液相法合成磷酸铁锂的研究进展

doi:10.3969/j.issn.2095-4239.2014.04.007

储能科学与技术 ›› 2014, Vol. 3 ›› Issue (4): 339-344.doi: 10.3969/j.issn.2095-4239.2014.04.007

液相法合成磷酸铁锂的研究进展

赵领, 刘兴泉, 王伟, 张峥, 赵红远

电子科技大学微电子与固体电子学院,电子薄膜与集成器件国家重点实验室,新能源材料与集成能源器件研发中心, 四川成都 610054

收稿日期:2014-02-11 出版日期:2014-07-01 发布日期:2014-07-01
通讯作者: 刘兴泉,教授,研究方向为新型储能与能量转换材料及集成储能器件,E-mail:lxquan2000@sina.com.
作者简介:赵领(1985--),男,硕士研究生,研究方向为锂离子电极材料与器件,E-mail:flyzhaoling@126.com;
基金资助:
国家自然科学基金(21071026)及电子科技大学杰出人才引进计划项目(08JC00303)

Research progress on liquid synthesis of lithium ferrous phosphate

ZHAO Ling, LIU Xingquan, WANG Wei, ZHANG Zheng, ZHAO Hongyuan

School of Microelectronics and Solid State Electronics,State Key Laboratory of Electronic Thin Film and Integrated Devices,Research & Development Center for New Power Materials and Integrated Power Devices,University of Electronic Science and Technology of China,Chengdu 610054,Sichuan,China

Received:2014-02-11 Online:2014-07-01 Published:2014-07-01

摘要/Abstract

摘要： 磷酸铁锂已经成为一种重要的锂离子动力电池正极材料,磷酸铁锂的合成方法分为固相法和液相法.液相法合成对材料的微观形貌影响较大,在合成具有特定形貌和尺寸的磷酸铁锂材料时,仍然以液相法合成为主.本文较详细地介绍了近年来液相法中的溶剂热法和溶胶-凝胶法制备磷酸铁锂的研究进展,包括传统的水热合成和非水溶剂热合成以及溶胶-凝胶法在某些具有特殊微结构的磷酸铁锂制备中的研究进展.

关键词: 锂离子电池, 磷酸铁锂, 溶剂热合成, 水热合成, 溶胶-凝胶法

Abstract: After more than a decade LiFePO₄ has become a widely used cathode material for lithium ion batteries due to its intrinsic properties such as safety and stability. Its preparation method includes solid state reactions and liquid phase reactions, of which liquid phase route has advantages of unique morphology and sizes. This work summarizes our recent work on the conventional hydrothermal and anhydrous-solvothermal processes and sol-gel methods for preparing LiFePO₄ with special microstructures.

Key words: lithium ion batteries, LiFePO4, solvothermal synthesis, hydrothermal synthesis, sol-gel method

中图分类号:

TM911

赵领, 刘兴泉, 王伟, 张峥, 赵红远. 液相法合成磷酸铁锂的研究进展[J]. 储能科学与技术, 2014, 3(4): 339-344.

ZHAO Ling, LIU Xingquan, WANG Wei, ZHANG Zheng, ZHAO Hongyuan. Research progress on liquid synthesis of lithium ferrous phosphate[J]. Energy Storage Science and Technology, 2014, 3(4): 339-344.

参考文献

[1] Park O K,Cho Y,Lee S,Yoo H C, et al . Who will drive electric vehicles, olivine or spinel?[J]. Energy & Environmental Science ,2011,4(5):1621-1633.
[2] Pecharsky V K,Zavalij P Y. Fundamentals of Powder Diffraction and Structural Characterization of Materials[M]. US:Springer,2009:691-702.
[3] Guang Cao,Lee Haiwon,Lynch Vincent M,Mallouk Thomas E. Structural studies of some new lamellar magnesium, manganese and calcium phosphorates[J]. Solid State Ionics ,1988,26(2):63-69.
[4] Levasseur S,Ménétrier M,Shao H Y,Gautier L, et al . Oxygen vacancies and intermediate spin trivalent cobalt ions in lithium-over stoichiometric LiCoO 2 [J]. Chemistry of Materials ,2002,15(1):348-354.
[5] Zaghib K,Guerfi A,Hovington P,Goodenough J B. Review and analysis of nanostructured olivine-based lithium rechargeable batteries:Status and trends[J]. Journal of Power Sources ,2013,232(213):357-369.
[6] Wang Yonggang,He Ping,Zhou Haoshen. Olivine LiFePO 4 :Development and future[J]. Energy & Environmental Science ,2011,4(3):805-817.
[7] Liao Xiaozhen,Ma Zifeng,Wang Liang, et al . A novel synthesis route for LiFePO 4 /C cathode materials for lithium-ion batteries[J]. Electrochemical and Solid-State Letters ,2004,7(12):A522-A525.
[8] Rangappa D,Sone K,kudo T, et al. Directed growth of nanoarchitectured LiFePO 4 electrode by solvothermal synthesis and their cathode properties[J]. Journal of Power Sources ,2010,195(18):6167-6171.
[9] Wei Lei(魏蕾),Guo Chunyu(郭春雨),Zhao Yongnan(赵永男), et al . Synthesis of LiFePO 4 by carbon-thermal reduction using FePO 4 as raw material[J]. Chinese Journal of Power Sources (电源技术),2013,37(1):25-27.
[10] Li Junyan,Zhao Haiyan,Qu Guangfei,Gu Junjie,Ning Ping. Research of lithium ferrous phosphate by microwave technique[J]. Materials Science Forum ,2013,743(2013):455-462.
[11] Jheng Jenn Shing,Chen Si Chi. The synthesis of LiFePO 4 /C composite by the precipitation between two water/oil emulsions[J]. Int. J. Electrochem. Sci .,2013,8(4):4901-4913.
[12] Wang Shuping,Yang Hongxiao,Feng Lijun, et al . A simple and inexpensive synthesis route for LiFePO 4 /C nanoparticles by co-precipitation[J]. Journal of Power Sources ,2013,233:43-46.
[13] Hu Zhiqiang,Yang Dongxue,Yin Kejian, et al . The effect of lithium source on the electrochemical performance of LiFePO 4 /C cathode materials synthesized by sol-gel method[J]. Advanced Materials Research ,2013,669(2013):311-315.
[14] Xie Gang,Zhu Huajun,Liu Xiaomin, et al . A core-shell LiFePO 4 /C nanocomposite prepared via a sol-gel method assisted by citric acid[J]. Journal of Alloys and Compounds ,2013,574:155-160
[15] Jüstel M,Schwinger A,Friedrich B, et al . Synthesis of LiFePO 4 by ultrasonic and nozzle spray pyrolysis[J]. Zeitschrift für Physikalische Chemie ,2012,226(2):177-183.
[16] Konarova M,Taniguchi I. Preparation of carbon coated LiFePO 4 by a combination of spray pyrolysis with planetary ball-milling followed by heat treatment and their electrochemical properties[J]. Powder Technology ,2009,191(1):111-116.
[17] Chen Jiajun,Bai Jianming,Chen Haiyan, et al . In situ hydrothermal synthesis of LiFePO 4 studied by synchrotron X-ray diffraction[J]. The Journal of Physical Chemistry Letters ,2011,2(15):1874-1878.
[18] Qian Jun(钱俊). 锂离子二次电池正极材料LiFePO 4 的水热合成及其改性研究[D]. Wuhan:Wuhan University of Technology,2012.
[19] Kuwahara A,Suzuki S,Miyayama M, et al . Hydrothermal synthesis of LiFePO 4 with small particle size and its electrochemical properties[J]. Journal of Electroceramics ,2010,24(2):69-75.
[20] Ellis B,Kan W H,Makahnouk W R M, et al . Synthesis of nanocrystals and morphology control of hydrothermally prepared LiFePO 4 [J]. Journal of Materials Chemistry ,2007,17(30):3248-3254.
[21] Ravet N,Gauthier M,Goodenough J B, et al . Mechanism of the Fe 3+ reduction at low temperature for LiFePO 4 synthesis from a polymeric additive[J]. Chemistry of Materials ,2007,19(10):2595-2602.
[22] Ni Jiangfeng,Morishita M,Kawabe Y, et al . Hydrothermal preparation of LiFePO 4 nanocrystals mediated by organic acid[J]. Journal of Power Sources ,2010,195(9):2877-2882.
[23] Murugan A V,Muraliganth T,Manthiram A. One-pot microwave-hydrothermal synthesis and characterization of carbon-coated LiMPO 4 (M= Mn, Fe, and Co) cathodes[J]. Journal of the Electrochemical Society ,2009,156(2):A79-A83.
[24] Yang Gang,Ji Hongmei,Liu Haidong, et al . Fast preparation of LiFePO 4 nanoparticles for lithium batteries by microwave-assisted hydrothermal method[J]. Journal of Nanoscience and Nanotechnology ,2010,10(2):980-986.
[25] Sun Ying(孙莹). 微波水热法制备LiFePO 4 电池阴极材料的研究[D]. Xi , an:Shaanxi University of Science Technology,2012.
[26] Cho Minyoung,Kim Kwangbum,Lee Jaewon, et al . Defect-free solvothermally assisted synthesis of microspherical mesoporous LiFePO 4 /C[J]. RSC Advances ,2013,3(10):3421-3427.
[27] Nan Caiyun,Lu Jun,Chen Chen, et al . Solvothermal synthesis of lithium iron phosphate nanoplates[J]. Journal of Materials Chemistry ,2011,21(27):9994-9996.
[28] Qu Yi(瞿毅),Tang Xincun(唐新村),Li Lianxing(李连兴), et al . Solvothermal systhesis of electrochemical properties of LiFePO 4 using different sdvents[J]. Journal of Central South University : Science and Technology (中南大学学报:自然科学版),2012,43(2):450-454.
[29] Guo Hongxia,Qiao Yuechun,Liu Guohua, et al . Solvothermal synthesis of nanoscaled LiFePO 4 with thinner thickness along [010] direction[J]. Russian Journal of Electrochemistry ,2013,49(4):396-399.
[30] Liu Xiaofei,Huang Jiaqi,Zhang Qiang, et al . N -Methyl- 2-pyrrolidone-assisted solvothermal synthesis of nanosize orthorhombic lithium iron phosphate with improved Li-storage performance[J]. Journal of Materials Chemistry ,2012,22(36):18908-18914.
[31] Zhou N,Wang H Y,Uchaker E, et al . Additive-free solvothermal synthesis and Li-ion intercalation properties of dumbbell-shaped LiFePO 4 /C mesocrystals[J]. Journal of Power Sources ,2013,239(2013):103-110.
[32] Dislich H. New routes to multiconponent oxide glasses[J]. Angewandte Chemie ,1971,10(6):363-370.
[33] Brinker C J,Keefer K D,Schaefer D W, et al . Sol-gel transition in simple silicates[J]. Journal of Non-Crystalline Solids ,1982,48(1):47-64.
[34] Hsu K F,Tsay S Y,Hwang B J. Synthesis and characterization of nano-sized LiFePO 4 cathode materials prepared by a citric acid-based sol-gel route[J]. Journal of Materials Chemistry ,2004,14(17):2690-2695.
[35] Wang Fuqing,Chen Jian,Wu Minghao,Yi Baolian. Propylene oxide-assisted fast sol-gel synthesis of mesoporous and nano-structured LiFePO 4 /C cathode materials[J]. Ionics ,2013,19(3):451-460.
[36] Qin Guohui,Ma Qianqian,Wang Chengyang. A porous C/LiFePO 4 /multiwalled carbon nanotubes cathode material for lithium ion batteries[J]. Electrochimica Acta ,2014,115:407-415.

液相法合成磷酸铁锂的研究进展

Research progress on liquid synthesis of lithium ferrous phosphate

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李海涛, 孔令丽, 张欣, 余传军, 王纪威, 徐琳. N/P设计对高镍NCM/Gr电芯性能的影响[J]. 储能科学与技术, 2022, 11(7): 2040-2045.
[2]	陈龙, 夏权, 任羿, 曹高萍, 邱景义, 张浩. 多物理场耦合下锂离子电池组可靠性研究现状与展望[J]. 储能科学与技术, 2022, 11(7): 2316-2323.
[3]	易顺民, 谢林柏, 彭力. 基于VF-DW-DFN的锂离子电池剩余寿命预测[J]. 储能科学与技术, 2022, 11(7): 2305-2315.
[4]	张肖洒, 王宏源, 李振彪, 夏志美. 废旧磷酸铁锂电池电极材料的硫酸化焙烧-水浸新工艺[J]. 储能科学与技术, 2022, 11(7): 2066-2074.
[5]	祝庆伟, 俞小莉, 吴启超, 徐一丹, 陈芬放, 黄瑞. 高能量密度锂离子电池老化半经验模型[J]. 储能科学与技术, 2022, 11(7): 2324-2331.
[6]	王宇作, 王瑨, 卢颖莉, 阮殿波. 孔结构对软碳负极储锂性能的影响[J]. 储能科学与技术, 2022, 11(7): 2023-2029.
[7]	刘显茜, 孙安梁, 田川. 基于仿生翅脉流道冷板的锂离子电池组液冷散热[J]. 储能科学与技术, 2022, 11(7): 2266-2273.
[8]	孔为, 金劲涛, 陆西坡, 孙洋. 对称蛇形流道锂离子电池冷却性能[J]. 储能科学与技术, 2022, 11(7): 2258-2265.
[9]	霍思达, 薛文东, 李新丽, 李勇. 基于CiteSpace知识图谱的锂电池复合电解质可视化分析[J]. 储能科学与技术, 2022, 11(7): 2103-2113.
[10]	邓健想, 赵金良, 黄成德. 高能量锂离子电池硅基负极黏结剂研究进展[J]. 储能科学与技术, 2022, 11(7): 2092-2102.
[11]	欧宇, 侯文会, 刘凯. 锂离子电池中的智能安全电解液研究进展[J]. 储能科学与技术, 2022, 11(6): 1772-1787.
[12]	韩俊伟, 肖菁, 陶莹, 孔德斌, 吕伟, 杨全红. 致密储能：基于石墨烯的方法学和应用实例[J]. 储能科学与技术, 2022, 11(6): 1865-1873.
[13]	辛耀达, 李娜, 杨乐, 宋维力, 孙磊, 陈浩森, 方岱宁. 锂离子电池植入传感技术[J]. 储能科学与技术, 2022, 11(6): 1834-1846.
[14]	燕乔一, 吴锋, 陈人杰, 李丽. 锂离子电池负极石墨回收处理及资源循环[J]. 储能科学与技术, 2022, 11(6): 1760-1771.
[15]	沈秀, 曾月劲, 李睿洋, 李佳霖, 李伟, 张鹏, 赵金保. γ射线辐照交联原位固态化阻燃锂离子电池[J]. 储能科学与技术, 2022, 11(6): 1816-1821.