储能科学与技术 ›› 2017, Vol. 6 ›› Issue (4): 633-643.doi: 10.12028/j.issn.2095-4239.2017.0071

• 相变储能专刊 • 上一篇    下一篇

纳米相变胶囊的制备、表征与传热强化研究进展

方  昕1,3,汪明军2,张晓龙1,吕洪坤1,俞自涛3   

  1. 1国网浙江省电力公司电力科学研究院,浙江 杭州 310014;2杭州意能电力技术有限公司,浙江 杭州 310014;
    3浙江大学热工与动力系统研究所,浙江 杭州 310027
  • 收稿日期:2017-05-24 修回日期:2017-06-01 出版日期:2017-07-01 发布日期:2017-06-05
  • 基金资助:
    浙江省自然科学基金(LY16E060002)项目。

Progress of preparation, characterization and heat transfer enhancement of nano-encapsulated phase change materials (NEPCM)

FANG Xin1, WANG Mingjun2, ZHANG Xiaolong1, LV Hongkun1, YU Zitao3   

  1. 1Zhejiang Electric Power Corporation Research Institute, Hangzhou 310014, Zhejiang, China; 2Hangzhou Yineng Power Technology Corporation Limited, Hangzhou 310014, Zhejiang, China; 3Institute of Thermal Science and Power Systems, Zhejiang University, Hangzhou 310027, Zhejiang, China
  • Received:2017-05-24 Revised:2017-06-01 Online:2017-07-01 Published:2017-06-05
  • Contact: 方昕(1988—),男,博士,从事强化传热、相变储能研究,E-mail:fwx918@gmail.com。

摘要: 作为一种新型的蓄热材料,纳米相变胶囊能够解决热量供求时间、空间和强度上的不匹配,在余热回收、太阳能热利用、电子器件热管理等多个领域具有广阔的应用前景。从样品制备、物性表征以及传热强化3个方面,对纳米相变胶囊最新的研究成果进行了总结。介绍了常见的纳米相变胶囊制备方法及对形貌、尺寸的影响,比较了各种方法的优劣。物性表征的结果显示,胶囊化的方式可以有效防止相变材料发生泄露,获得更好的热稳定性。纳米相变胶囊显著提升了相变材料的导热系数、降低了相变材料的过冷度,同时也没有造成相变乳液的黏度出现大幅度提高。此外,实验和数值模拟的结果都表明纳米相变胶囊能够有效提升工质的传热  性能。

关键词: 纳米胶囊, 热存储, 相变材料, 相变乳液, 强化传热

Abstract:  Nano-encapsulated phase change materials (NEPCM) have the potential to address the intermittent and less predictable nature of renewable energy resources. Other applications of the NEPCM include waste heat utilization, energy-saving buildings and thermal management of electronics. This paper introduces the latest research in NECPM preparation, characterization and heat transfer enhancement. The influence of preparation method on particle size and morphology of NEPCM are discussed. The characterization results show nanoencapsulation is able to effectively prevent the leakage of PCM and achieve an excellent thermal stability of PCM emulsions. In addition, the use of NEPCM could also effectively alleviate the rapid increase in the viscosity of PCM emulsions, and improve the thermal conductivity while reduce the subcooling degree of PCMs. Furthermore, both numerical and experimental studies have shown the benefit of NEPCM for heat transfer enhancement.

Key words: nanocapsule, thermal energy storage, PCM, PCM emulsion, heat transfer enhancement