Energy Storage Science and Technology ›› 2018, Vol. 7 ›› Issue (4): 692-697.doi: 10.12028/j.issn.2095-4239.2018.0072

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Preparation and thermal property of a tetradecane-octanoic acid eutectic phase change material

ZHOU Sunxi1,2, ZHANG Xuelai1, LIU Sheng2   

  1. 1. Cool Storage Technology Institute, Shanghai Maritime University, Shanghai 201306, China;
    2. Vegetable Research Center, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China
  • Received:2018-05-07 Revised:2018-05-29 Online:2018-07-01 Published:2018-07-01

Abstract: A new binary organic phase change material with a phase change temperature of 0~3℃ was developed. The material was mad by mixing tetradecane and octanoic acid around their eutectic point predicted by a theoretical calculation, which also gave the latent heat. A differential scanning calorimeter, a step cooling curve measurement device, and a hot disk thermal analyzer were used to measure the thermal properties of the formulations. A cyclic thermal testing box was used for understanding the cycle stability of the formulations. The results showed that the eutectic point was 1.0℃ at a molar mass ratio of tetradecane to octanoic acid of 51:49 with a latent heat of 191.8 J·g-1, and a thermal conductivity of 0.3790 W·(m·K)-1. The phase change material was shown to have a good cycle stability:the phase change temperature was 0.9℃ and the latent heat was 191.5 J·g-1, after 100 cycles.

Key words: phase change material, cold storage, thermal properties, cyclic stability

CLC Number: