储能科学与技术 ›› 2021, Vol. 10 ›› Issue (1): 50-58.doi: 10.19799/j.cnki.2095-4239.2020.0270

• 储能材料与器件 • 上一篇    下一篇

锂离子电池化成技术研究进展

林乙龙(), 肖敏, 韩东梅, 王拴紧, 孟跃中()   

  1. 中山大学低碳化学与过程节能广东省重点实验室,光电材料与技术国家重点实验室,广东 广州 510275
  • 收稿日期:2020-08-18 修回日期:2020-09-10 出版日期:2021-01-05 发布日期:2021-01-08
  • 通讯作者: 孟跃中 E-mail:linylong3@mail2.sysu.edu.cn;mengyzh@mail.sysu.edu.cn
  • 作者简介:林乙龙(1992—),男,博士研究生,主要研究方向为锂离子/锂硫电池化成行为及电解质,E-mail:linylong3@mail2.sysu.edu.cn
  • 基金资助:
    国家自然科学基金项目(51573215)

Research progress in formation technique for LIBs

Yilong LIN(), Min XIAO, Dongmei HAN, Shuanjin WANG, Yuezhong MENG()   

  1. The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou 510275, Guangdong, China
  • Received:2020-08-18 Revised:2020-09-10 Online:2021-01-05 Published:2021-01-08
  • Contact: Yuezhong MENG E-mail:linylong3@mail2.sysu.edu.cn;mengyzh@mail.sysu.edu.cn

摘要:

锂离子电池生产过程中需要进行化成,实现对电极的浸润及对电极材料进行充分激活。同时,在首次充电过程中,随着锂离子在负极的嵌入,电解液成分在负极发生还原反应形成一层稳定的固体电解质界面膜(SEI膜),以防止后续循环过程中电解液和锂离子的不可逆消耗,因此该技术对电池性能的意义非同寻常,化成的效果直接影响锂离子电池的后续性能表现,包括存储性能、循环寿命、倍率性能和安全性等。然而,对于电动汽车电池组中的每个单体电池,都需要耗时几天甚至几星期的化成和老化工序,导致较低的电池生产效率;大量的充放电设备、控温设备和环境空间提高了电池的生产成本;传统的化成方式无法完全满足容量,寿命和安全等高性能需求。目前已有很多研究通过优化锂离子电池化成技术来提高电池性能,降低化成时间,从而降低电池生产成本。本综述针对锂离子化成技术优化展开评述,介绍电池化成的意义、成本分析、各种技术参数和化成方法,并对未来的研究和改进方向进行展望。

关键词: 锂离子电池, 化成技术, 固体电解质界面膜, 生产效率, 生产成本

Abstract:

In the process of LIB production, the formation processes aim at achieving the wetting of the electrodes and the activation of the electrode materials. Meanwhile, during the initial charge, with the insertion of lithium ions, the electrolyte components are reduced in the anode and form a stable solid electrolyte interface film on the anode for preventing the irreversible consumption of the electrolyte and lithium ions in the subsequent cycling. Consequently, these techniques are of great significance for the battery performance; the formation effect directly affects the subsequent performance of LIBs, including storage performance, cycle life, rate performance and safety. However, for each single battery in the battery pack of electric vehicles, it takes days or even weeks to carry out the formation and conditioning processing, resulting in low battery production efficiency. A large amount of charge/discharge equipment, temperature control equipment, and environmental space increases the cost of battery production. The traditional formation method cannot completely meet the requirements of high performance, such as capacity, life, and safety, in LIBs. To date, there have been many studies on improving the battery performance and reducing the formation time and the cost of battery production by optimizing the formation technique of LIBs. This review focuses on the optimization of the lithium-ion formation technique, introducing the significance of battery formation, cost analysis, and various technological parameters and forecasting the future research and improvement directions.

Key words: lithium ion batteries, formation technique, SEI films, production efficiency, cost of production

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