无机添加剂用于锂离子电池电解液的研究进展

doi:10.3969/j.issn.2095-4239.2014.06.003

摘要/Abstract

摘要： 总结了无机添加剂用于锂离子电池电解液的发展概况和最新的一些研究进展,结合其作用机制或作用效果将其具体分成三类进行探讨:无机成膜添加剂;研究阴极活性物质溶解与容量衰减关系的过渡金属盐添加剂;其它种类添加剂,如除去电解液中的HF,抑制锰沉积对石墨负极性能的影响和增加电解液电导率等.详细阐述了这些无机添加剂的作用机理,作用效果以及应用的局限性,并分析了这类添加剂的未来前景.

关键词: 锂离子电池, 电解液, 无机添加剂

Abstract: This paper summarizes the development and the latest research progress on inorganic additives for lithium ion battery electrolytes. Combined with their working mechanisms, the inorganic additives are divided into three main categories: inorganic film-forming additives, transition metal salts and others. The important role of inorganic additives for lithium-ion battery electrolytes was described by analyzing their effects and working mechanisms. The future prospects of inorganic additives for lithium-ion battery electrolytes were analyzed.

Key words: lithium-ion batteries, electrolytes, inorganic additives

中图分类号:

TQ028.8

贠娇娇, 刘红梅, 郑会元, 郑洪河. 无机添加剂用于锂离子电池电解液的研究进展[J]. 储能科学与技术, 2014, 3(6): 584-589.

YUN Jiaojiao, LIU Hongmei, ZHENG Huiyuan, ZHENG Honghe. Research progress on inorganic additives for lithium-ion battery electrolytes[J]. Energy Storage Science and Technology, 2014, 3(6): 584-589.

参考文献

[1] Zheng Honghe(郑洪河),Qin Jianhua(秦建华),Guo Baosheng(郭宝生),Xu Zhongyu(徐仲榆). Development and prospects of the additives in electrolytes of lithium ion batteries[J]． Chemistry Online (化学通报),2004,67(10):W76.
[2] Zhang S S. A review on electrolyte additives for lithium-ion batteries[J] . Journal of Power Sources ,2006,162(2):1379-1394.
[3] Aurbach D,Chusid O,Carmeli Y,Babai M,Yamin H. The correlation between the surface chemistry and the performance of Li-carbon intercalation anodes for rechargeable "rocking-chair" type batteries[J]. J. Electrochem. ,1994,141(3):603-611.
[4] EinEli Y,Koch V R. The role of SO 2 as an additive to organic Li-ion battery electrolytes[J]. Journal of the Electrochemical Society ,1997,144(4):1159-1165.
[5] EinEli Y. Dithiocarbonic anhydride (CS 2 )-a new additive in Li-ion battery electrolytes[J]. Journal of Electroanalytical Chemistry ,2002,531:95-99.
[6] Komaba S,Itabashi T,Kaplan B,Groult H,Kumagai N. Enhancement of Li-ion battery performance of graphite anode by sodium ion as an electrolyte additive[J]. Electrochemistry Communications ,2003,5(11):962-966.
[7] Komaba S,Itabashi T,Watanabe M,Groult H,Kumagai N. Electrochemistry of graphite in Li and Na salt codissolving electrolyte for rechargeable batteries[J]. Journal of the Electrochemical Society ,2007,154(4):A322-A330.
[8] Jee-Sun Shina,Chi-Hwan H,Un-Ho Jungb,Shung-Ik Leeb,Hyeong-Jin Kimc,Keon Kima. Effect of Li 2 CO 3 additive on gas generation in lithium-ion batteries[J]. Journal of Power Sources ,2002,109(1):47-52.
[9] Zheng Honghe,Fu Yanbao,Zhang Hucheng,Takeshi Abe,Zempachi Ogumib. Potassium salts electrolyte additives for enhancing electrochemical performances of natural graphite anodes[J]. Electrochemical and Solid-State Letters ,2006,9(3):A115-A119.
[10] Zhuang Q C,Li J,Tian L L. Potassium carbonate as film forming electrolyte additive for lithium-ion batteries[J]. Journal of Power Sources ,2013,222:177-183.
[11] Wu Maosung,Lin Jungcheng,Julia Chiang Pin-Chi. A silver hexafluorophosphate additive to propylene carbonate-based electrolytes for lithium-ion batteries[J]. Electrochemical and Solid-State Letters ,2004,7(7):A206-A208.
[12] Verma P,Maire P,Novák P. A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries[J]. Electrochim. Acta ,2010,55:6332-6341.
[13] Zhang Yong,Feng Hui,Zhang Aiqin,Zhang Cuifen,Zhang Peng. Effect of SO 2 and CO 2 additives on the cycle performances of commercial lithium-ion batteries[J]. Ionics ,2011,17(8):677-682.
[14] Mao H,Reimers J N. US,5964902[P]. 1999.
[15] Wagner M W,Liebenow C,Besenhard J O. Effect of polysulfide- containing electrolyte on the film formation of the negative electrode[J]. Journal of Power Sources ,1997,68(2):763-737.
[16] Besenhard J O,Wagner M W,Winter M,Jannakoudakis A D,Jannakoudakis P D,Theodoridou E. Inorganic film-forming electrolyte additives improving the cycling behaviour of metallic lithium electrodes and the self-discharge of carbon-lithium electrodes[J]. Journal of Power Sources ,1993,44(1-3):413-420.
[17] Gan H,Takeuchi E S. US,6136477[P]. 2000.
[18] Gan H,Takeuchi E S. US,6027827[P]. 2000.
[19] Wu Maosung,Julia Chiang Pinchi,Lin Jungcheng,Lee Jyhtsung. Effects of copper trifluoromethanesulphonate as an additive to propylene carbonate-based electrolyte for lithium-ion batteries[J]. Electrochemical and Solid-State Letters ,2004,49:4379-4386.
[20] Wu Borong,Ren Yonghuan,Mu Daobin,Zhang Cunzhong,Liu Xiaojiang,Yang Guchang,Wu Feng. Effect of sodium chloride as electrolyte additive on the performance of mesocarbon microbeads electrode[J]. International Journal of Electrochemical Science ,2013,8:670-677.
[21] Takeuchi S,Miyazaki K,Sagane F,Fukutsuka T,Jeong S K,Abe T. Electrochemical properties of graphite electrode in propylene carbonate-based electrolytes containing lithium and calcium ions[J]. Electrochimica. Acta ,2011,56:10450-10453.
[22] Saya Takeuchi,Tomokazu Fukutsuka,Kohei Miyazaki,Takeshi Abe. Electrochemical preparation of a lithium-graphite-intercalation compound in a dimethyl sulfoxide-based electrolyte containing calcium ions[J]. Carbon ,2013,57:232-238.
[23] Kumagai N,Komaba S,Kataoka Y. Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries[J]. Electrochimica. Acta ,2002,47:1229-1239.
[24] Markovsky B,Rodkin A,Salitra G,Talyosef Y,Aurbach D,Kim H J. The impact of Co 2+ ions in solutions on the performance of LiCoO 2 , Li, and lithiated graphite electrodes[J]. Journal of the Electrochemical Society ,2004,151:A1068-A1076.
[25] Tsunekawa Hajime,Tanimoto Satoshi,Marubayashi Ryoji,Fujita Miho,Kifune Koichi,Sano Mitsuru. Capacity fading of graphite electrodes due to the deposition of manganese ions on them in Li-ion batteries[J]. Journal of the Electrochemical Society ,2002,149:A1326-A1331.
[26] Delacourt C,Kwong A,Liu X,Qiao R,Yang W L,Lu P,Harris S J,Srinivasan V. Effect of manganese contamination on the solid-electrolyte-interphase properties in Li-ion batteries[J]. Journal of the Electrochemical Society ,2013,160:A1099-A1107.
[27] Stux A M,Barker J. Additives for inhibiting decomposition of lithium salts and electrolytes containing said additives:US,5707760[P]. 1998-01-13.
[28] Komaba S,Kaplan B,Ohtsuka T,Kataoka Y,Kumagai N,Groult H. Inorganic electrolyte additives to suppress the degradation of graphite anodes by dissolved Mn(II) for lithium-ion batteries[J]. Journal of Power Sources ,2003,119-121:378-382.
[29] Zhong Q,Sacken U V. Low viscosity electrolyte comprising P 2 O 5 for use in nonaqueous rechargeable lithium batteries:US,5 650 245[P]. 1997-07-22.
[30] Fahys B,Herlem G,Szekely M,Sutter E,Mathieu C,Herlem M,Penneau J F. N -butylamine as solvent for lithium salt electrolytes. Structure and properties of concentrated solutions[J]. Electrochimica. Acta ,1996,41:2753-2760.
[31] Wu Borong,Ren Yonghuan,Mu Daobin,Liu Xiaojiang,Yang Guchang,Sun Zhe. Lithium insertion/desertion properties of LiFePO 4 cathode in a low temperature electrolyte modified with sodium chloride additive[J]. Solid State Ionics ,2014,260:8-14.