Energy Storage Science and Technology ›› 2022, Vol. 11 ›› Issue (6): 1934-1946.doi: 10.19799/j.cnki.2095-4239.2022.0195

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Interface engineering of self-supported electrode for electrochemical water splitting

WANG Peican(), WAN Lei, XU Ziang, XU Qin, PANG Maobin, CHEN Jinxun, WANG Baoguo()   

  1. Department of chemical engineering, Tsinghua University, Beijing 100084, China
  • Received:2022-04-07 Revised:2022-05-08 Online:2022-06-05 Published:2022-06-13
  • Contact: WANG Peican, WANG Baoguo E-mail:bgwang@tsinghua.edu.cn;wangpcleo@foxmail.com

Abstract:

Hydrogen energy, as a strategic emerging industry, is an essential part of the future national energy system and decarbonization energy carrier for end users. Hydrogen generation via water electrolysis benefits large-scale renewable energy consumption and the national energy structure transformation. To fulfill the need for large-scale, highly efficient, and long-life water electrolyzers, integrating interfacial engineering concepts and manufacturing methods to enhance nanotechnology industrialization is crucial. Based on interfacial engineering principles, this review summarizes recent progress on self-supported electrodes, with a focus on improving the stability of the electrode structure and electrocatalytic activity, and examines the influence of microstructure on catalytic performance, particularly at three key interfaces (catalytic sites/substrate interface, interface among catalysts, and electrode/electrolyte interface). Moreover, we discuss strategies for developing self-supported catalytic electrodes with high activity and stability.

Key words: oxygen evolution reaction (OER), hydrogen evolution reaction (HER), interfacial engineering, electrocatalysts, water electrolysis

CLC Number: