储能科学与技术 ›› 2016, Vol. 5 ›› Issue (4): 430-435.doi: 10.12028/j.issn.2095-4239.2016.04.005

• 研究及进展 • 上一篇    下一篇

单质磷复合材料在二次电池中的应用研究进展

周朝辉1,王  莉2,李建刚1,何向明2   

  1. 1北京石油化工学院,北京 102617;2清华大学核能与新能源技术研究院,北京 100084
  • 收稿日期:2015-11-17 修回日期:2016-01-04 出版日期:2016-07-01 发布日期:2016-07-01
  • 通讯作者: 李建刚,男,教授,研究方向为锂离子电池、燃料电池等新型能源材料的制备与性能,E-mail:lijiangang@bipt.edu.cn。
  • 作者简介:周朝辉(1990—),男,硕士研究生,研究方向为单质磷复合材料的制备及其负极极片工艺研究,E-mail:zhaohui902@163.com

Recent advances of elemental phosphorus composite as anode materials for secondary batteries

ZHOU Zhaohui1, WANG Li2, LI Jiangang1, HE Xiangming2   

  1. 1Beijing Institute of Petrochemical Technology, Beijing 102617, China; 2Institute of Nuclear & New Energy Technology, Tsinghua University, Beijing 100084, China
  • Received:2015-11-17 Revised:2016-01-04 Online:2016-07-01 Published:2016-07-01

摘要:

单质磷复合材料作为二次电池的新型负极,具有比容量高、热稳定性好等特点,近年来受到越来越多的关注。本文介绍了红磷、黑磷和蓝磷的单质磷复合材料的电化学性能,综述了单质磷复合材料的制备方法及其在锂离子电池和钠离子电池上的应用,对电化学性能及存在的问题进行了分析。总结了目前单质磷复合材料的研究情况,认为应当从材料的制备方法及改性等问题来进行探索和突破。

关键词: 单质磷, 二次电池, 制备及应用

Abstract:

As high capacity and thermal stable anode materials, elemental phosphorus composites have been showing more and more interests for secondary batteries. This paper has reviewed the preparation of the composite materials of elemental phosphorus and the application in the lithium-ion battery and sodium-ion batterie, and analyzed the electrochemical properties and its problems. Study on the composite of elemental phosphorus should be pay attention to explore and surmount such questions that the preparation methods and modified materials.

Key words: elemental phosphorus, secondary battery, preparation and application