动力学强化水合储氢技术研究进展

陈思远, 王燕鸿, 郎雪梅, 樊栓狮

Review of the kinetics enhancement technology of hydrogen storage in clathrate hydrates

Siyuan CHEN, Yanhong WANG, Xuemei LANG, Shuanshi FAN

表1 II型二元氢气水合物分解焓[41]

Table 1 Decompound enthalpy of sII binary hydrogen hydrate[41]

体系组成 相平衡温度/K 压缩因子z △Hdis/(kJ/mol) THF+H2+H2O 283.8 1.128 159.23 CP+H2+H2O 283.4 1.069 140.68 tert-Butylamine +H2+H2O 269.9 1.107 132.06 Acetone+H2+H2O 269.9 1.202 159.46 TBAB+H2+H2O 286.5 1.112 382.96 TBAF+H2+H2O 296.6 1.688 330.34 TBANO3+H2+H2O 284.9 1.192 340.23