锂离子电池纳米硅碳负极材料研究进展

doi:10.19799/j.cnki.2095-4239.2020.0012

储能科学与技术 ›› 2020, Vol. 9 ›› Issue (2): 569-582.doi: 10.19799/j.cnki.2095-4239.2020.0012

• 庆祝陈立泉院士八十寿辰专刊 • 上一篇下一篇

锂离子电池纳米硅碳负极材料研究进展

周军华¹, 罗飞¹, 褚赓¹, 刘柏男², 陆浩², 郑杰允^1,^3,⁴, 李泓^1,^3,^4,⁵(), 黄学杰^3,⁵, 陈立泉^3,⁵

^1. 溧阳天目先导电池材料科技有限公司，江苏溧阳 213300
^2. 中国科学院化学研究所，北京 100190
^3. 中国科学院物理研究所，北京 100190
^4. 天目湖先进储能技术研究院，江苏溧阳 213300
^5. 中国科学院大学材料与光电研究中心，北京 100049

收稿日期:2020-01-05 修回日期:2020-02-08 出版日期:2020-03-05 发布日期:2020-03-15
通讯作者: 李泓 E-mail:hli@iphy.ac.cn
作者简介:周军华（1991—），男，博士研究生，主要研究方向为锂离子电池硅基负极材料，E-mail：zhoujunhua@iopsilion.com；
基金资助:
国家重点研发计划项目(2016YFB0100100)

Research progress on nano silicon-carbon anode materials for lithium ion battery

ZHOU Junhua¹, LUO Fei¹, CHU Geng¹, LIU Bonan², LU Hao², ZHENG Jieyun^1,^3,⁴, LI Hong^1,^3,^4,⁵(), HUANG Xuejie^3,⁵, CHEN Liquan^3,⁵

^1. Tianmulake Excellent Anode Materials Co. Ltd. , Liyang 213300, Jiangsu, China
^2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
^3. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
^4. Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, Jiangsu, China
^5. Center of Materials Science and Optoelectronics Engineering，University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-01-05 Revised:2020-02-08 Online:2020-03-05 Published:2020-03-15
Contact: Hong LI E-mail:hli@iphy.ac.cn

摘要/Abstract

摘要：

高能量密度锂离子二次电池对于缓解能源和环境危机具有重要意义。硅基材料理论比容量远超石墨，是目前公认的下一代锂离子电池负极材料。中国科学院物理研究所自1999年在国际上首次报道纳米化对于硅负极性能提升的重要作用以来，持续对纳米硅基材料的基础科学问题以及产业化应用进行了大量探索，主要包括纳米硅基负极材料的脱嵌锂机理、结构及形貌的动态演变过程、应力积累与裂纹的产生和SEI的三维可视化研究等内容。本文将对这些工作的一些基础研究进行总结，并对今后负极材料的发展提出自己的见解。

关键词: 锂离子电池, 负极材料, 硅

Abstract:

High-energy-density lithium-ion batteries are of great importance in alleviating the energy and environmental crisis. The theoretical specific capacity of silicon-based materials is much higher than that of graphite, which is now recognized as the next generation of anode materials for lithium-ion batteries. Since 1999, when the Institute of Physics of the Chinese Academy of Sciences first reported the important role of nanotechnology in improving the performance of silicon negative electrode, it has continued to explore many basic scientific issues and industrial applications of nano silicon-based materials by mainly focusing on the electrochemical mechanism of nano silicon-based negative electrode materials, the dynamic evolution process of their structure and morphology, generation of stress accumulation and cracks, and the three-dimensional feasibility of solid electrolyte interface (SEI) visual research. In this paper, some of these works are summarized and some opinions on the future development of anode materials are present.

Key words: lithium ion battery, anode materials, silicon

中图分类号:

TM 911

周军华, 罗飞, 褚赓, 刘柏男, 陆浩, 郑杰允, 李泓, 黄学杰, 陈立泉. 锂离子电池纳米硅碳负极材料研究进展[J]. 储能科学与技术, 2020, 9(2): 569-582.

ZHOU Junhua, LUO Fei, CHU Geng, LIU Bonan, LU Hao, ZHENG Jieyun, LI Hong, HUANG Xuejie, CHEN Liquan. Research progress on nano silicon-carbon anode materials for lithium ion battery[J]. Energy Storage Science and Technology, 2020, 9(2): 569-582.

图/表 8

参考文献 28

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锂离子电池纳米硅碳负极材料研究进展

Research progress on nano silicon-carbon anode materials for lithium ion battery

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