超级电容器百篇论文点评（2015.11.1—2016.2.2）

doi:10.3969/j.issn.2095-4239.2016.03.015

摘要/Abstract

摘要：

该文是一篇近四个月的超级电容器文献评述，我们以“supercapacitor”为关键词检索了Web of Science从2015年11月1日至2016年2月29日上线的超级电容器研究论文，共有830篇，选取了其中100篇加以评论。双电层超级电容器主要研究了新型多孔碳材料、石墨烯等材料可控制备对其性能的影响。赝电容超级电容器的研究主要集中在金属氧化物复合材料、导电聚合物复合材料、杂质原子掺杂碳材料和新型赝电容材料等4个方面。混合型超级电容器包括水系混合型超级电容器和有机系混合型超级电容器两个方面的研究。

关键词: 超级电容器, 双电层超级电容器, 赝电容超级电容器, 混合型超级电容器

Abstract:

This four months review paper highlights 100 recent published papers on supercapacitors. We searched the Web of Science and found 830 papers online from November 1, 2015 to February 29, 2016. 100 of them were selected to be highlighted. The researches of electrical double-layer capacitor (EDLC) are mainly focused on new carbon material designed preparation, such as porous carbon materials, graphene, and their effect on supercapacitor performance. The published papers of pseudocapacitor include four aspects, such as metal oxide composites, conductive polymer composite, heteroatom doping carbon materials and new type of pseudocapactive materials. Hybrid supercapacitor includes aqueous hybrid supercapacitor and organic hybrid supercapacitor.

Key words: supercapacitors, electrical double-layer capacitors, pseudocapacitors, hybrid supercapacitors

郑超，周洲，李林艳，陈雪丹，刘秋香，陈宽，黄益，乔志军，傅冠生，阮殿波. 超级电容器百篇论文点评（2015.11.1—2016.2.2）[J]. 储能科学与技术, 2016, 5(3): 367-383.

ZHENG Chao, ZHOU Zhou, LI Linyan, CHEN Xuedan, LIU Qiuxiang, CHEN Kuan, HUANG Yi, QIAO Zhijun, FU Guansheng, RUAN Dianbo.

Review of selected 100 recent papers for supercapacitors（Nov. 1, 2015 to Feb. 29, 2016）

[J]. Energy Storage Science and Technology, 2016, 5(3): 367-383.

参考文献

[1] DYATKIN B，GOGOTSI O，MALINOVSKIY B，et al. High capacitance of coarse-grained carbide derived carbon electrodes[J]. Journal of Power Sources，2016，306：32-41.

[2] KIM M H，KIM K B，PARK S M，et al. Hierarchically structured activated carbon for ultracapacitors[J]. Scientific Reports，2016，6：21182-21187.

[3] ZHENG K W，FAN X R，MAO Y Z，et al. The well-designed hierarchical structure of musa basjoo for supercapacitors[J]. Scientific Reports，2016，6：20306-20311.

[4] CHENG P，LI T，YU H，et al. Biomass-derived carbon fiber aerogel as a binder-free electrode for high-rate supercapacitors[J]. Journal of Physical Chemistry，2016，120：2079-2086.

[5] GALHENA D T L，BAYER B C，HOFMANN S，et al. Nanometer pores by in situ tuning of interlayer constrictions[J]. ACS Nano，2016，10：747-754.

[6] CHEN G X，WU S L，HUI L W，et al. Assembling carbon quantum dots to a layered carbon for high-density supercapacitor electrodes[J]. Scientific Reports，2016，6：19028-19036.

[7] JIANG W C，ZHAI S L，QIAN Q H，et al. Space-confined assembly of all-carbon hybrid fibers for capacitive energy storage：Realizing a built-to-order concept for micro-supercapacitors[J]. Energy & Environmental Science，2016，9：611-622.

[8] WANG X H，ZHOU H T，SHERIDAN E，et al. Geometrically confined favourable ion packing for high gravimetric capacitance in carbon-ionic liquid supercapacitors[J]. Energy & Environmental Science，2016，9：232-239.

[9] LONG C L，JIANG L L，WU X L，et al. Facile synthesis of functionalized porous carbon with three-dimensional interconnected pore structure for high volumetric performance supercapacitors[J]. Carbon，2015，93：412-420.

[10] CHENG P，GAO S Y，ZANG P Y，et al. Hierarchically porous carbon by activation of shiitake mushroom for capacitive energy storage[J]. Carbon，2015，93：315-324.

[11] ZHANG H T，ZHANG X，MA Y W，et al. Enhanced capacitance supercapacitor electrodes from porous carbons with high mesoporous volume[J]. Electrochimica Acta，2015，184：347-355.

[12] FERRERO G A，FUERTES A B，SEVILLA M，et al. From soybean residue to advanced supercapacitors[J]. Scientific Reports，2015，5：16618.

[13] ZHENG S S，JU H，LU X，et al. A high-performance supercapacitor based on KOH activated 1DC-70 microstructures[J]. Advanced Energy Materials，2015，5（22）：1500871.

[14] ARIYANTO T，DYATKIN B，ZHANG G R，et al. Synthesis of carbon core-shell pore structures and their performance as supercapacitors[J]. Microporous and Mesoporous Materials，2015，218：130-136.

[15] ZHANG Y Q，JIA M M，GAO H Y，et al. Porous hollow carbon spheres：Facile fabrication and excellent supercapacitive properties[J]. Electrochimica Acta，2015，184：32-39.

[16] YANG J，ZHANG E，LI X，et al. Direct reduction of graphene oxide by Ni foam as a high-capacitance supercapacitor electrode[J]. ACS Applied Materials & Interfaces，2016，8（3）：2297-2305.

[17] LEE Y，CHOI H，KIM M S，et al. Nanoparticle-mediated physical exfoliation of aqueous-phase graphene for fabrication of three-dimensionally structured hybrid electrodes[J]. Scientific Reports，2016，6：19822.

[18] ZHAN H，GARRETT D J，APOLLO N V，et al. Direct fabrication of 3D graphene on nanoporous anodic alumina by plasma-enhanced chemical vapor deposition[J]. Scientific Reports，2016，6：19822.

[19] CHEN L，LIU Y，ZHAO Y，et al. Graphene-based fibers for supercapacitor applications[J]. Nanotechnology，2015，27（3），doi: 10.1088/0957-4484/27/3/032001.

[20] ZHANG S，LI Y，SONG H，et al. Graphene quantum dots as the electrolyte for solid state supercapacitors[J]. Scientific Reports，2016，6：19292.

[21] LIM J，NARAYAN M U，KIM N Y，et al. Dopant-specific unzipping of carbon nanotubes for intact crystalline graphene nanostructures[J]. Nature Communications，2016，7：10364-10372.

[22] YUN J，LIM Y，JANG G N，et al. Stretchable patterned graphene gas sensor driven by integrated micro-supercapacitor array[J]. Nano Energy，2015，19：401-414.

[23] SHA J，GAO C，LEE S K，et al. Preparation of three-dimensional graphene foams using powder metallurgy templates[J]. ACS Nano，2016，10 （1）：1411-1416.

[24] XU P，KANG J，SUHR J，et al. Spatial strain variation of graphene films for stretchable electrodes[J]. Carbon，2015，93：620-624.

[25] HAO J，LIAO Y，ZHONG Y，et al. Three-dimensional graphene layers prepared by a gas-foaming method for supercapacitor applications[J]. Carbon，2015，94：879-887.

[26] YUAN K，XU Y，JOHANNES U，et al. Straightforward generation of pillared, microporous graphene frameworks for use in supercapacitors[J]. Advanced Materials，2015，27 （42）：6714-6721.

[27] GU X Y，HU M，DU Z S. Fabrication of mesoporous graphene electrodes with enhanced capacitive deionization[J]. Electrochimica Acta，2015，182：183-191.

[28] HAN J，KIM W，KIM H K，et al. Longitudinal unzipped carbon nanotubes with high specific surface area and trimodal pore structure[J]. RSC Advances，2016，6：8661-8668.

[29] YU W，LI B Q，DING S J. Electroless fabrication and supercapacitor performance of CNT@NiO-nanosheet composite nanotubes[J]. Nanotechnology，2016，27：75605-75612.

[30] LIU X Y，GAO Y Q，WANG G W. Flexible, transparent and super-long-life supercapacitor based on ultrafine Co₃O₄ nanocrystal electodes[J]. Nanoscale，2016，7：4227-4235.

[31] PHATTHARASUPAKUN N，WUTTHIPROM J，CHIOCHAN P，et al. Turning conductive carbon nanospheres into nanosheets for high-performance supercapacitors of MnO₂nanrods[J]. Chemical Communications，2016，52：2585-2588.

[32] YIN X S，TANG C H，ZHANG L Y. Chemical insights into the roles of nanowire cores on the growth and supercapacitor performances of Ni-Co-O/Ni(OH)₂core/shell electrodes[J]. Scientific Reports，2016，6：21566.

[33] CHEN Y H，ZHOU J F，PIERCE M，et al. Enhancing capacitance behaviour of CoOOH nanostructures using transition metal dopants by ambient oxidation[J]. Scientific Reports，2016，6：20704-20711.

[34] ZHENG Y C，LIA Z Q，XU J，et al. Multi-channeled hierarchical porous carbon incorporated Co₃O₄ nanopillar arrays as 3D binder-free electrode for high performance supercapacitors[J]. Nano Energy，2016，20：94-107.

[35] PEI Z X，ZHU M S，HUANG Y，et al. Dramatically improved energy conversion and storage efficiencies by simultaneously enhancing charge transfer and creating active sites in MnO_x/TiO₂ nanotube composite electrodesh[J]. Nano Energy，2016，20：254-263.

[36] REN Z H，LI J P，REN Y Q，et al. Large-scale synthesis of hybrid metal oxides through metal redox mechanism for high-performance pseudo capacitors[J]. Scientific Reports，2016，doi:10.1038/srep20021.

[37] WEI W，WANG Y C，WU H. Transition metal oxide hierarchical nanotubes for energy applications[J]. Nanotechnology，2016，27（2）：02LT01.

[38] LV Q Y，WANG S，SUN H Y. Solid-state thin-film supercapacitors with ultrafast charge/discharge based on N-doped-carbon-tubes/ Au-nanoparticles-doped-MnO₂nanocomposites[J]. Nano Letters，2016，16：40-47.

[39] ZHU G Y，CHEN J，ZHANG Z Q，et al. NiO nanowall-assisted growth of thick carbon nanofiber layers on metal wires for fiber supercapacitors[J]. Chemical Communications，2016，13（52）：2721-2724.

[40] KO W Y，CHEN Y F，LU K M，et al. Porous honeycomb structures formed from interconnected MnO₂ sheets on CNT-coated substrates for flexible all-solid-state supercapacitors[J]. Scientific Reports，2016，6：18887-18893.

[41] NAGARAJU G，RAJU G S R，KO Y H，et al. Hierarchical Ni-Co layered double hydroxide nanosheets entrapped on conductive textile fibers：A cost-effective and flexible electrode for high-performance pseudocapacitors[J]. Nanoscale，2016，8（2）：812-825.

[42] LONG C，ZHENG M T，XIAO Y，et al. Amorphous Ni-Co binary oxide with hierarchical porous structure for electrochemical capacitors[J]. ACS Applied Materials & Interfaces，2015，7（44）：24419-24429.

[43] CHEN Y，QIN W Q，FAN R J，et al. Hydrothermal synthesis and electrochemical properties of spherical alpha-MnO₂ for supercapacitors[J]. Journal of Nanoscience and Nanotechnology，2015，15（12）：9760-9765.

[44] WANG H J，ZHOU D，LI G H，et al. Facile fabrication of cobalt oxide nanoflowers on Ni foam with excellent electrochemical capacitive performance[J]. Journal of Nanoscience and Nanotechnology，2015，15（12）：9754-9759.

[45] SUN S J，ZHAO X Y，YANG M，et al. Facile and eco-friendly synthesis of finger-like Co₃O₄ nanorods for electrochemical energy storage[J]. Nanomaterials，2015，5（4）：2335-2347.

[46] BALASUBRAMANIAN S，PURUSHOTHAMAN K K. Carbon coated flowery V₂O₅ nanostructure as novel electrode material for high performance supercapacitors[J]. Electrochemical Acta，2015，186：285-291.

[47] CHENG J，ZHAO B，ZHANG W K，et al. High-performance supercapacitor applications of NiO-nanoparticle-decorated millimeter-long vertically aligned carbon nanotube arrays via an effective supercritical CO₂-assisted method[J]. Advanced Functional Materials，2015，25（47）：7381-7391.

[48] ZHOU K，ZHOU W J，YANG L J，et al. Ultrahigh-performance pseudocapacitor electrodes based on transition metal phosphide nanosheets array via phosphorization：A general and effective approach[J]. Advanced Functional Materials，2015，25（48）：7530-7538.

[49] BOOTA M，ANASORI B，VOIGT C，et al. Pseudocapacitive electrodes produced by oxidant-free polymerization of pyrrole between the layers of 2D titanium carbide (MXene)[J]. Advanced Materials，2016，28：1517-1522.

[50] WANG Y，TANG S，VONGEHR S，et al. High-performance flexible solid-state carbon cloth supercapacitors based on highly processible N-graphene doped polyacrylic acid/polyaniline composites[J]. Scientific Reports，2016，6：12883.

[51] GAWLI Y，BANERJEE A，DHAKRAS D，et al. 3D polyaniline architecture by concurrent inorganic and organic acid doping for superior and robust high rate supercapacitor performance[J]. Scientific reports，2016，6.

[52] HU N，ZHANG L，YANG C，et al. Three-dimensional skeleton networks of graphene wrapped polyaniline nanofibers：An excellent structure for high-performance flexible solid-state supercapacitors[J]. Scientific Reports，2016，6：19777.

[53] KASHANI H，CHEN L，ITO Y，et al. Bicontinuous nanotubular graphene-polypyrrole hybrid for high performance flexible supercapacitors[J]. Nano Energy，2016，19：391-400.

[54] JEON J W，KWON S R，LI F，et al. Spray-on polyaniline/poly (acrylic acid) electrodes with enhanced electrochemical stability[J]. ACS Applied Materials & Interfaces，2015，7（43）：24150-24158.

[55] BOOTA M，PARANTHAMAN M P，NASKAR A K，et al. Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life[J]. Chem. Sus. Chem.，2015，8（21）：3576-3581.

[56] YUAN K，GUO-WANG P，HU T，et al. Nanofibrous and graphene-templated conjugated microporous polymer materials for flexible chemosensors and supercapacitors[J]. Chemistry of Materials，2015，27（21）：7403-7411.

[57] LIU Y，WENG B，RAZAL J M，et al. High-performance flexible all-solid-state supercapacitor from large free-standing graphene-PEDOT/PSS films[J]. Scientific reports，2015，5：17045.

[58] XU Y，TAO Y，ZHENG X，et al. A Metal-free supercapacitor electrode material with a record high volumetric capacitance over 800 F/cm³[J]. Advanced Materials，2015，27（48）：8082-8087.

[59] HUANG Z H，SONG Y，XU X X，et al. Ordered polypyrrole nanowire arrays grown on a carbon cloth substrate for a high-performance pseudocapacitor electrode[J]. ACS Applied Materials & Interfaces，2015，7（45）：25506-25513.

[60] WANG K，ZHANG X，LI C，et al. Chemically crosslinked hydrogel film leads to integrated flexible supercapacitors with superior performance[J]. Advanced Materials，2015，27（45）：7451-7457.

[61] JO K，GU M，KIM B S. Ultrathin supercapacitor electrode based on reduced graphene oxide nanosheets assembled with photo-cross-linkable polymer：Conversion of electrochemical kinetics in ultrathin films[J]. Chemistry of Materials，2015，27（23）：7982-7989.

[62] LOEBLEIN M，BOLKER A，TSANG S H，et al. 3D graphene-Infused polyimide with enhanced electrothermal performance for long-term flexible space applications[J]. Small，2015，11（48）：6425-6434.

[63] LIU R L，PAN L X，JIANG J Z，et al. Nitrogen-doped carbon microfiber with wrinkled surface for high performance supercapacitors[J]. Scientific Reports，2016，6：21750-21750.

[64] ZHANG L L，LI H H，SHI Y H. A novel layered sedimentary rocks structure of the oxygen-enriched carbon for ultrahigh-rate-performance supercapacitors[J]. ACS Applied Materials & Interfaces，2016，8：4233-4241.

[65] WAN M M，SUN X D，LI Y Y，et al. Facilely fabricating multifunctional N-enriched carbon[J]. ACS Applied Materials & Interfaces，2016，8：1252-1263.

[66] LING Z，WANG Z Y，ZHANG M D，et al. Sustainable synthesis and assembly of biomass-derived B/N co-doped carbon nanosheets with ultrahigh aspect ratio for high-performance supercapacitors[J]. Advanced Functional Materials，2016，26：111-119.

[67] LIU B Z，ZHANG L L，QI P R，et al. Nitrogen-doped banana peel-derived porous carbon foam as binder-free electrode for supercapacitors[J]. Nanomaterials，2016，6：1-18.

[68] SONG L T，WU Z Y，LIANG H W，et al. Macroscopic-scale synthesis of nitrogen-doped carbon nanofiber aerogels by template-directed hydrothermal carbonization of nitrogen-containing carbohydrates[J]. Nano Energy，2016，19：117-127.

[69] LI Y J，WANG G L，WEI T，et al. Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors[J]. Nano Energy，2016，19：165-175.

[70] LI B，DAI F，XIAO Q F. Nitrogen-doped activated carbon for a high energy hybrid supercapacitor[J]. Energy& Environmental Science，2016，9：102-106.

[71] WU X Z，ZHOU J，XING W，et al. Insight into high areal capacitances of low apparent surface area carbons derived from nitrogen-rich polymers[J]. Carbon，2015，94：560-567.

[72] LIANG Q H，YE L，XU Q，et al. Graphitic carbon nitride nanosheet-assisted preparation of N-enriched mesoporous carbon nanofibers with improved capacitive performance[J]. Carbon，2015，94：342-348.

[73] LI J，LIU K，GAO X. Oxygen-and nitrogen-enriched 3D porous carbon for supercapacitors of high volumetric capacity[J]. ACS Applied Materials & Interfaces，2015，7：24622-24628.

[74] XIE B Q，CHEN Y，YU M Y，et al. Carboxyl-assisted synthesis of nitrogen-doped graphene sheets for supercapacitor applications[J]. Nanoscale Research Letters，2015，10（1）：1031.

[75] KUMAR N A，BAEK J B. Doped graphene supercapacitors[J]. Nanotechnology，2015，26（49）：492001.

[76] LIN T Q，CHEN I W，LIU F X，et al. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage[J]. Science，2015，350：1508-1513.

[77] MADAGONDA V M，SAGAR B C，SANDIP P K，et al. Contact angle measurements：A preliminary diagnostic tool for evaluating the performance of ZnFe₂O₄ nano-flake based supercapacitors[J]. Chemical Communications，2016，52（12）：2557-2560.

[78] TANG J H，GE Y C，SHEN J F，et al. Facile synthesis of CuCo₂S₄ as a novel electrode material for ultrahigh supercapacitor performance[J]. Chemical Communications，2016，52（7）：1509-1512.

[79] WANG X L，XIA X J，BEKA L G，et al. In situ growth of urchin-like NiCo₂S₄ hexagonal pyramid microstructures on 3D graphene nickel foam for enhanced performance of supercapacitors[J]. RSC Advances，2016，6（12）：9446-9452.

[80] DAI S G，XU W N，XI Y，et al. Charge storage in KCu₇S₄ as redox active material for a flexible all-solid-state supercapacitor[J]. Nano Energy，2016，19：363-372.

[81] MA L，ZHOU X P，XU L M，et al. Microwave-assisted hydrothermal preparation of SnO₂/MoS₂ composites and their electrochemical performance[J]. Nano：Brief and Reviews，2016，11（2）：87-94.

[82] LI L Q，YANG H B，YANG J，et al. Hierarchical carbon@Ni₃S₂

@MoS₂ double core-shell nanorods for high-performance supercapacitors[J]. Electrochimica Acta，2016，4（4）：1319-1325.

[83] YANG Q，LIN S Y. Rationally designed nanosheet-based CoMoO₄-NiMoO₄ nanotubes for high-performance electrochemical electrodes[J]. RSC Advances，2016，6（13）：10520-10526.

[84] ZHU Y R，JI X B，WU Z B，et al. NiCo₂S₄ hollow microsphere decorated by acetylene black for high-performance asymmetric supercapacitor[J]. Electrochimica Acta，2015，186：562-571.

[85] LIU Y S，LI J，LI W Z，et al. Nitrogen-doped graphene aerogel-supported spinel CoMn₂O₄ nanoparticles as an efficient catalyst for oxygen reduction reaction[J]. Journal of Power Sources，2015，299：492-500.

[86] ZHU Y X，CHEN J，ZHAO N N，et al. Large-scale synthesis of uniform NiCo₂O₄ nanoparticles with supercapacitive properties[J]. Materials Letters，2015，160：171-174.

[87] JAGADALE A D，GUAN G Q，LI X M. Ultrathin nanoflakes of cobalt-manganese layered double hydroxide with high reversibility for asymmetric supercapacitor[J]. Journal of Power Sources，2016，306（29）：526-534.

[88] SUNDARAM M M，BISWAL A，MITCHELL D，et al. Correlation among physical and electrochemical behaviour of nanostructured electrolytic manganese dioxide from leach liquor and synthetic for aqueous asymmetric capacitor[J]. Physical Chemistry Chemical Physics，2016，18（6）：4711-4720.

[89] KIM S K，CHO J，MOORE J S，et al. High-performance mesostructured organic hybrid pseudocapacitor electrodes[J]. Advanced Functional Materials，2016，26（6）：903-910.

[90] LI T，LI G H，LI L H，et al. Large-scale self-assembly of 3D flower-like hierarchical Ni/Co-LDHs microspheres for high-performance flexible asymmetric supercapacitors[J]. ACS Applied Materials & Interfaces，2016，8（4）：2562-2572.

[91] MAHMOOD A，ZOU R Q，WANG Q F，et al. Nanostructured electrode materials derived from metal-organic framework xerogels for high-energy-density asymmetric supercapacitor[J]. ACS Applied Materials & Interfaces，2016，8（3）：2148-2157.

[92] ZHANG L C，ZHU P L，ZHOU F G，et al. Flexible asymmetrical solid-state supercapacitors based on laboratory filter paper[J]. ACS Nano，2016，10（1）：1273-1282.

[93] YU N，YIN H，ZHANG W，et al. High-performance fiber-shaped all-solid-state asymmetric supercapacitors based on ultrathin MnO₂ nanosheet/carbon fiber cathodes for wearable electronics[J]. Advanced Energy Materials，2016，6（2）：1501458.

[94] PENG H，MA G F，SUN K J，et al. A novel aqueous asymmetric supercapacitor based on petal-like cobalt selenide nanosheets and nitrogen-doped porous carbon networks electrodes[J]. Journal of Power Sources，2015，297：351-358.

[95] HU Y T，GUAN C，FENG G X，et al. Flexible asymmetric supercapacitor based on structure-optimized Mn₃O₄/reduced graphene oxide nanohybrid paper with high energy and power density[J]. Adavanced Functional Materials，2015，25（47）：7291-7299.

[96] SATISH R，ARAVINDAN V，LING W C，et al. Macroporous carbon from human hair：A journey towards the fabrication of high energy Li-ion capacitors[J]. Electrochimica Acta，2015，182：474-481.

[97] DONG S Y，WANG X Y，SHEN L F，et al. Trivalent Ti self-doped Li₄Ti₅O₁₂：A high performance anode material for lithium-ion capacitors[J]. Journal of Electroanalytical Chemistry，2015，757：1-7.

[98] ZHAO L W，LI H L，LI M J，et al. Lithium-ion storage capacitors achieved by CVD graphene/TaC/Ta-wires and carbon hollow spheres[J]. Applied Energy，2016，162：197-206.

[99] SUNDARAM M M，WATCHARATHARAPONG T，CHAKRABORTY S，et al. Synthesis, and electronic structure of sodium metal phosphate for use as a hybridcapacitor in non-aqueous electrolyte[J]. Dalton Transactions，2015，44（46）：20108-20120.

[100] HAO C L，WANG X F，YIN Y J，et al. Modeling and simulation of a lithium manganese oxide/activated carbon asymmetric supercapacitor[J]. Journal of Electronic Materials，2016，45（1）：515-526.