储能科学与技术 ›› 2023, Vol. 12 ›› Issue (9): 2971-2984.doi: 10.19799/j.cnki.2095-4239.2023.0305

• 储能测试与评价 • 上一篇    下一篇

原位表征技术在水系有机液流电池中的研究进展

张永辉1,2(), 傅杰1, 李先锋2(), 张长昆2()   

  1. 1.大连交通大学环境与化学工程学院,辽宁 大连 116028
    2.中国科学院大连化学物理研究所,辽宁 大连 116023
  • 收稿日期:2023-05-04 修回日期:2023-06-02 出版日期:2023-09-05 发布日期:2023-09-16
  • 通讯作者: 李先锋,张长昆 E-mail:zhangyonghui@dicp.ac.cn;lixianfeng@dicp.ac.cn;zhangchk17@dicp.ac.cn
  • 作者简介:张永辉(1998—),男,硕士研究生,研究方向为水系有机液流电池,E-mail:zhangyonghui@dicp.ac.cn
  • 基金资助:
    国家重点研发计划(2022YFB2405000);国家自然科学基金面上项目(22279133)

Research progress on in-situ characterization techniques for aqueous organic flow batteries

Yonghui ZHANG1,2(), Jie FU1, Xianfeng LI2(), Changkun ZHANG2()   

  1. 1.College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning, China
    2.Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China
  • Received:2023-05-04 Revised:2023-06-02 Online:2023-09-05 Published:2023-09-16
  • Contact: Xianfeng LI, Changkun ZHANG E-mail:zhangyonghui@dicp.ac.cn;lixianfeng@dicp.ac.cn;zhangchk17@dicp.ac.cn

摘要:

水系有机液流电池因活性分子结构和性质可调,低成本等潜在的优势近些年来受到研究者的广泛关注。水系有机液流电池面临着活性分子种类繁多,分子的电化学反应机理不明确,且分子的稳定性较差、副反应较多等问题。原位表征技术特别是原位谱学技术对解析水系有机液流电池中有机活性分子的电化学反应过程、机理以及优化电池的内部结构至关重要。本文综述了近些年来水系有机液流电池中原位谱学表征技术的研究进展,着重介绍了原位核磁共振波谱对于分子在电化学反应过程中结构演变的揭示作用、红外光谱原位表征分子与水的分子间氢键作用和电池充放电过程中分子结构变化、原位紫外光谱观测分子信号的周期性变化来确定其分子电化学反应的稳定性以及利用原位电子顺磁共振波谱来确定自由基浓度和反应速率常数等一系列原位光谱应用技术。另外,通过多种原位表征手段的联用,有望实现功能互补,从而更全面深入地了解电池的电化学反应机理、电池运行状态以及活性物质在电极表面的反应过程。

关键词: 原位表征技术, 谱学, 水系有机液流电池

Abstract:

Aqueous organic flow batteries have attracted more and more attention from researchers in recent years. This is due to their potential advantages, such as low cost and adjustable active molecular structure and properties. However, aqueous organic flow batteries face a wide variety of active molecules, unclear electrochemical reaction mechanisms, poor stability, and many side reactions of the molecules. In-situ characterization techniques, especially in-situ spectroscopy techniques, are essential for analyzing the electrochemical reaction processes and mechanisms of organic active molecules and optimizing the battery's internal structure. This paper reviews the research progress of a series of in-situ spectroscopy characterization techniques in aqueous organic flow batteries in recent years, focusing on the role of in-situ nuclear magnetic resonance spectroscopy in revealing the structural evolution of molecules during electrochemical reactions. The in-situ infrared spectroscopy characterizes the intermolecular hydrogen bonding between molecules and water, and the molecular structure changes during charging and discharging. The periodic changes of molecular signals in the in-situ ultraviolet spectroscopy can determine the stability of molecular electrochemical reactions, and in-situ electron paramagnetic resonance spectroscopy is used to calculate the free radical concentrations and reaction rate constants. In addition, combining several in-situ characterization methods is expected to achieve functional complementarity to gain a more comprehensive understanding of the battery's electrochemical reaction mechanism, the battery's operating state, and the reaction process of the active material on the electrode surface. Finally, we hope that the in-situ spectroscopy characterization techniques introduced in this article can provide valuable insights for researching aqueous organic flow batteries and further promote the development and application of battery technology.

Key words: in-situ characterization technique, spectroscopy, aqueous organic flow batteries

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