基于CO2转化的碳材料制备及其在超级电容器中的应用

doi:10.12028/j.issn.2095-4239.2017.0097

摘要/Abstract

摘要： 超级电容器是介于二次电池和传统电容器之间的新型能量存储器件，功率密度高、充放电效率高、循环寿命长且工作温度宽，具有广阔的市场前景。将CO2气体转化为各种碳材料是近年来逐渐成长的新方法，有望成为制备碳基能源材料的绿色技术路线。本文以高性能碳基电极材料的设计策略为切入点，梳理了各类基于CO2转化的碳材料制备技术的发展历程，包括直接燃烧法、高温镁热还原法和自蔓延高温合成法，并在此基础上深入讨论了基于CO2转化的碳材料在超级电容器中的应用，最后针对性地展望了CO2转化技术在碳材料制备及超级电容器构建中的发展方向。

关键词: 超级电容器, CO2转化, 碳材料, 能量存储

Abstract: Supercapacitors are energy storage devices which combine the advantages of secondary batteries and dialectical capacitors. Supercapacitors boast such characteristics as high power density, high charge/discharge efficiency, long cycle life and wide operation temperature. CO2 conversion into various carbon materials is recently developed and is considered as a promising technique towards green fabrication of carbon-based energy-storage materials. This review starts from different strategies for fabricating high-performance carbon-based electrodes, introduces the development of CO2 conversion methods, including direct combustion, high-temperature magnesiothermic reduction and self-propagating high-temperature synthesis, and then gives a detailed discussion of application of CO2-derived carbon in supercapacitors. At the end of this review, the prospect of CO2 conversion in production of carbon materials and fabrication of supercapacitors is given.

Key words: supercapacitor, CO2 conversion, carbon materials, energy storage

李晨，张熊，王凯，孙现众，马衍伟. 基于CO2转化的碳材料制备及其在超级电容器中的应用[J]. 储能科学与技术, 2017, 6(5): 1041-1049.

LI Chen, ZHANG Xiong, WANG Kai, SUN Xianzhong, MA Yanwwei. Supercapacitive application of carbon materials produced by CO2 conversion[J]. Energy Storage Science and Technology, 2017, 6(5): 1041-1049.

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