石墨负极界面SEI膜与锂离子电池热失控
张佳怡, 翁素婷, 王兆翔, 王雪锋

Solid electrolyte interphaseSEIon graphite anode correlated with thermal runaway of lithium-ion batteries
Jiayi ZHANG, Suting WENG, Zhaoxiang WANG, Xuefeng WANG
图5 HOPG(a)Mn2+ 电解液和(b)Mn2+ 电解液中循环后的AFM高度图像及其对应的平均横截面剖面图;(c) 电极在含Mn2+ 电解液中循环5周并存放1个月后得到的Mn元素分布截面图;(d) Mn2+ 沉积对石墨负极影响示意图[54]
2LiF+Mn2+MnF2+2Li+
(11)
Fig. 5 AFM height images and their corresponding averaged cross-section of HOPG cycled in (a) Mn-free electrolyte and (b) Mn-containing electrolyte; (c) Mn distribution along the cross-sectional electrode when it was stored for one month after 5 cycles in Mn-containing electrolyte; (d) Schematic diagram of the effect of Mn2+ deposition on graphite anode[54]