相变储能材料及其冷链运输应用

doi:10.19799/j.cnki.2095-4239.2020.0401

摘要/Abstract

摘要：

随着社会对冷链物流的需求日益增长，方便快捷的冷链运输得以迅速发展。作为冷链运输所需的核心技术，相变储冷技术因可以提高能源利用效率和提供冷链运输所需的稳定低温环境受到越来越多的关注，其实际应用的关键是相变储能材料。本文回顾了冷链物流行业的发展现状，介绍了应用于冷链运输的相变储能材料的分类及其优缺点，并总结了相变储能材料性能调控的方法与原理；同时，介绍了各类新型相变储冷剂在食品运输、疫苗运输等方面的应用；最后指出，制备高储冷容量、循环性能稳定的相变储冷材料并扩大其应用范围是今后的研究重点。

关键词: 相变储能材料, 储冷技术, 冷链运输

Abstract:

With the growing demand for cold chain logistics, convenient and fast cold chain transportation has been developed rapidly. As the core technology required for cold chain transportation, phase change cold storage technology is receiving more and more attention for it can improve energy utilization efficiency and provide a stable low-temperature environment required for cold chain transportation, and the key to its practical application is phase change energy storage material. This paper reviewed the development status of the cold chain logistics industry, introduced the classification of phase change energy storage materials used in cold chain transportation and their advantages and disadvantages, and summarized the methods and principles of phase change energy storage materials performance regulation; at the same time, it introduced the applications of various new phase change energy storage agents in food transportation and vaccine transportation; finally, it pointed out that the preparation of phase change energy storage materials with high cold storage capacity and stable cycling performance and the expansion of their applications are the focus of future research.

Key words: phase change energy storage materials, cold storage technology, cold-chain transportation

中图分类号:

TB 333

林酿志, 李传常. 相变储能材料及其冷链运输应用[J]. 储能科学与技术, 2021, 10(3): 1040-1050.

Niangzhi LIN, Chuanchang LI. Phase change materials for energy storage in cold-chain transportation[J]. Energy Storage Science and Technology, 2021, 10(3): 1040-1050.

图/表 5

参考文献 84

1	崔忠付. 2020年冷链物流回顾与2021年展望[J]. 物流技术与应用, 2020, 25(z2): 14-15.
	CUI Z F. Review of China's cold chain logistics in 2018 and trend outlook in 2019[J]. Logistics & Material Handling, 2020, 25(z2): 14-15.
2	王忍, 武卫东, 吴俊. 可用于冷链物流相变材料的研究进展[J]. 能源研究与信息, 2019, 35(1): 1-8.
	WANG R, WU W D, WU J. Research development on phase change materials for cold chain logistics[J]. Energy Research and Information, 2019, 35(1): 1-8.
3	章学来, 徐笑锋, 周孙希, 等. 蓄冷技术在冷链物流中的研究进展[J]. 制冷与空调, 2017, 17(12): 88-92.
	ZHANG X L, XU X F, ZHOU S X, et al. Research progress of cold storage technology in cold chain logistics[J]. Refrigeration and Air-Conditioning, 2017, 17(12): 88-92.
4	傅一波. 食品冷链运输中不同温度段的蓄冷剂研制[D]. 杭州: 浙江理工大学, 2017.
	FU Y B. Development of cold storage agents for different temperature bands in food cold chain transportation[D]. Hangzhou: Zhejiang Sci-Tech University, 2017.
5	王刚. 生鲜农产品冷链的蓄冷剂开发与应用[D]. 马鞍山: 安徽工业大学, 2017.
	WANG G. Development and application of refrigerant storage for fresh agricultural products cold chain[D]. Maanshan: Anhui Universit of Technology, 2017.
6	章学来, 陈裕丰, 曾涛, 等. 医药冷链物流用相变材料的研制[J]. 制冷与空调, 2017, 17(7): 43-46, 25.
	ZHANG X L, CHEN Y F, ZENG T, et al. Research and development of phase change materials for pharmaceutical cold chain logistics[J]. Refrigeration and Air-Conditioning, 2017, 17(7): 43-46, 25.
7	杨天润, 孙锲, WENNERSTEN 等. 相变蓄冷材料的研究进展[J]. 工程热物理学报, 2018, 39(3): 567-573.
	YANG T R, SUN Q, WENNERSTEN R, et al. Review of phase change materials for cold thermal energy storage[J]. Journal of Engineering Thermophysics, 2018, 39(3): 567-573.
8	FU X, LIU Z, XIAO Y, et al. Preparation and properties of lauric acid/diatomite composites as novel form-stable phase change materials for thermal energy storage[J]. Energy and Buildings, 2015, 104: 244-249.
9	李妍. 应用于冷链的有机相变蓄冷剂的制备及性能研究[D]. 西安: 西安理工大学, 2020.
	LI Y. Preparation and performance of organic phase change refrigerant for cold chain application[D]. Xi'an: Xi'an University of Technology, 2020.
10	徐笑锋, 章学来, 周孙希, 等. 蓄冷式多温区保温箱系统设计与实验研究[J]. 制冷学报, 2019, 40(3): 92-98.
	XU X F, ZHANG X L, ZHOU S X, et al. Design and experimental study on the storage type insulation box with multi-temperature[J]. Journal of Refrigeration, 2019, 40(3): 92-98.
11	朱冰清. 农产品冷链专用相变蓄冷剂研制与初步应用[D]. 杭州: 浙江大学, 2015.
	ZHU B Q. Development and preliminary application of phase change refrigerant for agricultural products cold chain[D]. Hangzhou: Zhejiang University, 2015.
12	苏党. 非冷冻低温区定形相变蓄冷剂的研究[D]. 杭州: 浙江大学, 2018.
	SU D. Study of shaped phase change accumulator in non-freezing low temperature zone[D]. Hangzhou: Zhejiang University, 2018.
13	徐笑锋, 章学来, 李玉洋, 等. 十水硫酸钠低温相变材料的制备及稳定性[J]. 化学工程, 2018, 46(10): 11-15, 25.
	XU X F, ZHANG X L, LI Y Y, et al. Preparation and stability properties of sodium sulphate PCMs for thermal energy storage[J]. Chemical Engineering, 2018, 46(10): 11-15, 25.
14	贾蒲悦, 武卫东, 王益聪. 新型0 ℃相变蓄冷材料制备及蓄冷特性[J]. 化工进展, 2019, 38(6): 2862-2869.
	JIA P Y, WU W D, WANG Y C. Preparation of 0 ℃phase change material and its cold storage performance in cold-chain logistics[J]. Chemical Industry and Engineering Progress, 2019, 38(6): 2862-2869.
15	戚晓丽. 复合相变蓄冷剂开发及在果蔬保鲜上的应用研究[D]. 杭州: 浙江大学, 2015.
	QI X L. Research on the development of composite phase change accumulator and its application on fruit and vegetable preservation[D]. Hangzhou: Zhejiang University, 2015.
16	盛况. 农产品冷链专用高效相变蓄冷剂的应用研究[D]. 杭州: 浙江大学, 2016.
	SHENG K. Application study of high-efficiency phase change refrigerant for agricultural cold chain[D]. Hangzhou: Zhejiang University, 2016.
17	DERENSBERTHEAU E, OSSWALD V, LAGUERRE O, et al. Cold chain of chilled food in France[J]. International Journal of Refrigeration-revue Internationale Du Froid, 2015, 52: 161-167.
18	ASHOK A, BRISON M, LETALLEC Y. Improving cold chain systems: Challenges and solutions[J]. Vaccine, 2017, 35(17): 2217-2223.
19	雷国. 我国冷链物流业发展现状及对策[J]. 对外经贸, 2015(4): 59-61.
	LEI G. The current situation and countermeasures for the development of China's cold chain logistics industry[J]. Foreign Economic Relations & Trade, 2015(4): 59-61.
20	吴学红, 王春煦, 高茂条, 等. 相变蓄冷技术在食品冷链中的应用进展[J]. 冷藏技术, 2016, 39(3): 5-11.
	WU X H, WANG C X, GAO M T, et al. A review of application of phase change storage technology in the food cold chain[J]. Journal of Refrigeration Technology, 2016, 39(3): 5-11.
21	鄢冬茂. 相变储能材料在食品冷链物流中的应用研究进展[J]. 制冷与空调, 2017, 17(11): 1-5.
	YAN D M. The application of phase change in food cold chain logistics[J]. Refrigeration and Air-Conditioning, 2017, 17(11): 1-5.
22	豆孟柯, 刘宝林, 宋晓燕, 等. 蓄冷箱在疫苗冷链中的研究进展[J]. 制冷学报, 2019, 40(2): 135-141.
	DOU M K, LIU B L, SONG X Y, et al. Research progress of cold storage insulation box in vaccine cold chains[J]. Journal of Refrigeration, 2019, 40(2): 135-141.
23	ORO E, GRACIA D A, CASTELL A, et al. Review on phase change materials (PCMs) for cold thermal energy storage applications[J]. Applied Energy, 2012, 99(99): 513-533.
24	RATHOD M K, BANERJEE J. Thermal stability of phase change materials used in latent heat energy storage systems: A review[J]. Renewable and Sustainable Energy Reviews, 2013, 18: 246-258.
25	CÁRDENAS-RAMÍREZ C, JARAMILLO F, GÓMEZ M. Systematic review of encapsulation and shape-stabilization of phase change materials[J]. Journal of Energy Storage, 2020, 30: doi: 10.1016/j.est.2020.101495.
26	ZHAO Y, ZHANG X, XU X, et al. Development of composite phase change cold storage material and its application in vaccine cold storage equipment[J]. Journal of Energy Storage, 2020, 30: doi: 10.1016/j.est.2020.101455.
27	傅一波, 王冬梅, 朱宏. 果蔬保温包装中蓄冷剂的实验研究[J]. 包装工程, 2016, 37(21): 23-27.
	FU Y B, WANG D M, ZHU H. Cold storage agent for fruit and vegetable packaging[J]. Packaging Engineering, 2016, 37(21): 23-27.
28	李志江, 王水灵, 陈小兰, 等. 用于药品冷藏的蓄冷剂研究进展[J]. 2018, 39(1): P.37-43.
	LI Z J, WANG S L, CHEN X L, et al. Research progress of coolant for drug cold storage[J]. Pharmaceutical Engineering Design, 2018, 39(1):37-43.
29	赵建辉. 适用于血液疫苗相变材料的研制以及相变蓄能技术在部队冷藏库集装箱改造中的应用[D]. 北京: 中国人民解放军军事医学科学院, 2010.
	ZHAO J H. Development of phase change materials for blood vaccines and application of phase change energy storage technology in the modification of cold storage containers for the military[D]. Beijing: Academy of Military Medical Sciences, 2010.
30	于党伟. 冷藏用控温包装微胶囊相变蓄冷材料的制备及性能优化研究[D]. 无锡: 江南大学, 2014.
	YU D W. Preparation and performance optimization of temperature controlled packaging microencapsulated phase change cold storage materials for refrigeration[D]. Wuxi: Jiangnan University, 2014.
31	应铁进, 朱冰清, 戚晓丽, 等. 用于农产品保鲜的有机物水溶液相变蓄冷剂[J]. 农业机械学报, 2015, 46(2): 208-212, 207.
	YING T J, ZHU B Q, QI X L, et al. Development of organics solution phase change materials for preservation of agricultural products[J]. Transactions of the Chinese Society for Agricultural Machinery, 2015, 46(2): 208-212, 207.
32	应铁进, 苏党, 白家玮. 用于非冷冻低温区运输的复合有机物相变蓄冷剂[J]. 农业机械学报, 2017, 48(8): 309-314.
	YING T J, SU D, BAI J W. Organic phase change compound materials for non-freezing cold chain[J]. Transactions of the Chinese Society for Agricultural Machinery, 2017, 48(8): 309-314.
33	徐笑锋, 章学来, JOTHAM M, 等. 十水硫酸钠相变蓄冷保温箱保冷特性的试验研究[J]. 农业工程学报, 2017, 33(22): 308-314.
	XU X F, ZHANG X L, JOTHAM M, et al. Experimental study on cold retention characteristics of cold storage incubator using Na₂SO₄·10H₂O as PCMs[J]. Transactions of the Chinese Society of Agricultural Engineering, 2017, 33(22): 308-314.
34	朱志强, 张小栓, 于晋泽. 我国鲜活农产品冷链物流与纳米蓄冷材料的应用[J]. 中国果菜, 2014, 34(6): 14-18.
	ZHU Z Q, ZHANG X S, YU J Z. Nano cool-storage material and cold-chain logistics of fresh agriculture products[J]. China Fruit Vegetable, 2014, 34(6): 14-18.
35	CONG L, SHE X, LENG G, et al. Formulation and characterisation of ternary salt based solutions as phase change materials for cold chain applications[J]. Energy Procedia, 2019, 158: 5103-5108.
36	傅一波, 王家俊, 王冬梅. 复合相变蓄冷剂性能研究[J]. 化工新型材料, 2017, 45(10): 235-237.
	FU Y B, WANG J J, WANG D M. Study on the performance of composite phase change coolant[J]. New Chemical Materials, 2017, 45(10): 235-237.
37	李玉婷, 周永全, 葛飞, 等. 无机水合盐相变储能材料的过冷及相分离研究进展[J]. 盐湖研究, 2018, 26(1): 81-86.
	LI Y T, ZHOU Y Q, GE F, et al. Supercooling and phase separation of inorganic salt hydrates as phase change materials[J]. Journal of Salt Lake Research, 2018, 26(1): 81-86.
38	LI C, ZHANG B, XIE B, et al. Tailored phase change behavior of Na₂SO₄·10H₂O/expanded graphite composite for thermal energy storage[J]. Energy Conversion and Management, 2020, 208: doi: 10.1016/j.enconman.2020.112586.
39	ZHENG M, XIE C, LIU J, et al. Composite hydrate salt Na₂HPO₄·12H₂O-Na₂SO₄·10H₂O and its thermal storage properties[J]. Emerging Materials Research, 2019, 8(1): 68-76.
40	LI G, HWANG Y, RADERMACHER R, et al. Review of cold storage materials for subzero applications[J]. Energy, 2013, 51: 1-17.
41	JIA X, ZHAI X, CHENG X. Thermal performance analysis and optimization of a spherical PCM capsule with pin-fins for cold storage[J]. Applied Thermal Engineering, 2019, 148: 929-938.
42	ELIAS C N, STATHOPOULOS V N. A comprehensive review of recent advances in materials aspects of phase change materials in thermal energy storage[J]. Energy Procedia, 2019, 161: 385-394.
43	张志同, 王瑾, 柳建华, 等. Na₂SO₄·10H₂O相变蓄冷材料的研究进展[J]. 建筑节能, 2016, 44(8): 55-59.
	ZHANG Z T, WANG J, LIU J H, et al. Research progress of Na₂SO₄·10H₂O phase change cooling storage materials[J]. Building Energy Efficiency, 2016, 44(8): 55-59.
44	ORÓ E, BARRENECHE C, FARID M M, et al. Experimental study on the selection of phase change materials for low temperature applications[J]. Renewable Energy, 2013, 57: 130-136.
45	ZAHIR M H, MOHAMED S, SAIDUR A R, et al. Supercooling of phase-change materials and the techniques used to mitigate the phenomenon[J]. Applied Energy, 2019, 240: 793-817.
46	FANG Y T, SU J M, TANG Y F, et al. Form‐stable Na₂SO₄·10H₂O‐Na₂HPO₄·12H₂O eutectic/hydrophilic fumed silica composite phase change material with low supercooling and low thermal conductivity for indoor thermal comfort improvement[J]. International Journal of Energy Research, 2020, doi: 10.1002/er5178.
47	谷海明. 相变储能材料Mg(NO₃)₂·6H₂O的稳定与储热性能研究[D]. 昆明: 昆明理工大学, 2013.
48	XU X, ZHANG X, MUNYALO J M. Key technologies and research progress on enhanced characteristics of cold thermal energy storage[J]. Journal of Molecular Liquids, 2019, 278: 428-437.
49	黄金, 柯秀芳. 无机水合盐相变材料Na₂SO₄·10H₂O的研究进展[J]. 材料导报, 2008, 22(3): 63-67.
	HUANG J, KE X F. Research and development of Na₂SO₄·10H₂O as phase change materials[J]. Materials Review, 2008, 22(3): 63-67.
50	XU X F, ZHANG X L, ZHOU S X, et al. Experimental and application study of Na₂SO₄·10H₂O with additives for cold storage[J]. Journal of Thermal Analysis and Calorimetry, 2019, 136(2): 505-512.
51	何媚质, 杨鲁伟, 张振涛. 无机相变材料CaCl₂·6H₂O的过冷特性[J]. 化工学报, 2017, 68(11): 4016-4024.
	HE M Z, YANG L W, ZHANG Z T. Supercooling characteristics of inorganic phase change material CaCl₂·6H₂O[J]. CIESC Journal, 2017, 68(11): 4016-4024.
52	潘嘹. 潜热型控温包装系统传热模型与试验研究[D]. 无锡: 江南大学, 2016.
	PAN L. Heat transfer model and experimental study of latent heat type temperature control packaging system[D]. Wuxi: Jiangnan University, 2016.
53	ALEHOSSEINI E, JAFARI S M. Micro/nano-encapsulated phase change materials (PCMs) as emerging materials for the food industry[J]. Trends in Food Science & Technology, 2019, 91: 116-128.
54	SINGH S, GAIKWAD K K, LEE Y S. Phase change materials for advanced cooling packaging[J]. Environmental Chemistry Letters, 2018, 16(3): 845-859.
55	NIE B, SHE X, DU Z, et al. System performance and economic assessment of a thermal energy storage based air-conditioning unit for transport applications[J]. Applied Energy, 2019, 251: doi: 10.1016/j.apenergy.2019.05.057.
56	LI Y C, CHEN Y H. Assessing the thermal performance of three cold energy storage materials with low eutectic temperature for food cold chain[J]. Energy, 2016, 115: 238-256.
57	李忠平. 膨胀石墨/共晶盐复合相变蓄冷材料的制备及性能研究[D]. 广州: 华南理工大学, 2019.
	LI Z P. Preparation and properties of expanded graphite/eutectic salt composite phase change cold storage materials[D]. Guangzhou: South China University of Technology, 2019.
58	SHARMA R K, GANESAN P, TYAGI V V, et al. Developments in organic solid-liquid phase change materials and their applications in thermal energy storage[J]. Energy Conversion and Management, 2015, 95: 193-228.
59	REGIN A F, SOLANKI S C, SAINI J S. Heat transfer characteristics of thermal energy storage system using PCM capsules: A review[J]. Renewable and Sustainable Energy Reviews, 2008, 12(9): 2438-2458.
60	赵祎, 章学来, 徐笑锋, 等. 应用于冷链运输相变蓄冷技术研究进展[J]. 包装工程, 2020, 41(21): 117-124.
	ZHAO Y, ZHANG X L, XU X F, et al. Research progress of phase change cold storage technology applied to cold chain transportation[J]. Packaging Engineering, 2020, 41(21): 117-124.
61	汤元睿, 谢晶, 徐慧文, 等. 相变蓄冷工艺在金枪鱼冷链物流中的应用研究[J]. 现代食品科技, 2015, 31(1): 173-178, 253.
	TANG Y R, XIE J, XU H W, et al. Application of cold storage phase-change technology in cold chain logistics of tuna[J]. Modern Food Science & Technology, 2015, 31(1): 173-178, 253.
62	VEERAKUMAR C, SREEKUMAR A. Phase change material based cold thermal energy storage: Materials, techniques and applications-A review[J]. International Journal of Refrigeration, 2016, 67: 271-289.
63	GIRO-PALOMA J, MARTÍNEZ M, CABEZA L F, et al. Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review[J]. Renewable and Sustainable Energy Reviews, 2016, 53: 1059-1075.
64	HOANG H M, LEDUCQ D, PÉREZ-MASIA R, et al. Heat transfer study of submicro-encapsulated PCM plate for food packaging application[J]. International Journal of Refrigeration, 2015, 52: 151-160.
65	ORÓ E, GRACIA DE A, CABEZA L F. Active phase change material package for thermal protection of ice cream containers[J]. International Journal of Refrigeration, 2013, 36(1): 102-109.
66	LU W, TASSOU S A. Characterization and experimental investigation of phase change materials for chilled food refrigerated cabinet applications[J]. Applied Energy, 2013, 112: 1376-1382.
67	LEDUCQ D, NDOYE F T, ALVAREZ G. Phase change material for the thermal protection of ice cream during storage and transportation[J]. International Journal of Refrigeration, 2015, 52: 133-139.
68	BAI B, ZHAO K, LI X. Application research of nano-storage materials in cold chain logistics of e-commerce fresh agricultural products[J]. Results in Physics, 2019, 13: doi: 10.1016/j.rinp.2019.01.083.
69	彭胜华, 尹惠玲. 基于相变蓄冷技术的便携式离体样品储运装置的研制[J]. 中国医疗器械信息, 2014, 20(3): 47-50.
	PENG S H, YIN H L. The development of portable storage and transport equipment for the isolated samples based on cold-charging technology[J]. China Medical Device Information, 2014, 20(3): 47-50.
70	赵海民. 疫苗的运输、保管、使用应注意事项[J]. 中国畜禽种业, 2017, 13(3): 27.
	ZHAO H M. Vaccine transportation, storage and use should be noted[J]. The Chinese Livestock and Poultry Breeding, 2017, 13(3): 27.
71	高贵涛. 畜禽疫苗的安全保存与运输[J]. 新农村, 2015(4): 30.
	GAO G T. Safe storage and transportation of livestock vaccines[J]. New Countryside, 2015(4): 30.
72	杨梅. 疫苗运输、保存与使用过程中应注意的事项[J]. 甘肃畜牧兽医, 2017, 47(1): 100, 104.
	YANG M. Matters that should be noted during the transportation, preservation and use of vaccines[J]. Gansu Animal and Veterinary Sciences, 2017, 47(1): 100, 104.
73	郭浩, 刘敏霞, 阎少多, 等. 无源型低温血液运输箱的研制[J]. 军事医学, 2018, 42(7): 489-493.
	GUO H, LIU M X, YAN S D, et al. Development of passive low-temperature blood transportation boxes[J]. Military Medical Sciences, 2018, 42(7): 489-493.
74	CROMMELIN D J, ANCHORDOQUY T J, VOLKIN D B, et al. Addressing the cold reality of mRNA vaccine stability[J]. Journal of Pharmaceutical Sciences, 2021, 110(3): 997-1001.
75	李晓燕, 张晓雅, 邱雪君, 等. 相变蓄冷技术在食品冷链运输中的研究进展[J]. 包装工程, 2019, 40(15): 150-157.
	LI X Y, ZHANG X Y, QIU X J, et al. Research progress of phase change cold storage technology in food cold chain transportation[J]. Packaging Engineering, 2019, 40(15): 150-157.
76	马冰奇. 相变蓄冷技术在食品冷链中的应用与进展[J]. 制冷, 2016, 37(3): 79-83.
	MA B Q. Review of development of phase change cold storage technology for food cold chain application[J]. Refrigeration, 2016, 37(3): 79-83.
77	AHMED M, MEADE O, MEDINA M A. Reducing heat transfer across the insulated walls of refrigerated truck trailers by the application of phase change materials[J]. Energy Conversion and Management, 2010, 51(3): 383-392.
78	夏全刚, 刘宝林, 宋晓燕. 一种新型冷藏车箱体模型的设计与实验验证[J]. 制冷学报, 2014, 35(4): 108-112.
	XIA Q G, LIU B L, SONG X Y. Design and experimental verification of a new type of refrigerated vehicle model[J]. Journal of Refrigeration, 2014, 35(4): 108-112.
79	童山虎, 聂彬剑, 李子潇, 等. 基于相变蓄冷技术的冷链集装箱性能研究[J]. 储能科学与技术, 2020, 9(1): 211-216.
	TONG S H, NIE B J, LI Z X, et al. Investigation of the cold thermal energy storage reefer container for cold chain application[J]. Energy Storage Science and Technology, 2020, 9(1): 211-216.
80	李晓燕, 王雪雷, 苗馨月, 等. 冷链蓄冷保温箱性能优化数值模拟研究[J]. 节能技术, 2019, 37(1): 87-90.
	LI X Y, WANG X L, MIAO X Y, et al. Numerical simulation on performance optimization of cold storage incubator during cold chain progress[J]. Energy Conservation Technology, 2019, 37(1): 87-90.
81	HANSON C M, GEORGE A M, SAWADOGO A, et al. Is freezing in the vaccine cold chain an ongoing issue? A literature review[J]. Vaccine, 2017, 35(17): 2127-2133.
82	赵建辉, 张庆勇, 李捞摸. 相变储能技术在血液、疫苗储运装备中的应用[J]. 医疗卫生装备, 2010, 31(10): 108-110.
	ZHAO J H, ZHANG Q Y, LI L M. Application of phase change energy storage technology in storage and transportation equipments for blood and vaccine[J]. Chinese Medical Equipment Journal, 2010, 31(10): 108-110.
83	马艳娟, 郭鹏涛, 李宏, 等. 相变蓄冷剂结合冰袋用于高原野战条件下血液的储存[J]. 西南国防医药, 2017, 27(9): 918-921.
	MA Y J, GUO P T, LI H, et al. Application of phase change coolant combined with ice packs in blood storage under plateau field conditions[J]. Medical Journal of National Defending Forces in Southwest China, 2017, 27(9): 918-921.
84	洪乔荻, 邹同华, 宋晓燕, 等. 疫苗运输用蓄冷材料性能研究[J]. 低温与超导, 2013, 41(8): 59-62.
	HONG Q D, ZOU T H, SONG X Y, et al. Study on the performance of cool storage material for vaccine transportation[J]. Cryogenics and Superconductivity, 2013, 41(8): 59-62.

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