSI | PC+DME | | LiFSI | FEC+GBL+EMC+MB | | LiPF6 | EC+EMC，EC+EMC+MA，EC+DMC+MA | 0～40 | 0.5～2 | 5 | [45] | | NaPF6 | PC+EC | -10～50 | 0.1～2 | 7 | [46] | | 分子动力学 | LiPF6 | PC，EC+EMC+MA，EC+DMC+MA EC+EMC，EC+DMC，FEC，EC+FEC，PC+FEC | 10～40 | 0.5～2 | 15 | [52] | | LiFSI | DMC，EMC，PC | 0～60 | 0.1～0.5 | | LiTFSI | MP，DMC，EC，GLN，MGLN，PC EC-DEC，DMC-MP，BC-DMC | 25～85 | 0.1～1(mol/L) | | LiPF6 | PC+DEC，PC | -10～80 | 1 | — | [54] | | 蒙特卡洛模拟 | LiClO4 | γBL | 25 | 0～0.8 | — | [56] | | NaClO4 | γBL |
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