基于水合盐的热化学吸附储热技术研究进展

doi:10.19799/j.cnki.2095-4239.2020.0168

储能科学与技术 ›› 2020, Vol. 9 ›› Issue (6): 1729-1736.doi: 10.19799/j.cnki.2095-4239.2020.0168

基于水合盐的热化学吸附储热技术研究进展

翁立奎¹(), 张叶龙^2,³, 姜琳¹, 贾亦轩¹, 谈玲华^2,³, 金翼¹(), 丁玉龙^2,⁴

^1.南京金合能源材料有限公司，江苏南京 210047
^2.南京理工大学化工学院，江苏南京 210094
^3.南京理工大学国家特种超细粉体工程技术研究中心，江苏南京 210094
^4.英国伯明翰大学，英国伯明翰 B15 2TT

收稿日期:2020-05-07 修回日期:2020-06-22 出版日期:2020-11-05 发布日期:2020-10-28
通讯作者: 金翼 E-mail:likui.weng@jinhe-energy.com;yi.jin@jinhe-energy.com
作者简介:翁立奎（1981—），男，硕士，高级工程师，主要研究方向为储热材料及系统，E-mail：likui.weng@jinhe-energy.com；
基金资助:
国家重点研发计划项目“变革性技术关键科学问题”专项(2018YFA0702300);江苏省科技项目政策引导类计划(国际科技合作)—重点国别及机构产业技术合作项目(BZ2017052)

Research progress on thermochemical adsorption heat storage technology based on hydrate

Likui WENG¹(), Yelong ZHANG^2,³, Lin JIANG¹, Yixuan JIA¹, Linghua TAN^2,³, Yi JIN¹(), Yulong DING^2,⁴

^1.Nanjing Jinhe Energy Material Company Limited, Nanjing 210047, Jiangsu, China
^2.School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, Jiangsu, China
^3.National Special Superfine Powder Engineering Research Center of China, Nanjing 210094, Jiangsu, China
^4.University of Birmingham, Birmingham B15 2TT, UK

Received:2020-05-07 Revised:2020-06-22 Online:2020-11-05 Published:2020-10-28
Contact: Yi JIN E-mail:likui.weng@jinhe-energy.com;yi.jin@jinhe-energy.com

摘要/Abstract

摘要：

热化学吸附储热技术与传统的显热储热和相变储热技术相比具有储热密度高、热损失小和能实现跨季节储热的优点。本文综述了无机盐-水体系（也称水合盐）热化学吸附储热技术的研究现状，对典型热化学吸附材料和化学吸附反应器进行了总结。现有水合盐化学吸附体系主要包括卤盐-水和硫酸盐-水，虽然具有较高的储热密度，然而在化学吸附储热系统中使用时存在潮解导致的反应器腐蚀或膨胀结块导致的动力学性能降低等问题。以多孔材料为载体复合水合盐的方式有望解决目前存在的技术问题，提出开发新型多孔载体和化学吸附储热系统的结构优化是推动化学吸附储热技术工业化的关键。

关键词: 储热, 热化学, 吸附, 水合盐, 吸附系统

Abstract:

The thermochemical adsorption heat storage has a higher heat storage density, a lower heat loss, and a long-term heat storage, which exhibit significant advantages over both sensible heat and phase change heat storages. This paper summarizes the developments in inorganic salt-H₂O systems, called hydrated salts, for the thermochemical adsorption heat storage, including typical thermal chemisorption materials and chemisorption reactors. Hydrated salts for the thermochemical adsorption heat storage usually contain halide-H₂O and sulphate-H₂O. Although hydrated salts have high heat storage densities, their application in the thermochemical adsorption system still faces some problems, including the degradation of kinetic properties and reactor corrosion caused by the deliquescence and expansion agglomeration of hydrated salts. As a carrier for hydrated salts, a porous material is expected to solve the current technical problems. Moreover, the development of new porous carriers and the structural optimization of the thermochemical adsorption heat storage systems are expected as the keys to promoting the industrialization of the thermochemical adsorption heat storage technology.

Key words: heat storage, thermochemical, adsorption, hydrated salts, adsorption system

中图分类号:

TK 229.92

翁立奎, 张叶龙, 姜琳, 贾亦轩, 谈玲华, 金翼, 丁玉龙. 基于水合盐的热化学吸附储热技术研究进展[J]. 储能科学与技术, 2020, 9(6): 1729-1736.

Likui WENG, Yelong ZHANG, Lin JIANG, Yixuan JIA, Linghua TAN, Yi JIN, Yulong DING. Research progress on thermochemical adsorption heat storage technology based on hydrate[J]. Energy Storage Science and Technology, 2020, 9(6): 1729-1736.

图/表 10

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基于水合盐的热化学吸附储热技术研究进展

Research progress on thermochemical adsorption heat storage technology based on hydrate

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