红柳基锂电池负极材料的制备及电化学性能

doi:10.19799/j.cnki.2095-4239.2021.0170

储能科学与技术 ›› 2021, Vol. 10 ›› Issue (6): 2082-2089.doi: 10.19799/j.cnki.2095-4239.2021.0170

红柳基锂电池负极材料的制备及电化学性能

苏少鹏¹(), 李进¹(), 张佃平^1,², 李严¹, 席文¹, 李杨¹

^1.宁夏光伏材料重点实验室
^2.宁夏大学机械工程学院，宁夏银川 750021

收稿日期:2021-04-21 修回日期:2021-06-09 出版日期:2021-11-05 发布日期:2021-11-03
作者简介:苏少鹏（1994—），男，硕士研究生，研究方向为锂电负极材料，E-mail：Su0213mail@163.com|李进，教授，从事复合材料研究，E-mail: li-jin@163.com。
基金资助:
国家自然科学基金重点项目(51962030);宁夏自然科学基金项目(2020AAC03007)

Preparation and electrochemical properties of negative eletrode materials for tamarium-based lithiumion batteries

Shaopeng SU¹(), Jin LI¹(), Dianping ZHANG^1,², Yan LI¹, Wen XI¹, Yang LI¹

^1.Ningxia Key Laboratory of Photovoltaic Materials
^2.School of Mechanics Engineering, Ningxia University, Yinchuan 750021, Ningxia, China

Received:2021-04-21 Revised:2021-06-09 Online:2021-11-05 Published:2021-11-03

摘要/Abstract

摘要：

以中国西北地区特色植物红柳为碳源，经过干燥、热解和酸洗等处理，通过机械破碎的方法制得纳米碳颗粒(CRN)，以其为主要活性材料制备了锂电池硬碳负极并研究了电化学性能。利用X射线衍射仪(XRD)、激光显微拉曼光谱仪(Raman)以及扫描电镜(SEM)，分别对所制备CRN的物相结构、石墨化程度和表面形貌进行对比分析。采用恒流充放电对所制备的负极材料进行比容量、倍率和循环稳定性测试，使用电化学工作站(CHI660E)分析了负极材料的交流阻抗(EIS)和循环伏安(CV)。结果表明，干燥后的红柳经过500、600、700和800 ℃的低温热解和HCl酸洗处理后，低温热解温度为600 ℃时所制得的CRN循环稳定性、比容量和倍率性能最佳。本研究表明，以红柳为碳源制备的CRN完全可以用于锂电池负极材料。

关键词: 红柳, 低温热解, 锂离子电池, 电化学性能

Abstract:

Nanocarbon particles (CRN) were prepared from red willow, which mostly exists planted in the northwest of China, processed by the mechanical crushing method after drying, pyrolysis, and pickling treatment processing. The electrochemical properties of a lithium-ion anode based primarily on CRN were investigated. X-ray diffractometry (XRD), Raman, and scanning electron microscopy (SEM) were used to examine the phase structure, degree of graphitization, and surface topography, respectively. Constant current charge and discharge were used to test the anode's specific capacity, magnification, and cycle stability. An electrochemical work-station was used to analyze the anode's electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) (CHI660E). The results show that the CRN prepared at 600 ℃ in the pyrolyzed temperature (500 ℃, 600 ℃, 700 ℃, and 800 ℃) has better cycle stability, higher specific capacity, and the best magnification. This study shows that the CRN prepared from red willow can be used properly as the anode of lithium-ion batteries.

Key words: red willow, low temperature pyrolysis, lithium-ion battery, eletrochemical properties

中图分类号:

TQ 152

苏少鹏, 李进, 张佃平, 李严, 席文, 李杨. 红柳基锂电池负极材料的制备及电化学性能[J]. 储能科学与技术, 2021, 10(6): 2082-2089.

Shaopeng SU, Jin LI, Dianping ZHANG, Yan LI, Wen XI, Yang LI. Preparation and electrochemical properties of negative eletrode materials for tamarium-based lithiumion batteries[J]. Energy Storage Science and Technology, 2021, 10(6): 2082-2089.

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红柳基锂电池负极材料的制备及电化学性能

Preparation and electrochemical properties of negative eletrode materials for tamarium-based lithiumion batteries

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