飞行时间二次离子质谱在锂基二次电池中的应用
赵志伟, 杨智, 彭章泉

Application of time-of-flight secondary ion mass spectrometry in lithium-based rechargeable batteries
Zhiwei ZHAO, Zhi YANG, Zhangquan PENG
图8 (a) 锂负极表面LiO-LiS-H- 二次离子在第540以及300圈循环的深度分布,分别代表Li2OLi2S以及包含H的界面物种;(b) 锂负极表面LiH-LiOH-C2H3- 二次离子在第540以及300圈循环的深度分布,分别代表LiHLiOH以及各种有机界面物种;(c)(d)在第540以及300圈循环后Li2-LiH-LiS-SIMS扫描3D重建图像[45]
Fig. 8 (a) depth profiles of LiO-, LiS- and H- secondary ions that represents respectively Li2O, Li2S and various hydrogen-containing interphasial species, at 5, 40 and 300 cycles on lithium anode; (b) depth profiles of LiH-, LiOH- and C2H3- secondary ions that represents respectively LiH, LiOH and various organic interphasial species, at 5, 40, and 300 cycles on lithium anode; (c), (d) 3D reconstructions of the SIMS signal for LiH- and LiS- at 5, 40, and 300 cycles[45]