火焰法原位改性不锈钢电极及其电催化析氧反应的研究

doi:10.19799/j.cnki.2095-4239.2025.0292

储能科学与技术 ›› 2025, Vol. 14 ›› Issue (10): 4020-4026.doi: 10.19799/j.cnki.2095-4239.2025.0292

火焰法原位改性不锈钢电极及其电催化析氧反应的研究

白智群(), 沙微浩, 苗津源, 谢鳌, 林峻如, 万平玉, 唐阳()

北京化工大学化学学院，北京 100029

收稿日期:2025-03-27 修回日期:2025-04-10 出版日期:2025-10-28 发布日期:2025-10-20
通讯作者: 唐阳 E-mail:baizq@mail.buct.edu.cn;120616135@qq.com
作者简介:白智群（1990—），男，博士研究生，研究方向为电解水制氢阳极催化剂，E-mail：baizq@mail.buct.edu.cn；
基金资助:
中央高校基本科研业务费(BH202436)

Flame-enabled in situ engineering of stainless-steel electrodes for high-efficiency electrocatalytic oxygen evolution

Zhiqun BAI(), Weihao SHA, Jinyuan MIAO, Ao XIE, Junru LIN, Pingyu WAN, Yang TANG()

College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

Received:2025-03-27 Revised:2025-04-10 Online:2025-10-28 Published:2025-10-20
Contact: Yang TANG E-mail:baizq@mail.buct.edu.cn;120616135@qq.com

摘要/Abstract

摘要：

本研究发展了一种基于火焰燃烧的“一步成型”原位改性策略，在316L不锈钢表面原位构筑多孔NiFe复合氧化物催化层(NiFe/316L)，实现了析氧反应(OER)催化剂活性与工业稳定性的协同优化。通过高温火焰氧化耦合及快速冷淬，实现合金相分离与分级造孔，形成具有连续多孔结构的多孔界面；X射线光电子能谱(XPS)证实电极表面Ni，Fe，O元素共存，并均匀地分布在电极表面。在1 mol/L KOH中，电极表现出优异OER活性，10 mA/cm²下过电位为256 mV，Tafel斜率为40.8 mV/dec，电化学活性面积为141 cm²，较基底提升7倍，电荷转移电阻(R_ct)从基底的202.9 Ω降至3.36 Ω。在模拟工业条件(30% KOH，80 ℃)下，1000 mA/cm²电流密度持续运行100小时后，电极性能未有明显衰减，稳定性优于多数报道的非贵金属催化剂。本研究为工业级OER电极开发提供了高效、低成本的解决方案。

关键词: 析氧反应, 316L不锈钢, 火焰燃烧法, 电解水

Abstract:

This study presents a flame-combustion-driven one-step in situ modification strategy to construct a porous NiFe composite oxide catalytic layer (NiFe/316L) on 316L stainless steel, achieving synergistic optimization of oxygen evolution reaction (OER) activity and industrial-grade stability. A hierarchical porous structure with interconnected channels was fabricated through high-temperature flame oxidation coupled with rapid quenching, inducing alloy phase separation and multiscale pore formation. X-ray photoelectron spectroscopy confirmed the coexistence and uniform distribution of Ni, Fe, and O species across the electrode surface. In 1 mol/L KOH electrolyte, the optimized electrode exhibited excellent OER performance with a low overpotential of 256 mV at 10 mA/cm², a Tafel slope of 40.8 mV/dec, and a sevenfold increase in electrochemically active surface area (141 cm²) relative to the bare substrate. The charge transfer resistance decreased markedly from 202.9 Ω to 3.36 Ω. Under industrially relevant conditions (30% KOH, 80 ℃), the electrode demonstrated outstanding durability with negligible performance decay after 100 h of continuous operation at 1000 mA/cm², surpassing most reported non-precious metal catalysts. This work offers a cost-effective and scalable approach for fabricating industrially viable OER electrodes

Key words: oxygen evolution reaction, 316L stainless steel, flame spray pyrolysis, electrolysis water

中图分类号:

TK 02

白智群, 沙微浩, 苗津源, 谢鳌, 林峻如, 万平玉, 唐阳. 火焰法原位改性不锈钢电极及其电催化析氧反应的研究[J]. 储能科学与技术, 2025, 14(10): 4020-4026.

Zhiqun BAI, Weihao SHA, Jinyuan MIAO, Ao XIE, Junru LIN, Pingyu WAN, Yang TANG. Flame-enabled in situ engineering of stainless-steel electrodes for high-efficiency electrocatalytic oxygen evolution[J]. Energy Storage Science and Technology, 2025, 14(10): 4020-4026.

图/表 4

参考文献 25

[1]	国家发展改革委. 国家发展改革委发布«氢能产业发展中长期规划(2021—2035年)»[J]. 稀土信息, 2022(4): 26-32.
	National Development and Reform Commission. The National Development and Reform Commission issued the medium and long-term plan for the development of hydrogen energy industry (2021-2035)[J]. Rare Earth Information, 2022(4): 26-32.
[2]	刘玮, 万燕鸣, 熊亚林, 等. "双碳" 目标下我国低碳清洁氢能进展与展望[J]. 储能科学与技术, 2022, 11(2): 635-642. DOI: 10.19799/j.cnki.2095-4239.2021.0385.
	LIU W, WAN Y M, XIONG Y L, et al. Outlook of low carbon and clean hydrogen in China under the goal of "carbon peak and neutrality"[J]. Energy Storage Science and Technology, 2022, 11(2): 635-642. DOI: 10.19799/j.cnki.2095-4239.2021.0385.
[3]	陈海生, 李泓, 徐玉杰, 等. 2023年中国储能技术研究进展[J]. 储能科学与技术, 2024, 13(5): 1359-1397. DOI: 10.19799/j.cnki.2095-4239.2024.0441.
	CHEN H S, LI H, XU Y J, et al. Research progress on energy storage technologies of China in 2023[J]. Energy Storage Science and Technology, 2024, 13(5): 1359-1397. DOI: 10.19799/j.cnki.2095-4239.2024.0441.
[4]	MAN I C, SU H Y, CALLE-VALLEJO F, et al. Cover picture: Universality in oxygen evolution electrocatalysis on oxide surfaces [J]. ChemCatChem, 2011, 3(7): 1085. DOI: 10.1002/cctc.201190027.
[5]	XING Y C, LIU S L, LIU Y, et al. Construction of nickel phosphide/iron oxyhydroxide heterostructure nanoparticles for oxygen evolution[J]. Nano Energy, 2024, 123: 109402. DOI: 10.1016/j.nanoen.2024.109402.
[6]	张唯怡, 张议洁, 王进伟, 等. 电解水制氢技术及大电流析氧反应研究与展望[J]. 工程科学学报, 2023, 45(7): 1057-1070. DOI: 10. 13374/j.issn2095-9389.2022.09.20.005.
	ZHANG W Y, ZHANG Y J, WANG J W, et al. Research and perspectives on electrocatalytic water splitting and large current density oxygen evolution reaction[J]. Chinese Journal of Engineering, 2023, 45(7): 1057-1070. DOI: 10.13374/j.issn2095-9389.2022.09.20.005.
[7]	NAMI H, RIZVANDI O B, CHATZICHRISTODOULOU C, et al. Techno-economic analysis of current and emerging electrolysis technologies for green hydrogen production[J]. Energy Conversion and Management, 2022, 269: 116162. DOI: 10.1016/j.enconman. 2022.116162.
[8]	WANG J, GAO Y, KONG H, et al. Non-precious-metal catalysts for alkaline water electrolysis: Operando characterizations, theoretical calculations, and recent advances[J]. Chemical Society Reviews, 2020, 49(24): 9154-9196. DOI: 10.1039/d0cs00575d.
[9]	WAN R D, YUAN T H, WANG L C, et al. Earth-abundant electrocatalysts for acidic oxygen evolution[J]. Nature Catalysis, 2024, 7(12): 1288-1304. DOI: 10.1038/s41929-024-01266-6.
[10]	TANG D, MABAYOJE O, LAI Y Q, et al. In situ growth of Fe(Ni)OOH catalyst on stainless steel for water oxidation[J]. ChemistrySelect, 2017, 2(7): 2230-2234. DOI: 10.1002/slct.2017 00081.
[11]	WU H B, LOU X W D. Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges[J]. Science Advances, 2017, 3(12): eaap9252. DOI: 10.1126/sciadv.aap9252.
[12]	KIM J, LEE C W, KIM S, et al. Electrodeposited NiFe layered double hydroxide on Ni foam for efficient oxygen evolution reaction[J]. Chemistry of Materials, 2020, 32(18): 7624-7632.
[13]	SWARNKAR P, SARFO D K, PANNU A S, et al. Co-electrodeposition of nanostructured Ce-NiOx on stainless-steel substrates for the oxygen evolution reaction under alkaline conditions[J]. Advanced Materials Technologies, 2022, 7(4): 2100705. DOI: 10.1002/admt.202100705.
[14]	DAI W J, YANG X Y, HU F Y, et al. Solution combustion synthesis of hierarchical porous CoNiFeCu_0.1 medium-entropy alloy: A highly efficient and robust electrocatalyst for water oxidation[J]. Journal of Alloys and Compounds, 2023, 952: 169987. DOI: 10. 1016/j.jallcom.2023.169987.
[15]	QAYUM A, PENG X, YUAN J F, et al. Highly durable and efficient Ni-FeOx/FeNi₃ electrocatalysts synthesized by a facile In situ combustion-based method for overall water splitting with large current densities[J]. ACS Applied Materials & Interfaces, 2022, 14(24): 27842-27853. DOI: 10.1021/acsami.2c04562.
[16]	YU D S, HAO Y X, HAN S L, et al. Ultrafast combustion synthesis of robust and efficient electrocatalysts for high-current-density water oxidation[J]. ACS Nano, 2023. DOI: 10.1021/acsnano.2c11939.
[17]	TAMURA H, MITA K, TANAKA A, et al. Mechanism of hydroxylation of metal oxide surfaces[J]. Journal of Colloid and Interface Science, 2001, 243(1): 202-207. DOI: 10.1006/jcis. 2001.7864.
[18]	VOIRY D, CHHOWALLA M, GOGOTSI Y, et al. Best practices for reporting electrocatalytic performance of nanomaterials[J]. ACS Nano, 2018, 12(10): 9635-9638. DOI: 10.1021/acsnano.8b07700.
[19]	李航洋, 周凌, 韩博鸣, 等. CoFeOx/MoO₂准平行纳米阵列电极的析氢性能[J]. 无机化学学报, 2023, 39(7): 1275-1286.
	LI H Y, ZHOU L, HAN B M, et al. Hydrogen evolution performance of CoFeOx/MoO₂ quasi-parallel nanoarray electrode[J]. Chinese Journal of Inorganic Chemistry, 2023, 39(7): 1275-1286.
[20]	BUCCI A, GARCÍA-TECEDOR M, CORBY S, et al. Self-supported ultra-active NiO-based electrocatalysts for the oxygen evolution reaction by solution combustion[J]. Journal of Materials Chemistry A, 2021, 9(21): 12700-12710. DOI: 10.1039/D1TA00072A.
[21]	NAGAYAMA T, YAMAMOTO T, NAKAMURA T. Thermal expansions and mechanical properties of electrodeposited Fe-Ni alloys in the Invar composition range[J]. Electrochimica Acta, 2016, 205: 178-187. DOI: 10.1016/j.electacta.2016.04.089.
[22]	SMITH R D L, BERLINGUETTE C P. Accounting for the dynamic oxidative behavior of nickel anodes[J]. Journal of the American Chemical Society, 2016, 138(5): 1561-1567. DOI: 10.1021/jacs. 5b10728.
[23]	LI G Q, LI L, ZHANG J H, et al. Enhance the proportion of Fe³⁺ in NiFe-layered double hydroxides by utilizing citric acid to improve the efficiency and durability of the oxygen evolution reaction[J]. ChemSusChem, 2025, 18(3): e202401582. DOI: 10.1002/cssc. 202401582.
[24]	ZHANG B, WANG L, CAO Z, et al. High-valence metals improve oxygen evolution reaction performance by modulating 3d metal oxidation cycle energetics[J]. Nature Catalysis, 2020, 3(12): 985-992. DOI: 10.1038/s41929-020-00525-6.
[25]	ZHANG N, HU Y, AN L, et al. Surface activation and Ni-S stabilization in NiO/NiS₂ for efficient oxygen evolution reaction[J]. Angewandte Chemie International Edition, 2022, 61(35): e202207217. DOI: 10.1002/anie.202207217.

火焰法原位改性不锈钢电极及其电催化析氧反应的研究

Flame-enabled in situ engineering of stainless-steel electrodes for high-efficiency electrocatalytic oxygen evolution

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 4

参考文献 25

相关文章 9

编辑推荐

Metrics

本文评价

[1]	阚宏伟, 吴孝彬, 何良, 张新建, 邢官飞. 操作条件对低温PEM电解水单池CV测试的影响及机理分析[J]. 储能科学与技术, 2024, 13(5): 1653-1657.
[2]	邢学奇, 宋鹏翔, 申爱景, 鲁仰辉, 陈俊, 刘伟. 电解水制氢用阴离子交换膜研究进展[J]. 储能科学与技术, 2024, 13(11): 3856-3870.
[3]	徐进, 丁显, 宫永立, 何广利, 胡婷. 电解水制氢厂站经济性分析[J]. 储能科学与技术, 2022, 11(7): 2374-2385.
[4]	王培灿, 万磊, 徐子昂, 许琴, 庞茂斌, 陈金勋, 王保国. 基于界面工程的自支撑催化电极用于电解水制氢[J]. 储能科学与技术, 2022, 11(6): 1934-1946.
[5]	林楠, KREWER Ulrike, ZAUSCH Jochen, STEINER Konrad, 林海波, 冯守华. 电化学能量储存和转换体系多物理场模型的建立及其应用[J]. 储能科学与技术, 2022, 11(4): 1149-1164.
[6]	徐滨, 王锐, 苏伟, 何广利, 缪平. 质子交换膜电解水技术关键材料的研究进展与展望[J]. 储能科学与技术, 2022, 11(11): 3510-3520.
[7]	丁显, 冯涛, 何广利, 胡婷, 刘延江. 风电光伏波动性电源对电解水制氢电解槽影响的研究进展[J]. 储能科学与技术, 2022, 11(10): 3275-3284.
[8]	杨家豪, 施兆平, 王意波, 葛君杰, 刘长鹏, 邢巍. 用于酸性析氧反应研究的原位表征技术[J]. 储能科学与技术, 2021, 10(6): 1877-1890.
[9]	苏秀丽, 廖文俊, 李严. 分步法电解水制氢的机遇与挑战[J]. 储能科学与技术, 2021, 10(1): 87-95.