储能科学与技术 ›› 2021, Vol. 10 ›› Issue (1): 68-76.doi: 10.19799/j.cnki.2095-4239.2020.0289
李林林1(), 王昱杰1, 门一飞1, 杨伟1(), 邹汉波2, 陈胜洲2
收稿日期:
2020-08-27
修回日期:
2020-09-05
出版日期:
2021-01-05
发布日期:
2021-01-08
作者简介:
李林林(1995—),男,硕士研究生,研究方向为废旧锂离子电池回收,E-mail:基金资助:
Linlin LI1(), Yujie WANG1, Yifei MEN1, Wei YANG1(), Hanbo ZOU2, Shengzhou CHEN2
Received:
2020-08-27
Revised:
2020-09-05
Online:
2021-01-05
Published:
2021-01-08
摘要:
近几年电动汽车的迅速普及,使得锂离子电池的生产需求激增,因此废旧锂离子电池数量也迅速增长。废旧锂离子电池随意丢弃造成严重的环境污染,威胁人类健康,同时造成大量资源浪费。从环境保护和资源利用的角度来说,废旧锂离子电池的回收直接解决了资源分布不均衡以及环境污染等问题,因此,发展回收技术迫在眉睫。然而废旧锂离子电池的回收技术由于工艺流程复杂、成本高、二次污染等问题,未得到广泛的应用。目前湿法冶金技术是废旧锂离子电池回收方法中最具有前景的工艺,其工艺流程简单、回收利用率高、成本较低。本文详述了目前湿法冶金回收技术中无机酸作为浸出剂的研究进展,着重介绍了几种常用无机酸的特点,重点比较了各种无机酸在浸出过程中的反应条件和金属浸出效率,此外还对浸出过程中热力学反应机理进行了分析。在今后的研究中,应大力推进废旧锂离子电池回收技术的发展,寻求一个更加环保、通用的工艺,同时还应重点研究反应机理,探索更加高效的回收方法。
中图分类号:
李林林, 王昱杰, 门一飞, 杨伟, 邹汉波, 陈胜洲. 湿法冶金回收技术中无机酸作为浸出剂的研究进展[J]. 储能科学与技术, 2021, 10(1): 68-76.
Linlin LI, Yujie WANG, Yifei MEN, Wei YANG, Hanbo ZOU, Shengzhou CHEN. Research progress of inorganic acids in hydrometallurgical recovery technology[J]. Energy Storage Science and Technology, 2021, 10(1): 68-76.
1 | ZHANG Xihua, XIE Yongbing, LIN Xiao, et al. An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries[J]. Journal of Material Cycles and Waste Management, 2013, 15(4): 420-430. |
2 | LIANG Yuhan, SU Jing, XI Beidou, et al. Life cycle assessment of lithium-ion batteries for greenhouse gas emissions[J]. Resources, Conservation and Recycling, 2017, 117: 285-293. |
3 | ORDOÑEZ J, GAGO E J, GIRARD A. Processes and technologies for the recycling and recovery of spent lithium-ion batteries[J]. Renewable and Sustainable Energy Reviews, 2016, 60: 195-205. |
4 | 李金东, 古月圆, 王路阳, 等. 退役锂离子电池健康状态评估方法综述[J]. 储能科学与技术, 2019, 8(5): 807-812. |
LI Jindong, GU Yueyuan, WANG Luyang, et al. Review on state of health estimation of retired lithium-ion batteries[J]. Energy Storage Science and Technology, 2019, 8(5): 807-812. | |
5 | 朱国才. 废旧动力锂离子电池回收再利用产业化进展[J]. 新材料产业, 2018(3): 31-33. |
ZHU Guocai. Progress in industrialization of recycling and reuse of used power lithium ion batteries[J]. Advanced Materials Industry, 2018(3): 31-33. | |
6 | RICHA K, BABBITT C W, GAUSTAD G, et al. A future perspective on lithium-ion battery waste flows from electric vehicles[J]. Resources, Conservation and Recycling, 2014, 83: 63-76. |
7 | BIGUM M, DAMGAARD A, SCHEUTZ C, et al. Environmental impacts and resource losses of incinerating misplaced household special wastes (WEEE, batteries, ink cartridges and cables)[J]. Resources, Conservation and Recycling, 2017, 122: 251-260. |
8 | PUCA A, CARRANO M, LIU Gengyuan, et al. Energy and eMergy assessment of the production and operation of a personal computer[J]. Resources, Conservation and Recycling, 2017, 116: 124-136. |
9 | JAGANNATH A, SHETTY K V, SAIDUTTA M B. Bioleaching of copper from electronic waste using Acinetobacter sp. Cr B2 in a pulsed plate column operated in batch and sequential batch mode[J]. Journal of Environmental Chemical Engineering, 2017, 5(2): 1599-1607. |
10 | WEI Jucai, ZHAO Shichang, JI Liangxin, et al. Reuse of Ni-Co-Mn oxides from spent Li-ion batteries to prepare bifunctional air electrodes[J]. Resources, Conservation and Recycling, 2018, 129: 135-142. |
11 | 陈永珍, 黎华玲, 宋文吉, 等. 废旧磷酸铁锂电池回收技术研究进展[J]. 储能科学与技术, 2019, 8(2): 237-247. |
CHEN Yongzhen, LI Hualiang, SONG Wenji, et al. A review on recycling technology of spent lithium iron phosphate battery[J]. Energy Storage Science and Technology, 2019, 8(2): 237-247. | |
12 | 卫寿平, 孙杰, 周添, 等. 废旧锂离子电池中金属材料回收技术研究进展[J]. 储能科学与技术, 2017, 6(6): 1196-1207. |
WEI Shouping, SUN Jie, ZHOU Tian, et al. Research development of metals recovery from spent lithium-ion batteries[J]. Energy Storage Science and Technology, 2017, 6(6): 1196-1207. | |
13 | 楼平, 徐国华, 岳灵平, 等. 熔盐法再生修复退役三元动力电池正极材料[J]. 储能科学与技术, 2020, 9(3): 848-855. |
LOU Ping, XU Guohua, YUE Lingping, et al. Degraded LixNi0.5Co0.2Mn0.3O2(0<x<1) via eutectic solutions for direct regeneration of spent lithium ion battery cathodes[J]. Energy Storage Science and Technology, 2020, 9(3): 848-855. | |
14 | INNOCENZI V, IPPOLITO N M, DE MICHELIS I, et al. A review of the processes and lab-scale techniques for the treatment of spent rechargeable NiMH batteries[J]. Journal of Power Sources, 2017, 362: 202-218. |
15 | SUN Zhi, CAO Hongbin, ZHANG Xihua, et al. Spent lead-acid battery recycling in China—A review and sustainable analyses on mass flow of lead[J]. Waste Management, 2017, 64: 190-201. |
16 | WANG Wei, WU Yufeng. An overview of recycling and treatment of spent LiFePO4 batteries in China[J]. Resources, Conservation and Recycling, 2017, 127: 233-243. |
17 | 钟雪虎, 焦芬, 刘桐, 等. 废旧锂离子电池回收工艺概述[J]. 电池, 2018, 48(1): 63-67. |
ZHONG Xuehu, JIAO Fen, LIU Tong, et al. Overview of recovery technology for spent Li-ion battery[J]. Battery Bimonthly, 2018, 48(1): 63-67. | |
18 | BAHALOO-HOREH N, MOUSAVI S M. Enhanced recovery of valuable metals from spent lithium-ion batteries through optimization of organic acids produced by Aspergillus niger[J]. Waste Management, 2017, 60: 666-679. |
19 | HOREH N B, MOUSAVI S M, SHOJAOSADATI S A. Bioleaching of valuable metals from spent lithium-ion mobile phone batteries using Aspergillus niger[J]. Journal of Power Sources, 2016, 320: 257-266. |
20 | 李肖肖, 王楠, 郭盛昌, 等. 废旧动力锂离子电池回收的研究进展[J]. 电池, 2017, 47(1): 52-55. |
LI Xiaoxiao, WANG Nan, GUO Shengchang, et al. Research progress in recycling of spent power Li-ion battery[J]. Battery Bimonthly, 2017, 47(1): 52-55. | |
21 | GARCIA E M, SANTOS J S, PEREIRA E C, et al. Electrodeposition of cobalt from spent Li-ion battery cathodes by the electrochemistry quartz crystal microbalance technique[J]. Journal of Power Sources, 2008, 185(1): 549-553. |
22 | 朱显峰, 赵瑞瑞, 常毅, 等. 废旧锂离子电池三元正极材料酸浸研究[J]. 电池, 2017, 47(2): 105-108. |
ZHU Xianfeng, ZHAO Ruirui, CHANG Yi, et al, Study on the acid leaching of ternary anode materials in spent Li-ion battery[J]. Battery Bimonthly, 2017, 47(2): 105-108. | |
23 | 沈棒, 顾卫星, 袁海平, 等. 废旧三元锂离子电池浸出及纯化技术研究进展[J]. 环境科学与技术, 2018, 41(2): 114-121. |
SHEN Bang, GU Weixing, YUAN Haiping, et al. A review on leaching and purification technologies of spent ternary Li-ion batteries[J]. Environmental Science & Technology, 2018, 41(2): 114-121. | |
24 | TESFAYE F, LINDBERG D, HAMUYUNI J, et al. Improving urban mining practices for optimal recovery of resources from e-waste[J]. Minerals Engineering, 2017, 111: 209-221. |
25 | INNOCENZI V, DE MICHELIS I, VEGLIÒ F. Design and construction of an industrial mobile plant for WEEE treatment: Investigation on the treatment of fluorescent powders and economic evaluation compared to other e-wastes[J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 80: 769-778. |
26 | YAO Yonglin, ZHU Meiying, ZHAO Zhuo, et al. Hydrometallurgical processes for recycling spent lithium-ion batteries: A critical review[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(11): 13611-13627. |
27 | 邓浩臻, 张帆, 文小强, 等. 稀硫酸优浸工艺分离废旧钛酸锂材料中锂钛的研究[J]. 稀有金属与硬质合金, 2019, 47(3): 17-20+85. |
DENG Haozhen, ZHAG Fan, WEN Xiaoqiang, et al. Reaserach on separation of lithium and titanium from waste lithium titanate materials by dilute sulfuric acid preferential leaching[J]. Rare Metals and Cemented Carbides, 2019, 47(3): 17-20+85. | |
28 | ROCCHETTI L, VEGLIÒ F, KOPACEK B, et al. Environmental impact assessment of hydrometallurgical processes for metal recovery from WEEE residues using a portable prototype plant[J]. Environmental Science & Technology, 2013, 47: 1581-1588. |
29 | BARIK S P, PRABAHARAN G, KUMAR L. Leaching and separation of Co and Mn from electrode materials of spent lithium-ion batteries using hydrochloric acid: Laboratory and pilot scale study[J]. Journal of Cleaner Production, 2017, 147: 37-43. |
30 | TAKACOVA Z, HAVLIK T, KUKURUGYA F, et al. Cobalt and lithium recovery from active mass of spent Li-ion batteries: Theoretical and experimental approach[J]. Hydrometallurgy, 2016, 163: 9-17. |
31 | WANG Rongchi, LIN Yuchuan, WU Shehuang. A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries[J]. Hydrometallurgy, 2009, 99(3): 194-201. |
32 | LI Jinhui, SHI Pixing, WANG Zefeng, et al. A combined recovery process of metals in spent lithium-ion batteries[J]. Chemosphere, 2009, 77(8): 1132-1136. |
33 | ZHANG P W, YOKOYAMA T, ITABASHI O, et al. Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries[J]. Hydrometallurgy, 1998, 47(2): 259-271. |
34 | LI Jinhui, LI Xinhai, HU Qiyang, et al. Study of extraction and purification of Ni, Co and Mn from spent battery material[J]. Hydrometallurgy, 2009, 99(1): 7-12. |
35 | MESHRAM P, PANDEY B D, MANKHAND T R. Recovery of valuable metals from cathodic active material of spent lithium ion batteries: Leaching and kinetic aspects[J]. Waste Management, 2015, 45: 306-313. |
36 | MESHRAM P, PANDEY B D, MANKHAND T R. Hydrometallurgical processing of spent lithium ion batteries(LIBs) in the presence of a reducing agent with emphasis on kinetics of leaching[J]. Chemical Engineering Journal, 2015, 281: 418-427. |
37 | JHA M K, KUMARI A, JHA A K, et al. Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone[J]. Waste Management, 2013, 33(9): 1890-1897. |
38 | BERTUOL D A, MACHADO C M, SILVA M L, et al. Recovery of cobalt from spent lithium-ion batteries using supercritical carbon dioxide extraction[J]. Waste Management, 2016, 51: 245-251. |
39 | 黎华玲, 陈永珍, 宋文吉, 等. 湿法回收退役三元锂离子电池有价金属的研究进展[J]. 化工进展, 2019, 38(2): 217-228. |
LI Hualing, CHEN Yongzhen, SONG Wenji, et al. Research progress on the recovery of valuable metals in retired LiNixCoyMnzO2 batteries by wet process[J]. Chemical Industry and Engineering Progress, 2019, 38(2): 217-228. | |
40 | SHIN S M, KIM N H, SOHN J S, et al. Development of a metal recovery process from Li-ion battery wastes[J]. Hydrometallurgy, 2005, 79(3): 172-181. |
41 | KANG J, SENANAYAKE G, SOHN J, et al. Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272[J]. Hydrometallurgy, 2010, 100(3): 168-171. |
42 | 王筱彤, 张基伟, 刘聪, 等. 硫酸法回收废旧手机锂离子电池中钴的研究[J]. 绿色科技, 2016(14): 164-165. |
WANG Xiaotong, ZHANG Jiwei, LIU Cong, et al. Study on the recovery of cobalt in Li-ion battery of used mobile phone by sulfuric acid method[J]. Journal of Green Science and Technology, 2016(14): 164-165. | |
43 | PINNA E G, RUIZ M C, OJEDA M W, et al. Cathodes of spent Li-ion batteries: Dissolution with phosphoric acid and recovery of lithium and cobalt from leach liquors[J]. Hydrometallurgy, 2017, 167: 66-71. |
44 | CHEN Xiangping, MA Hongrui, LUO Chuanbao, et al. Recovery of valuable metals from waste cathode materials of spent lithium-ion batteries using mild phosphoric acid[J]. Journal of Hazardous Materials, 2017, 326: 77-86. |
45 | LEE Churlkyoung, RHEE Kangin. Preparation of LiCoO2 from spent lithium-ion batteries[J]. Journal of Power Sources, 2002, 109(1): 17-21. |
46 | LI Li, CHEN Renjie, SUN Feng, et al. Preparation of LiCoO2 films from spent lithium-ion batteries by a combined recycling process[J]. Hydrometallurgy, 2011, 108(3): 220-225. |
47 | JOULIÉ M, LAUCOURNET R, BILLY E. Hydrometallurgical process for the recovery of high value metals from spent lithium nickel cobalt aluminum oxide based lithium-ion batteries[J]. Journal of Power Sources, 2014, 247: 551-555. |
48 | LYU Weiguang, WANG Zhonghang, CAO Hongbin, et al. A sustainable process for metal recycling from spent lithium-ion batteries using ammonium chloride[J]. Waste Management, 2018, 79: 545-553. |
49 | GAO Wenfang, LIU Chenming, CAO Hongbin, et al. Comprehensive evaluation on effective leaching of critical metals from spent lithium-ion batteries[J]. Waste Management, 2018, 75: 477-485. |
50 | EL HAZEK M N, LASHEEN T A, HELAL A S. Reductive leaching of manganese from low grade Sinai ore in HCl using H2O2 as reductant[J]. Hydrometallurgy, 2006, 84(3): 187-191. |
51 | XUAN W, OTSUKI A, CHAGNES A. Investigation of the leaching mechanism of NMC811 (LiNi0.8Mn0.1Co0.1O2) by hydrochloric acid for recycling lithium ion battery cathodes[J]. RSC Advances, 2019, 9(66): 38612-38618. |
52 | SAYILGAN E, KUKRER T, YIGIT N O, et al. Acidic leaching and precipitation of zinc and manganese from spent battery powders using various reductants[J]. Journal of Hazardous Materials, 2010, 173(1): 137-143. |
53 | HUANG Yanfang, HAN Guihong, LIU Jiongtian, et al. A stepwise recovery of metals from hybrid cathodes of spent Li-ion batteries with leaching-flotation-precipitation process[J]. Journal of Power Sources, 2016, 325: 555-564. |
54 | LIU Kang, ZHANG Fushen. Innovative leaching of cobalt and lithium from spent lithium-ion batteries and simultaneous dechlorination of polyvinyl chloride in subcritical water[J]. Journal of Hazardous Materials, 2016, 316: 19-25. |
55 | 刘小娟, 凌雨轩, 成江涛, 等. 废旧钴酸锂离子电池材料中钴、锂的回收工艺研究[J]. 湖南工程学院学报(自然科学版), 2019, 29(4): 67-71. |
LIU Xiaojuan, LING Yuxuan, CHENG Jiangtao, et al. Study on recycling of spent lithiumion batteries containing cobalt and lithium[J]. Journal of Hunan Institute of Engineering, 2019, 29(4): 67-71. | |
56 | LI Huan, XING Shengzhou, LIU Yu, et al. Recovery of lithium, iron, and phosphorus from spent LiFePO4 batteries using stoichiometric sulfuric acid leaching system[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(9): 8017-8024. |
57 | 祝宏帅, 孙金峰, 胡启阳, 等. 磷酸体系应用于失效磷酸铁锂电池正极材料回收的研究[J]. 高校化学工程学报, 2017, 31(5): 1238-1244. |
ZHU Hongshuai, SUN Jinfeng, HU Qiyang, et al. Application of phosphoric acid system in positive electrode material recovery from invalid lithium iron phosphate batteries[J]. Journal of Chemical Engineering of Chinese Universities, 2017, 31(5): 1238-1244. | |
58 | YANG Yang, GUO Jinzhi, GU Zhenyi, et al. Effective recycling of the whole cathode in spent lithium ion batteries: From the widely used oxides to high-energy/stable phosphates[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(14): 12014-12022. |
59 | PENG Chao, LIU Fupeng, WANG Zulin, et al. Selective extraction of lithium (Li) and preparation of battery grade lithium carbonate(Li2CO3) from spent Li-ion batteries in nitrate system[J]. Journal of Power Sources, 2019, 415: 179-188. |
60 | ZHANG Qiwu, LU Jinfeng, SAITO Fumio, et al. Room temperature acid extraction of Co from LiCo0.2Ni0.8O2 scrap by a mechanochemical treatment[J]. Advanced Powder Technology, 2000, 11(3): 353-359. |
61 | SAEKI Shu, LEE Jaeryeong, ZHANG Qiwu, et al. Co-grinding LiCoO2 with PVC and water leaching of metal chlorides formed in ground product[J]. International Journal of Mineral Processing, 2004, 74: S373-S378. |
62 | WANG Bin, LIN Xinye, TANG Yuanyuan, et al. Recycling LiCoO2 with methanesulfonic acid for regeneration of lithium-ion battery electrode materials[J]. Journal of Power Sources, 2019, 436: doi: 10.1016/j.jpowsour.2019.226828. |
63 | ZOU H Y, GRATZ E, APELIAN D, et al. A novel method to recycle mixed cathode materials for lithium ion batteries[J]. Green Chemistry, 2013, 15(5): 1183-1191. |
64 | SETIAWAN H, PETRUS H T B M, PERDANA I. Reaction kinetics modeling for lithium and cobalt recovery from spent lithium-ion batteries using acetic acid[J]. International Journal of Minerals, Metallurgy, and Materials, 2019, 26(1): 98-107. |
65 | TAO Shengdong, LI Jian, WANG Lihua, et al. A method for recovering Li3PO4 from spent lithium iron phosphate cathode material through high-temperature activation[J]. Ionics , 2019, 25(12): 5643-5653. |
66 | LIU Pengcheng, YANG Xinran, XIAO Li, et al. Preparation of ternary precursor derived from spent LiNixCoyMn1-x-yO2 materials[J]. JOM, 2019, 71(12): 4492-4499. |
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