吸附热泵技术和应用研究进展

doi:10.3969/j.issn.2095-4239.2014.05.008

摘要/Abstract

摘要： 吸附热泵是一种以低品位热能驱动的节能环保型热泵技术,利用吸附剂与吸附质间的吸附热实现制冷或制热效果,从文献检索结果来看该技术越来越受到广泛关注,国内外相关学者开展了大量的研究工作.本文首先介绍了开展吸附热泵相关研究的课题组和其主要研究方向,进而简要介绍了吸附式热泵技术;其次,着重描述了吸附热泵技术的国内外研究现状,对吸附工质的研究,床层的传热传质强化,热泵新技术及商业化热泵产品等进行了详细的叙述;最后,叙述了吸附式热泵当前存在的主要问题,指出了吸附热泵发展存在的挑战性问题和未来的发展方向.

关键词: 吸附, 热泵, 强化传热和传质, 吸附剂

Abstract: An adsorption heat pump uses sorption heat for refrigeration or heating. Such a technology has gained significant attention in recent years with lots of research and development nationally and internationally. This paper provides a review on the area covering working fluids, new adsorption heat pump technologies and commercial products, and methods to enhance heat and mass transfer. Challenges and recommendations for future research and development are also given.

Key words: adsorption, heat pump, enhancement of heat and mass transfer, adsorbent

中图分类号:

TK11+5

郑新港, 丁玉龙. 吸附热泵技术和应用研究进展[J]. 储能科学与技术, 2014, 3(5): 495-508.

ZHENG Xingang, DING Yulong. Recent progress in the adsorption heat pump technology[J]. Energy Storage Science and Technology, 2014, 3(5): 495-508.

参考文献

[1] Critoph R E. Solid sorption cycles:A short history[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2012,35(3):490-493.
[2] Wang R Z. Efficient adsorption refrigerators integrated with heat pipes[J]. Applied Thermal Engineering ,2008,28(4):317-326.
[3] Wang R Z. Adsorption refrigeration research in Shanghai Jiao Tong university[J]. Renewable & Sustainable Energy Reviews ,2001,5(1):1-37.
[4] Wang R Z,Xia Z Z,Wang L W, et al . Heat transfer design in adsorption refrigeration systems for efficient use of low grade thermal energy[C]//Washington:Proceedings of the Asme International Heat Transfer Conference,2010:575-589.
[5] Wang L W,Wang R Z,Oliveira R G. A review on adsorption working pairs for refrigeration[J]. Renewable & Sustainable Energy Reviews ,2009,13(3):518-534.
[6] Zhu D S,Wu H J,Wang S W. Experimental study on composite silica gel supported CaCl 2 sorbent for low grade heat storage[J]. International Journal of Thermal Sciences ,2006,45(8):804-813.
[7] Wang S W,Zhu D S. A novel type of coupling cycle for adsorption heat pumps[J]. Applied Thermal Engineering ,2002,22(9):1083-1088.
[8] Zhao Z H,Zhu D S,Li J. Experimental research on preparation and adsorption properties of a new composite adsorbent[C]//Guang zhou:Proceedings of the 3rd International Symposium on Heat Transfer Enhancement and Energy Conservation,2004:876-879.
[9] Passos E,Meunier F,Gianola J C. Thermodynamic performance improvement of an intermittent solar-powered refrigeration cycle using adsorption of methanol on activated carbon[J]. Journal of Heat Recovery Systems ,1986,6(3):259-264.
[10] Meunier F. Sorption solar cooling[J]. Renewable Energy ,1994,5(1-4):422-429.
[11] Meunier F. Solid sorption heat powered cycles for cooling and heat pumping applications[J]. Applied Thermal Engineering ,1998,18(9-10):715-729.
[12] Clausse M,Meunier F,Coulie J, et al . Comparison of adsorption systems using natural gas fired fuel cell as heat source, for residential air conditioning[J]. International Journal of Refriger- ation : Revue Internationale Du Froid ,2009,32(4):712-719.
[13] Critoph R E. Evaluation of alternative refrigerant-adsorbent pairs for refrigeration cycles[J]. Applied Thermal Engineering ,1996,16(11):891-900.
[14] Metcalf S J,Critoph R E,Tamainot-Telto Z. Optimal cycle selection in carbon-ammonia adsorption cycles[J]. International Journal of Refrigeration-Revue Internationale Du Froid ,2012,35(3):571-580.
[15] Zhong Y,Critoph R E,Thorpe R. Evaluation of the performance of solid sorption refrigeration systems using carbon dioxide as refrigerant[J]. Applied Thermal Engineering ,2006,26(16):1807-1811.
[16] Tamainot-Telto Z,Critoph Z R E. Monolithic carbon for sorption refrigeration and heat pump applications[J]. Applied Thermal Engineering ,2001,21(1):37-52.
[17] Okunev B N,Gromov A P,Aristov Y I. Modelling of isobaric stages of adsorption cooling cycle:An optimal shape of adsorption isobar[J]. Applied Thermal Engineering ,2013,53(1):89-95.
[18] Aristov Y I. Challenging offers of material science for adsorption heat transformation:A review[J]. Applied Thermal Engineering ,2013,50(2):1610-1618.
[19] Pons M F,Meunier G,Cacciola R E, et al . Thermodynamic based comparison of sorption systems for cooling and heat pumping[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,1999,22(1):5-17.
[20] Aristov Y I,Restuccia G,Cacciola G,Parmon V N. A family of new working materials for solid sorption air conditioning systems[J]. Applied Thermal Engineering ,2002,22(2):191-204.
[21] Miles D J,Shelton S V. Design and testing of a solid-sorption heat-pump system[J]. Applied Thermal Engineering ,1996,16(5):389-394.
[22] Khan M Z I,Alam K C A,Saha B B, et al . Parametric study of a two-stage adsorption chiller using re-heat:The effect of overall thermal conductance and adsorbent mass on system performance[J]. International Journal of Thermal Sciences ,2006,45(5):511-519.
[23] Teng Yi(滕毅),Wang Ruzhu(王如竹). Progress on adsorption refrigeration technology[J]. Journal of Shanghai Jiao Tong University (上海交通大学学报),1998(04):111-115.
[24] Wongsuwan W,Kumar S,Neveu P,Meunier F. A review of chemical heat pump technology and applications[J]. Applied Thermal Engineering ,2001,21(15):1489-1519.
[25] Li Tingxian(李廷贤),Wang Ruzhu(王如竹),Wang Liwei(王丽伟).低品位热能驱动的高效热化学吸附式制冷研究[J]. Science in China Press (科学通报),2008,53(24):2978-2993.
[26] Demir H,Mobedi M,Ulku S. A review on adsorption heat pump:Problems and solutions[J]. Renewable & Sustainable Energy Reviews ,2008,12(9):2381-2403.
[27] Pons M,Kodama A. Entropic analysis of adsorption open cycles for air conditioning, Part 1:First and second law analyses[J]. International Journal of Energy Research ,2000,24(3):251-262.
[28] Kodama A,Jin W L,Goto M,Hirose T,Pons M. Entropic analysis of adsorption open cycles for air conditioning, Part 2:Interpretation of experimental data[J]. International Journal of Energy Research ,2000,24(3):263-278.
[29] Chahbani M H,Labidi J,Paris J. Effect of mass transfer kinetics on the performance of adsorptive heat pump systems[J]. Applied Thermal Engineering ,2002,22(1):23-40.
[30] Askalany A A,Salem M,Ismael I M,Ali A H H,Morsy M G,Saha B B. An overview on adsorption pairs for cooling[J]. Renewable & Sustainable Energy Reviews ,2013,19:565-572.
[31] Saha B B,Chakraborty A,Koyama S,Aristov Y I. A new generation cooling device employing CaCl 2 -in-silica gel-water system[J]. International Journal of Heat and Mass Transfer ,2009,52(1-2):516-524.
[32] Beck J S,Vartuli J C,Roth W J, et al . A new family of mesoporous molecular-sieves prepared with liquid-crystal templates[J]. Journal of the American Chemical Society ,1992,114(27):10834-10843.
[33] Schlögl R. Handbook of Porous Solids[M]. New York:Wiley-VCH,2002.
[34] Barton T J,Bull L M,Klemperer W G, et al . Tailored porous materials[J]. Chemistry of Materials ,1999,11(10):2633-2656.
[35] Janchen J D,Ackermann H,Stach W, et al . Studies of the water adsorption on zeolites and modified mesoporous materials for seasonal storage of solar heat[J]. Solar Energy ,2004,76(1-3):339-344.
[36] Shimooka S,Oshima K,Hidaka H, et al . The evaluation of direct cooling and heating desiccant device coated with FAM[J]. Journal of Chemical Engineering of Japan ,2007,40(13):1330-1334.
[37] Aristov Y I. Novel materials for adsorptive heat pumping and storage:Screening and nanotailoring of sorption properties[J]. Journal of Chemical Engineering of Japan ,2007,40(13):1242-1251.
[38] Ehrenmann J,Henninger S K,Janiak C. Water adsorption characteristics of MIL-101 for heat transformation applications of MOFs[J]. European Journal of Inorganic Chemistry ,2011,4:471-474.
[39] Critoph R E,Zhong Y. Review of trends in solid sorption refrigeration and heat pumping technology[J]. Journal of Process Engineering ,2004,19(E3):285-300.
[40] Follin S,GoetzV,GuillotA. Influence of microporous characteristics of activated carbons on the performance of an adsorption cycle for refrigeration[J]. Industrial & Engineering Chemistry Research ,1996,35(8):2632-2639.
[41] Tamainot-Telto Z,Metcalf S J,Critoph R E, et al . Carbon-ammonia pairs for adsorption refrigeration applications:Ice making, air conditioning and heat pumping[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2009,32(6):1212-1229.
[42] Vasiliev L L,Kanonchik L E,Antuh A A, et al . NaX zeolite, carbon fibre and CaCl 2 ammonia reactors for heat pumps and refrigerators[J]. Adsorption Journal of the International Adsor- ption Society ,1996,2(4):311-316.
[43] Vasiliev L L,Nikanpour D,Antukh A, et al . Multisalt-carbon chemical cooler for space applications[J]. Journal of Engineering Physics and Thermophysics ,1999,72(3):572-577.
[44] Attan D,Alghoul M A,Saha B B, et al . The role of activated carbon fiber in adsorption cooling cycles[J]. Renewable & Sustainable Energy Reviews ,2011,15(3):1708-1721.
[45] Gordeeva L G,Restuccia G,Cacciola G, et al . Selective water sorbents for multiple applications.5.LiBr confined in mesopores of silica gel:Sorption properties[J]. Reaction Kinetics and Catalysis Letters ,1998,63(1):81-88.
[46] Gordeeva L G,Grekova A D,Krieger T A, et al . Adsorption properties of composite materials (LiCl plus LiBr)/silica[J]. Microporous and Mesoporous Materials ,2009,126(3):262-267.
[47] Gordeeva L,Grekova A,Krieger T, et al . Composites "binary salts in porous matrix" for adsorption heat transformation[J]. Applied Thermal Engineering ,2013,50(2):1633-1638.
[48] Tokarev M M,Freni A,Restuccia G,Aristov Y I. Selective water sorbents for multiple applications.12.Water sorption equilibrium at elevated temperature[J]. Reaction Kinetics and Catalysis Letters ,2002,76(2):295-301.
[49] Aristov Y I,Restuccia G,Tokarev M M, et al . Selective water sorbents for multiple applications.11.CaCl 2 confined to expanded vermiculite[J]. Reaction Kinetics and Catalysis Letters ,2000,71(2):377-384.
[50] Gordeeva L G,Mrowiec-Bialon J,Jarzebski A B, et al . Selective water sorbents for multiple applications.8.Sorption properties of CaCl 2 -SiO 2 sol-gel composites[J]. Reaction Kinetics and Catalysis Letters ,1999,66(1):113-120.
[51] Aristov Y I,DiMarco G,Tokarev M M,Parmon V N. Selective water sorbents for multiple applications.3.CaCl 2 solution confined in micro- and mesoporous silica gels:Pore size effect on the ''solidification-melting'' diagram[J]. Reaction Kinetics and Catalysis Letters ,1997,61(1):147-154.
[52] Aristov Y I,Tokarev M,Cacciola G,Restuccia G. Selective water sorbents for multiple applications .1.CaCl 2 confined in mesopores of silica gel:Sorption properties[J]. Reaction Kinetics and Catalysis Letters ,1996,59(2):325-333.
[53] Glaznev I,Ponomarenko I,Kirik S,Aristov Y. Composites CaCl 2 /SBA-15 for adsorptive transformation of low temperature heat:Pore size effect[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2011,34(5):1244-1250.
[54] Moreno-Castilla C,Perez-Cadenas A F. Carbon-based honeycomb monoliths for environmental gas-phase applications[J]. Materials ,2010,3(2):1203-1227.
[55] Chahbani M H,Labidi J,Paris J. Modeling of adsorption heat pumps with heat regeneration[J]. Applied Thermal Engineering ,2004,24(2-3):431-447.
[56] Douss N,Meunier F E,Sun L M. Predictive model and experimental results for a 2-adsorber solid adsorption heat-pump[J]. Industrial & Engineering Chemistry Research ,1988,27(2):310-316.
[57] Restuccia G,Recupero V,Cacciola G,Rothmeyer M. Zeolite heat-pump for domestic heating[J]. Energy ,1988,13(4):333-342.
[58] Rezk A,Al-Dadah R K,Mahmoud S,Elsayed A. Effects of contact resistance and metal additives in finned-tube adsorbent beds on the performance of silica gel/water adsorption chiller[J]. Applied Thermal Engineering ,2013,53(2):278-284.
[59] Wang L J,Zhu D S,Tan Y K. Heat transfer enhancement on the adsorber of adsorption heat pump[J]. Adsorption : Journal of the International Adsorption Society ,1999,5(3):279-286.
[60] Yu Shunhui(余舜辉),Chen Li(陈砺). Analysis and enhancement of the heat and mass transfer process in the adsorber of the solid adsorption refrigeration system[J]. Refrigeration (制冷),2001,20(2):43-47.
[61] Watanabe F,Watabe Y,Katsuyama H, et al . Heat-transfer accompanied by adsorption desorption of water-vapor in adsorption heat-pump of packed-bed type[J]. Kagaku Kogaku Ronbunshu ,1993,19(1):83-90.
[62] Freni A,Bonaccorsi L,Proverbio E, et al . Zeolite synthesised on copper foam for adsorption chillers:A mathematical model[J]. Microporous and Mesoporous Materials ,2009,120(3):402-409.
[63] Restuccia G,Freni A,Maggio G. A zeolite-coated bed for air conditioning adsorption systems:Parametric study of heat and mass transfer by dynamic simulation[J]. Applied Thermal Engineering ,2002,22(6):619-630.
[64] Eun T H,Song H K,Han J H, et al . Enhancement of heat and mass transfer in silica-expanded graphite composite blocks for adsorption heat pumps .Part II. Cooling system using the composite blocks[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2000,23(1):74-81.
[65] Speidel K,Kleinemeier H P. Solar cooling and air-conditioning processes using chemical-reactions[C]//Denver:1991 Solar World Congress,1992:1601-1606.
[66] Groll M. Reaction beds for dry sorption machines[J]. Heat Recovery Systems & Chp. ,1993,13(4):341-346.
[67] Eun T H,Song H K,Han J H, et al . Enhancement of heat and mass transfer in silica-expanded graphite composite blocks for adsorption heat pumps:Part I. Characterization of the composite blocks[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2000,23(1):64-73.
[68] Wang S G,Wang R Z,Li X R. Research and development of consolidated adsorbent for adsorption systems[J]. Renewable Energy ,2005,30(9):1425-1441.
[69] Hu P,Yao J J,Chen Z S. Analysis for composite zeolite/foam aluminum-water mass recovery adsorption refrigeration system driven by engine exhaust heat[J]. Energy Conversion and Management ,2009,50(2):255-261.
[70] Gui Y B,Wang R Z,Wang W, et al . Performance modeling and testing on a heat-regenerative adsorptive reversible heat pump[J]. Applied Thermal Engineering ,2002,22(3):309-320.
[71] Kubota M,Ueda T,Fujisawa R, et al. Cooling output performance of a prototype adsorption heat pump with fin-type silica gel tube module[J]. Applied Thermal Engineering ,2008,28(2-3):87-93.
[72] Grisel R J H,Smeding S F,De-Boer R. Waste heat driven silica gel/water adsorption cooling in trigeneration[J]. Applied Thermal Engineering ,2010,30(8-9):1039-1046.
[73] Saba B B,Koyama S,El-Sharkawy I I, et al. Experiments for measuring adsorption characteristics of an activated carbon fiber/ethanol pair using a plate-fin heat exchanger[J]. Hvac&R Research ,2006,12(3B):767-782.
[74] Miyazaki T,Akisawa A. The influence of heat exchanger parameters on the optimum cycle time of adsorption chillers[J]. Applied Thermal Engineering ,2009,29(13):2708-2717.
[75] Guilleminot J J,Choisier A,Chalfen J B, et al. Heat-transfer intensification in fixed-bed adsorbers[J]. Heat Recovery Systems & Chp. ,1993,13(4):297-300.
[76] Alam K C A,Saha B B,Kang Y T, et al . Heat exchanger design effect on the system performance of silica gel adsorption refrigeration systems[J]. International Journal of Heat and Mass Transfer ,2000,43(24):4419-4431.
[77] Tangkengsirisin V,Kanzawa A,Watanabe T. A solar-powered adsorption cooling system using a silica gel water mixture[J]. Energy ,1998,23(5):347-353.
[78] Zhu Dongsheng(朱冬生),Wang Lijun (汪立军),Kang Xinyu(康新宇),Tan Yingke(谭盈科),Wang Shengwei(王盛卫). An experimental study of heat conduction enhancement on the solar-powered adsorber[J]. ACTA Energiae Solaris Sinica (太阳能学报),1998,19(1):186-190.
[79] Mauran S,Prades P,Lharidon F. Heat and mass-transfer in consolidated reacting beds for thermochemical systems[J]. Heat Recovery Systems & Chp. ,1993,13(4):315-319.
[80] Critoph R E,Tamainot-Telto Z,Davies G N L. A prototype of a fast cycle adsorption refrigerator utilizing a novel carbon-aluminium laminate[J]. Journal of Power and Energy ,2000,214(A5):439-448.
[81] Freni A,Russo F,Vasta S, et al. An advanced solid sorption chiller using SWS-1Ll[J]. Applied Thermal Engineering ,2007,27(13):2200-2204.
[82] Bonaccorsi L,Freni A,Proverbio E, et al. Zeolite coated copper foams for heat pumping applications[J]. Microporous and Mesoporous Materials ,2006,91(1-3):7-14.
[83] Heyden V H,Munz G,Schnabel L, et al. Kinetics of water adsorption in microporous aluminophosphate layers for regenerative heat exchangers[J]. Applied Thermal Engineering ,2009,29(8-9):1514-1522.
[84] Critoph R E. Multiple bed regenerative adsorption cycle using the monolithic carbon-ammonia pair[J]. Applied Thermal Engineering ,2002,22(6):667-677.
[85] Douss N,Meunier F. Experimental-study of cascading adsorption cycles[J]. Chemical Engineering Science ,1989,44(2):225-235.
[86] Wang Ruzhu(王如竹),Wang Liwei(王丽伟). 低品位热能驱动的绿色制冷技术:吸附式制冷[J]. Science in China Press (科学通报),2005,50(2):101-111.
[87] Ritthong W,Kiatsiriroat T,Wongsuwan W, et al. Performance analysis of a modular adsorption cooling system with sonic vibration in the adsorber[J]. Experimental Heat Transfer ,2014,27(1):14-27.
[88] Xue B,Iwama Y,Tanaka Y, et al. Cyclic steam generation from a novel zeolite-water adsorption heat pump using low-grade waste heat[J]. Experimental Thermal and Fluid Science ,2013,46:54-63.
[89] Xue B,Tahara K,Nakashima K, et al. Numerical simulation for steam generation process in a novel zeolite-water adsorption heat pump[J]. Journal of Chemical Engineering of Japan ,2012,45(6):408-416.
[90] Oktariani E,Tahara K,Nakashima K, et al. Experimental investigation on the adsorption process for steam generation using a zeolite-water system[J]. Journal of Chemical Engineering of Japan ,2012,45(5):355-362.
[91] Oktariani E,Noda A,Nakashima K, et al. Potential of a direct contact adsorption heat pump system for generating steam from waste water[J]. International Journal of Energy Research ,2012,36(11):1077-1087.
[92] Nakaso K,Oktariani E,Noda A, et al. Estimation of performance of absorption/desorption system for regenerating waste water from industrial process[C]//Washington:Proceedings of the Asme 5th International Conference on Energy Sustainability 2011,Pts a-C,2012:1043-1049.
[93] Miles D J,Sanborn D M,Nowakowski G A,Shelton S V. Gas-fired sorption heat-pump development[J]. Heat Recovery Systems & Chp. ,1993,13(4):347-351.
[94] Näslund M. Residential gas-fired sorption heat pumps[EB/OL]. 2008. http://www.risoe.dk/rispubl/NEI/NEI-DK-5118.pdf.
[95] Yong L,Sumathy K. Performance analysis of a continuous multi-bed adsorption rotary cooling system[J]. Applied Thermal Engineering ,2005,25(2-3):393-407.
[96] Li H,Dai Y J,Li Y, et al. Experimental investigation on a one-rotor two-stage desiccant cooling/heating system driven by solar air collectors[J]. Applied Thermal Engineering ,2011,31(17-18):3677-3683.
[97] Ge T S,Dai Y J,Wang R Z, et al. Experimental investigation on a one-rotor two-stage rotary desiccant cooling system[J]. Energy ,2008,33(12):1807-1815.
[98] Kodama A,Hirayama T,Goto M, et al. The use of psychrometric charts for the optimisation of a thermal swing desiccant wheel[J]. Applied Thermal Engineering ,2001,21(16):1657-1674.
[99] Llobet J,Goetz V. Rotary system for the continuous production of cold by solid-gas sorption:Modeling and analysis of energy performance[J]. International Journal of Refrigeration : Revue Internationale Du Froid ,2000,23(8):609-625.
[100] Stabat P,Marchio D. Heat and mass transfer modeling in rotary desiccant dehumidifiers[J]. Applied Energy ,2009,86(5):762-771.
[101] Zhang X J,Dai Y J,Wang R Z. A simulation study of heat and mass transfer in a honeycombed rotary desiccant dehumidifier[J]. Applied Thermal Engineering ,2003,23(8):989-1003.
[102] TeGrotenhuis W E,Humble P H,Sweeney J B. Compact high efficiency adsorption heat pump[C]//Lafayette:International Refrigeration and Air Conditioning Conference,2012:1303.
[103] TeGrotenhuis W E,Humble P H,Sweeney J B. Simulation of a high efficiency multi-bed adsorption heat pump[J]. Applied Thermal Engineering ,2012,37:176-182.
[104] Wang R Z,Oliveira R G. Adsorption refrigeration:An efficient way to make good use of waste heat and solar energy[J]. Progress in Energy and Combustion Science ,2006,32(4):424-458.