基于化学吸/脱附固态储氢的PEMFC动力系统耦合特性研究

doi:10.19799/j.cnki.2095-4239.2019.0152

储能科学与技术 ›› 2020, Vol. 9 ›› Issue (1): 152-161.doi: 10.19799/j.cnki.2095-4239.2019.0152

基于化学吸/脱附固态储氢的PEMFC动力系统耦合特性研究

闫红丽¹, 敬志良¹, 陆佐伟¹, 王玉琪², 吴震³()

1. 西安交通大学城市学院机械工程系，陕西西安 710018
2. 西北大学化工学院，陕西西安 710069
3. 西安交通大学化学工程与技术学院，陕西西安 710049

收稿日期:2019-07-04 修回日期:2019-07-22 出版日期:2020-01-05 发布日期:2020-01-10
作者简介:吴震，副教授，研究方向为氢能系统，E-mail：wuz2015@mail.xjtu.edu.cn。
基金资助:
陕西省自然科学基金项目(2017JQ5059)

Study on coupling characteristics of PEMFC power generation system using chemisorption as solid-state hydrogen storage

YAN Hongli¹, JING Zhiliang¹, LU Zuowei¹, WANG Yuqi², WU Zhen³()

1. Department of Mechanical Engineering, Xi 'an Jiaotong University City College, Xi 'an 710018, Shaanxi, China
2. School of Chemical Engineering, Northwest University, Xi'an 710069, Shaanxi, China
3. School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China

Received:2019-07-04 Revised:2019-07-22 Online:2020-01-05 Published:2020-01-10

摘要/Abstract

摘要：

基于氢燃料电池PEMFC的动力系统清洁高效，PEMFC动力系统主要由燃料供应系统和PEMFC两大部分组成。高效、安全以及经济的储氢技术仍是制约其规模化应用的核心问题。固态储氢具有高储氢量、安全以及可逆性能好的特点，其作为氢源系统，供氢特性影响着PEMFC动力系统的输出特性。本文建立了基于化学吸/脱附固态储氢的氢源反应器和PEMFC的数学模型，并使用MATLAB/SIMULINK软件建立了耦合固态储氢的PEMFC动力系统的仿真模型，详细分析了反应器供氢压力、阴极氧气压力、燃料电池温度、质子交换膜面积等关键操作和设计参数对氢动力系统输出特性的影响。研究结果表明：提高储氢反应器温度可以提高PEMFC供氢压力，进而提高了其输出功率；同时升高PEMFC温度、增大质子交换膜面积和供氧压力都能提高动力系统的输出功率，相应的功率敏感因数为1.81、0.73和0.036。

关键词: 氢燃料电池, 储氢反应器, 数值仿真, 参数优化

Abstract:

The power generation system based on PEMFC has been proven to be clean and efficient, which mainly consists of fuel supply and fuel cell subsystems. High-efficiency, safe and economic hydrogen storage technology is still the crucial factor affecting the large-scale practical applications of the PEMFC power generation system. The solid-state hydrogen storage method by chemisorption has the advantages of high capacity, good safety, and reversibility, thus being widely used as hydrogen sources and generally affecting the output properties of the power system. In this work, the models of the solid-state hydrogen storage reactor based on metal hydride and the PEMFC are established. Besides, the coupling process between the reactor and the fuel cell is modeled by MATLAB/SIMULINK to investigate the coupling characteristics. Based on the model, the effects of the important operating and design parameters, including hydrogen pressure, oxygen pressure, fuel cell temperature, and proton exchange membrane area, on the output performance of the power generation system are investigated. The simulation results show that the elevated temperature of the hydrogen storage reactor facilitates the improvement of power output of the system. This is because that the higher reaction temperature results in the higher hydrogen supply pressure, accordingly enhancing the fuel cell performance. In addition, the output power of the system also increases with the increase of the hydrogen pressure, fuel cell temperature and proton exchange membrane area. The corresponding power sensitivity coefficient of the three parameters is calculated to be 1.81, 0.73, and 0.036, respectively.

Key words: fuel cell, hydrogen storage reactor, numerical simulation, parameter optimization

中图分类号:

TM 911

闫红丽, 敬志良, 陆佐伟, 王玉琪, 吴震. 基于化学吸/脱附固态储氢的PEMFC动力系统耦合特性研究[J]. 储能科学与技术, 2020, 9(1): 152-161.

YAN Hongli, JING Zhiliang, LU Zuowei, WANG Yuqi, WU Zhen. Study on coupling characteristics of PEMFC power generation system using chemisorption as solid-state hydrogen storage[J]. Energy Storage Science and Technology, 2020, 9(1): 152-161.

图/表 1

参考文献 22

1	侯明, 衣宝廉. 燃料电池技术发展现状与展望[J]. 电化学, 2011, 18（1）: 1-13.
	HOU M, YI B L. Progress and perspective of fuel cell technology[J]. Journal of Electrochemistry, 2011, 18（1）: 1-13.
2	何丽, 韩喆, 冯坤, 等. 操作条件对质子交换膜燃料电池电化学阻抗动态行为的影响[J]. 化工进展, 2018, 37（2）: 533-539.
	HE LHAN J, FENG K, et al. Effects of operating conditions on PEMFC dynamic behavior by EIS[J]. Chemical Industry and Engineering Prograss, 2018, 37（2）: 533-539.
3	贾秋红, 韩明, 邓斌. 质子交换膜燃料电池动态建模及特性分析[J]. 电化学, 2011, 178（4）: 438-443.
	JIA Q H, HAN M, DEN B. Dynamic modeling and characteristic analysis of proton exchange membrane fuel cell[J]. Journal of Electrochemistry, 2011, 178（4）: 438-443.
4	任德鹏, 李青, 彭松. 月面探测器燃料电池应用的初步研究[J]. 深空探测学报, 2017, 4（6）: 552-555.
	REN D P, LI Q, PENG S. Preliminary research on the application of fuel cells on lunar probe[J]. Journal of Deep Space Exploration, 2017, 4（6）: 552-555.
5	王洪建, 程健, 张瑞云, 等. 质子交换膜燃料电池应用现状及分析[J]. 热力发电, 2016, 45（3）: 1-7.
	WANG H J, CHENG J, ZHANG R Y, et al. Development and analysis of proton exchange membrane fuel cell applications[J]. Thermal Power Generation, 2016, 45（3）: 1-7.
6	杨小平, 田景文. 固体储氢材料的研究进展[J]. 化工管理, 2015, 16: 95-97.
	YANG X P, TIAN J W. Research progress on solid hydrogen storage materials[J]. Chemical Management, 2015, 16: 95-97.
7	郭浩, 杨洪海. 固体储氢材料的研究现状及发展趋势[J]. 化工新型材料, 2016, 9: 19-21.
	GUO H, YANG H H. Current status and future prospect of research on solid-state hydrogen storage material[J]. New Chemical Materials, 2016, 9: 19-21.
8	彭赟, 欧阳家俊, 阙海丹. 考虑环境温湿度的空冷PEMFC最佳工作温度研究与控制[J]. 太阳能学报, 2016, 37（6）: 1423-1430.
	PENG Y,YANG J JOU OU, QUE H D. Study and control of optimal operating temperature in air-cooled PEMFC based on certain ambient temperature and humidity[J]. Acta Energiae Solaris Sinica, 2016, 37（6）: 1423-1430.
9	周靖, 张晓维, 谈金祝, 等. 操作参数对PEMFC性能的影响[J]. 南京工业大学学报, 2013, 35（4）: 79-81.
	ZHOU J, ZHANG X W, TAN J Z, et al. Effects of operating parameters on performance of PEMFC[J]. Journal of Nanjing University of Technology, 2013, 35（4）: 79-81.
10	皇甫宜耿, 石麒, 李玉忍. 质子交换膜燃料电池系统建模仿真与控制[J]. 西北工业大学学报, 2015, 33（4）: 682-687.
	HUANGFU Y G, SHI Q, LI Y R. Modelling and simulation system of proton exchange membrane fuel cell[J]. Journal of Northwestern Polytechnical University, 2015, 33（4）: 682-687.
11	尧兢, 朱鹏飞, 任佳伟, 等. 耦合相变储热的金属氢化物反应器吸氢过程模拟[J]. 过程工程学报, 2018, 18（5）: 1093-1101.
	YAO J, ZHU P F, REN J W, et al. Simulation on hydrogen absorption process of metal hydride based hydrogen storage reactor coupled with phase-change thermal storage[J]. The Chinese Journal of Process Engineering, 2018, 18（5）: 1093-1101.
12	KYOUNG S, FEREKH S, GWAK G, et al. Three-dimensional modeling and simulation of hydrogen desorption in metal hydride hydrogen storage vessels[J]. International Journal of Hydrogen Energy, 2015, 40（41）: 14322-14330.
13	付甜甜. 电动汽车用氢燃料电池发展综述[J]. 电源技术, 2017, 41（4）: 651-653.
	FU T T. Development of hydrogen fuel cell for electric vehicle[J]. Chinese Journal of Power Sources, 2017, 41（4）: 651-653.
14	ARVIND S, NAGAR A. A mathematical model for performance of proton exchange membrane fuel cell as a nonlinear voltage processes[J]. International Journal of Advanced Research in Computer Science, 2017, 8（1）: 27-33.
15	MUSIO F, TACCHI F, OMATI L, et al. PEMFC system simulation in MATLAB-simulink environment[J]. International Journal of Hydrogen Energy, 2011, 36: 8045-8052.
16	JEFFERSON M, LUCIANE N, MARCELO G, et al. An electrochemical-based fuel-cell model suitable for electrical engineering automation approach[J]. IEEE Transactions on Industrial Electronics, 2004, 51（5）: 1103-1112.
17	KHAN M, IQBAL M. Modelling and analysis of electro-chemical, thermal, and reactant flow dynamics for a PEM fuel cell system[J]. Fuel Cell, 2010, 5（4）: 463-475.
18	WISHART J, DONG Z, SECANALL M. Optimization of a PEM fuel cell system based on empirical data and a generalized electrochemical semi-empirical model[J]. Journal of Power Sources, 2006, 161（2）: 1041-1055.
19	JUNBOM K, SEONG-MIN L, SUPRAMANIAM S. Modeling of proton exchange membrane fuel cell performance with an empirical equation[J]. Journal of the Electrochemical Society, 1995, 142（8）: 2670-2674.
20	徐腊梅, 肖金生, 潘牧, 等.基于电化学模型的PEM燃料电池建模与仿真[J]. 武汉理工大学学报（交通科学与工程版）, 2008, 32（5）: 933-936.
	XU L M, XIAO J S, PAN M, at el. Modeling and simulation of PEM fuel cell based on electrochemical model[J]. Journal of Wuhan University of Technology （Transportation Science & Engineering）, 2008, 32（5）: 933-936.
21	夏发银, 陈玉, 宾洋.基于SIMULINK的PEM燃料电池系统模型建立及其仿真分析[J]. 宿州学院学报, 2016, 31（1）: 102-105.
	XIA F Y, CHEN Y, BIN Y. Modeling and simulation analysis of PEM fuel cell system based on SIMULINK[J]. Journal of Suzhou University, 2016, 31（1）: 102-105.
22	魏司琪, 姜成果, 王宝玉.提高热机效率的研究和实践[J]. 科技创新导报, 2017, 13: 103-105.
	WEI S Q, JIANG C G, WANG B Y. Research and practice on improving the efficiency of heat engine[J]. Science and Technology Innovation Herald, 2017, 13: 103-105.

[1]	李昂, 李晓蒙, 杨林, 王含, 项俊帆, 刘雨涵. 液流电池封装压力计算[J]. 储能科学与技术, 2022, 11(2): 609-614.
[2]	刘偲艳, 胡毕华. 氢燃料汽车双向DC-DC变换器改进模型预测控制[J]. 储能科学与技术, 2021, 10(6): 2046-2052.

基于化学吸/脱附固态储氢的PEMFC动力系统耦合特性研究

Study on coupling characteristics of PEMFC power generation system using chemisorption as solid-state hydrogen storage

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 1

参考文献 22

相关文章 2

编辑推荐

Metrics

本文评价