锂离子电池及其材料热失控毒物研究

doi:10.3969/j.issn.2095-4239.2015.06.008

储能科学与技术 ›› 2015, Vol. 4 ›› Issue (6): 609-615.doi: 10.3969/j.issn.2095-4239.2015.06.008

锂离子电池及其材料热失控毒物研究

孙杰¹, 李吉刚¹, 党胜男¹, 唐娜¹, 周添¹, 李江存¹, 卫寿平¹, 杨凯², 高飞²

1 防化学院新能源与能源安全实验室,北京 102205;
2 中国电力科学研究院,北京 100192

收稿日期:2015-04-16 出版日期:2015-12-19 发布日期:2015-12-19
通讯作者: 孙杰（1974—）,女,博士,教授,研究方向为新能源及能源安全与防护,E-mail：magnsun@mail.tsinghua.edu.cn。
作者简介:孙杰（1974—）,女,博士,教授,研究方向为新能源及能源安全与防护,E-mail：magnsun@mail.tsinghua.edu.cn。

Research of toxic productions from thermal runaway processes of Li-ion battery and materials

SUN Jie¹, LI Jigang¹, DANG Shengnan¹, TANG Na¹, ZHOU Tian¹, LI Jiangcun¹, WEI Shouping¹, YANG Kai², GAO Fei²

1 Lab of Renewable Energy and Energy Safety, Institute of NBC Defense, Beijing 102205, China;
2 China Electric Power Research Institute, Beijing 100192, China

Received:2015-04-16 Online:2015-12-19 Published:2015-12-19

摘要/Abstract

摘要： 本文阐述了锂离子电池常规安全性问题和热失控引发燃烧爆炸泄漏毒物的非常规安全性问题,探讨了锂离子电池泄露物的毒性及其对人体和环境的危害,以电动车用锂离子电池为例分析了城市交通和环境将面临的继发问题和压力,定量对比了10 A·h软包装的磷酸铁锂、锰酸锂和三元材料锂离子电池热失控燃烧释放的代表性毒物之一的CO浓度,提出了锂离子电池热失控毒物安全性问题的不可回避性。

关键词: 锂离子电池, 材料, 毒物, 热失控

Abstract: The safety and thermal runaway processes of a lithium ion battery and its toxic leakage effects on human and environments are elaborated and discussed in detail. The EV power lithium ion battery was used as example to analysis its impact to a city environment. One of the representative combustion toxics CO was analyst in quantity from three different 10 A·h lithium ion cell (LiFePO₄, LiMnO₂ and NMC) combustion experiment. It shows that the toxics safety problems of lithium ion battery can not be ignored any more.

Key words: Li-ion battery, materials, toxics, thermal runway

中图分类号:

TM911

孙杰, 李吉刚, 党胜男, 唐娜, 周添, 李江存, 卫寿平, 杨凯, 高飞. 锂离子电池及其材料热失控毒物研究[J]. 储能科学与技术, 2015, 4(6): 609-615.

SUN Jie, LI Jigang, DANG Shengnan, TANG Na, ZHOU Tian, LI Jiangcun, WEI Shouping, YANG Kai, GAO Fei. Research of toxic productions from thermal runaway processes of Li-ion battery and materials[J]. Energy Storage Science and Technology, 2015, 4(6): 609-615.

参考文献

[1] Gallagher S. Boeing’s dreamliner batteries “inherently unsafe”—and yours may be too[EB/OL]. 2013-01-19. http://arstechnica.com/ business/2013/01/boeings-dreamliner-batteries-inherently-unsafe-and- yours- may-be-too/.
[2] Meier F,Woodyard C. Third fire in Tesla Model S reported[EB/OL]. 2013-07-11. http://www.usatoday.com/story/money/cars/2013/11/07/ third-fire-in-tesla-model-s-reported/3465717/>（2013).
[3] Cravotta N. Contributing technical editor for edn, understanding battery safety[EB/OL]. http://em. avnet.com / nscbatterymgt.
[4] Eshetu G G,Marlair G. In-depth safety-focused analysis of solvents used in electrolytes for large scale lithium ion batteries[J]. Phys. Chem. Chem. Phys. ,2013,15：9145.
[5] Ribiere P,Marlair G. Investigation on the fire-induced hazards of Li-ion battery cells by fire calorimetry[J]. Energy Environ. Sci. ,2012,5：5271.
[6] UN38.3 MSDS新版本锂电池UN38.3《危险物品规则》 [EB/OL]. http://www.cnlinfo.net/info /3088671.htm.
[7] UL. The standard in safety WHITE PAPER on：Safety issues for lithium-ion batteries[S].
[8] Lithium batteries：Markets and materials[R]. Report FCB028E,2009,http://www. ccresearch.com.
[9] FTA/FMEA safety analysis model for lithium-ion batteries[R]. UL presentation at 2009 NASA Aerospace Battery Workshop.
[10] Jones H. Critical review of commercial secondary lithium-ion battery safety standards[R]. UL presentation at 4th IAASS Conference,Making Safety Matter,2010.
[11] Yen K H. Estimation of explosive pressure for abused lithium-ion cells[R]. UL Presentation at 44th Power Sources Conference,2010.
[12] Alvin W. Blunt Nail Crush Internal Short Circuit Lithium-Ion Cell Test Method[R]. UL presentation at NASA Aerospace Battery Workshop,2009.
[13] 危险物品鉴定书MSDS检测,化学品MSDS测试,锂电池空运UN38.3认证[R]. http://www.china.nowec.com/product/detail/ 2471758. html.
[14] Liu Xin（刘馨）. 陈立泉：锂电产业全面突围是电动汽车发展的关键[J]. Advanced Materials Industry （新材料产业）,2014,16（10）：doi:10.3969/j.issn.1008-892X.2014.10.001.
[15] Dowall J M,Biensan P,Broussely M. Industrial lithium ion battery safety - What are the tradeoffs[S]. 978-1-4244-1628-8/07,IEEE,2007：701-707.
[16] Kim G H,Smith K,Pesaran A. Lithium-ion battery safety study using multi-physics internal short-circuit model[C]//The 5th Intl. Symposium on Large Lithium-Ion Battery Technology and Application in Conjunction with AABC09,Long Beach,2009.
[17] Spotnitz R,Franklin J. Abuse behavior of high-power lithium-ion cells[C]//11th International Meeting on Lithium Batteries,Monterey,California,2002.
[18] Tobishima S,Takei K,Sakurai Y,Yamaki J. Lithium ion cell safety[J]. J. Power Sources ,2000,90：188-195.
[19] Huang P,Wang Q,Li K,Ping P,Sun J. The combustion behavior of large scale lithium titanate battery[J]. Sci. Rep. ,2015,doi:10.1038/srep07788.
[20] Sun J,Qiu X P,Lai X K. Investigation on the toxic leakage production process of Li-ion battery induced by combustion[R]. Chengdu：Presentation at 8th China-US Electric Vehicle and Battery Technology Workshop,2013.
[21] Sun J,Dong Z C,Li J G. Toxity analysis and test methods for EV Li-ion battery and materials[C]//Presentation at 5th China-US Electric Vehicle and Battery Technology Workshop,Hangzhou,2012.
[22] Sun J,Qiu X P,Dong Z C,Li J G. Safety and toxity analysis for materials of EV power Li-ion battery[C]//Argonne National Laboratory：4th US-Cina Electric Vehicle and Battery Technology Workshop,2011.
[23] Choi K H,Cho S J,Kim S H. Thin, deformable, and safety-reinforced plastic crystal polymer electrolytes for high-performance flexible lithium-ion batteries[J]. Advanced Functional Materials ,2014,24：44-52.
[24] Spotnitz R,Muller R. Simulation of abuse behavior of lithium-ion batteries[J]. Electrochemical Society Interface ,2012,21：57-60.
[25] Zhang Z,Fouchard D,Rea J. Differential scanning calorimetry material studies：Implications for the safety of lithium-ion cells[J]. Journal of Power Sources ,1998,70：16-20.
[26] Fu Y,Lu S,Li K,Liu C,Cheng X,Zhang H. An experimental study on burning behaviors of 18650 lithium ion batteries using a cone calorimeter[J]. Journal of Power Sources ,2015,273：216-222.
[27] Eshetu G G,Bertrand J P,Lecocq A,Grugeon S,Laruelle S,Armand M,Marlair G. Fire behavior of carbonates-based electrolytes used in Li-ion rechargeable batteries with a focus on the role of the LiPF 6 and LiFSI salts[J]. Journal of Power Sources ,2014,269：804-811.
[28] Ravdel B,Abraham K M,Gitzendanner R. Thermal stability of lithium-ion battery electrolytes[J]. Journal of Power Sources ,2003,119-121：805-810.
[29] Pasquier D A,Disma F,Bowmer T,Gozdz A S,Amatucci G,Tarascon J M. Study of the reactivity of carbon anodes in plastic Li-ion battery[J]. J. Electrochem. Soc. ,1998 ,145（2）：472-477.
[30] 中国工程科技发展战略研究院. 中国战略性新兴产业发展报告[M]. 北京：科学出版社,2013.

锂离子电池及其材料热失控毒物研究

Research of toxic productions from thermal runaway processes of Li-ion battery and materials

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