电化学氧还原反应合成H2O2碳基催化剂研究进展

doi:10.19799/j.cnki.2095-4239.2021.0122

摘要/Abstract

摘要：

电化学氧还原反应(ORR)合成H₂O₂是一种低成本、无污染的绿色合成方法。但是，ORR动力学缓慢，存在四电子ORR生成H₂O的竞争反应，因此需要使用催化剂提升ORR的反应活性以及二电子ORR的选择性。近年来，碳基材料因价格便宜、来源广泛、调控方法多样，被广泛应用于该领域。本文首先简要介绍了电催化ORR合成H₂O₂的机理，并根据机理分析了影响电化学合成H₂O₂催化性能的关键因素。接着阐述了提升碳基ORR催化剂活性与二电子选择性的策略，并着重介绍了非金属原子掺杂碳材料和过渡金属氮碳材料。最后，总结了碳基催化剂在电化学合成H₂O₂中存在的问题和面临的挑战，对碳基催化剂在电合成H₂O₂中应用的发展趋势进行了展望。

关键词: 电化学合成, 2电子氧还原反应, 过氧化氢, 掺杂碳材料, 过渡金属氮碳催化剂

Abstract:

The electrochemical synthesis of H₂O₂ via oxygen reduction reaction (ORR) is a low-cost, environment-friendly, and green synthesis method. However, the kinetics of ORR is very slow, and is also accompanied by the competitive reaction of 4 electron (4e^-) ORR to generate H₂O. The catalysts are therefore required. In recent years, carbon-based materials with low prices, abundant resources, competitive activity, and easy adjustability, have received extensive attention in this field. Herein, this review first briefly introduces the mechanism of ORR to the synthesis of H₂O₂, and the key factors of the catalytic performance of electrochemical synthesis of H₂O₂. Further, the strategy to improve the ORR activity and selectivity of carbon-based catalysts is reviewed, in which the doping of non-metallic atoms and the construction of transition metal single atoms on carbon-based materials are emphasized. Finally, the existing problems, challenges, and perspectives of carbon-based catalysts toward the electrosynthesis of H₂O₂ were described.

Key words: electrochemical synthesis, 2-electron oxygen reduction reaction, hydrogen peroxide, doped carbon materials, transition metal nitrogen-carbon catalysts

中图分类号:

O 643.36

何峰, 张静静, 陈奕君, 张建, 王得丽. 电化学氧还原反应合成H₂O₂碳基催化剂研究进展[J]. 储能科学与技术, 2021, 10(6): 1963-1976.

Feng HE, Jingjing ZHANG, Yijun CHEN, Jian ZHANG, Deli WANG. Recent progress on carbon-based catalysts for electrochemical synthesis of H₂O₂ via oxygen reduction reaction[J]. Energy Storage Science and Technology, 2021, 10(6): 1963-1976.

图/表 5

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电化学氧还原反应合成H₂O₂碳基催化剂研究进展

Recent progress on carbon-based catalysts for electrochemical synthesis of H₂O₂ via oxygen reduction reaction

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