Energy Storage Science and Technology ›› 2016, Vol. 5 ›› Issue (5): 678-701.doi: 10.12028/j.issn.2095-4239.2016.0045

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The development of studies in all-solid-state thin film lithium batteries

WU Yongmin, WU Xiaomeng, ZHU Lei, XU Dinghao, TIAN Wensheng, TANG Weiping   

  1. State Key Laboratory of Space Power Source Technology, Shanghai Institute of Space Power-sources, Shanghai 200245, China
  • Received:2016-07-10 Revised:2016-07-29 Online:2016-09-01 Published:2016-09-01

Abstract: All-solid-state thin film lithium batteries (TFBs) have better safety as well as greater potential in the energy density, power density and cycle life than lithium ion batteries (LIBs). TFBs have the most mature preparation technology among the exiting type of all-solid-state lithium batteries, which performance were excellent and were also taking the lead to achieve the commercialization. The states of art preparation of TFBs were quite different with LIB, which is mainly depending on physical deposition. Every part of TFBs such as cathode, anode, electrolyte and collector was prepared into high density films followed with in situ stack. This review summarizes the progress and advances for the studies of TFBs in the recent decade. We tried to give an airscape from the view points of the whole preparation of TFBs, the existing problems of scientific and technical. The solid inorganic electrolyte film, cathode film and anode film regard as three main steps for TFBs preparation, which progress and key issues of were described separately. On this basis, the whole preparation of TFBs and the TFBs with special structure were discussed, following with the brief advances of substrate, current collector and encapsulation.

Key words: all-solid-state thin-film lithium batteries (TFB), solid inorganic electrolyte film, cathode film, anode film, solid interface of TFB