封装PCM陶瓷储热材料的性能

储能科学与技术 ›› 2012, Vol. 1 ›› Issue (2): 123-130.

封装PCM陶瓷储热材料的性能

冷光辉¹, 吴建锋², 徐晓虹²

1 中国科学院过程工程研究所,北京 100190;
2 武汉理工大学材料科学与工程学院,湖北武汉 430070

收稿日期:2012-06-29 出版日期:2012-11-19 发布日期:2012-11-19
通讯作者: 吴建锋,博士,教授,博士生导师,研究方向为陶瓷材料,储热材料及储热系统,E-mail:wujf@whut.edu.cn.
作者简介:冷光辉(1984--),男,博士,研究方向为储热材料及系统,E-mail:a280794125@163.com
基金资助:
国家重点基础研究发展计划(973)项目(2010CB227105)

Encapsulation of PCM in ceramic thermal energy storage materials

LENG Guanghui¹, WU Jianfeng², XU Xiaohong²

1 Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China;
2 School of Material Science and Engineering,Wuhan University of Technology,Wuhan 430070,Hubei,China

Received:2012-06-29 Online:2012-11-19 Published:2012-11-19

摘要/Abstract

摘要： 以红柱石为主要原料,采用原位生成堇青石技术制备高温性能优良的红柱石蜂窝陶瓷储热材料.再利用特制的封装剂将相变材料(PCM)封装在部分蜂窝陶瓷孔中,制备储热密度大的显热-潜热高温复合储热材料.采用SEM,EPMA,TG-DTA等测试方法对封装剂与陶瓷基体的结合性,PCM与陶瓷基体的适应性及复合储热材料的储热密度进行研究.结果表明红柱石蜂窝陶瓷能安全地封装PCM,封装质量分数为20%的K₂SO₄后的储热密度为987.70 kJ/kg(0~1080 ℃),封装质量分数为16%的NaCl复合储热密度为796.40 kJ/kg(0~810 ℃).制备的复合储热材料具有较高的储热密度,能实现高温储热.

关键词: 储热材料, 红柱石蜂窝陶瓷, 显热-潜热复合储热, 封装剂, 高温高效

Abstract: This study is concerned about encapsulation of phase change materials (PCM) with a ceramic honeycomb structure to give composite PCM. K₂SO₄ and NaCl were used as the PCM, whereas the honeycomb structure was made of cordierite synthesized in-situ with andalusite as the main raw material. A special agent was developed to seal the opening of the honeycomb pores filled with the PCM. A number of techniques were used to characterize the properties of the prepared composite PCM, including SEM, EPMA, TG-DTA and so on. It was shown that andalusite based ceramic honeycomb structures and the sealing agent can effectively encapsulate the PCMs. The prepared thermal storage density of the composite material containing 20% K₂SO₄ was around 987.70 kJ/kg (0~1080 ℃), whereas that with 16% NaCl was 796.40 kJ/kg (0~810 ℃).

Key words: thermal energy storage materials, andalusite based honeycomb ceramic, sensible-latent composite thermal storage, package agent, encapsulation

中图分类号:

TK02

冷光辉, 吴建锋, 徐晓虹. 封装PCM陶瓷储热材料的性能[J]. 储能科学与技术, 2012, 1(2): 123-130.

LENG Guanghui, WU Jianfeng, XU Xiaohong. Encapsulation of PCM in ceramic thermal energy storage materials[J]. Energy Storage Science and Technology, 2012, 1(2): 123-130.

参考文献

[1] Agyenima F,Hewitt N,Eames P,et al. A review of materials,heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS)[J]. Renewable and Sustainable Energy Reviews ,2010,14(2):615-628.
[2] Zalba B,Marin M J,Cabeza F L,et al. Review on thermal energy storage with phase change:Materials,heat transfer analysis and applications[J]. Applied Thermal Engineering ,2003,23:251-283.
[3] Liu Ming,Saman W,Bruno F. Review on storage materials and thermal performance enhancement techniques for high temperature phase change thermal storage systems[J]. Renewable and Sustainable Energy Reviews ,2012,16(4):2118-2132.
[4] Arteconi A,Hewitt N J,Polonara F. State of the art of thermal storage for demand-side management[J]. Applied Energy ,2012,93:371-389.
[5] Bai Fengwu,Xu Chao. Performance analysis of a two-stage thermal energy storage system using concrete and steam accumulator[J]. Applied Thermal Engineering ,2011,31(14-15):2764-2771.
[6] 吴会军,朱冬生,李军,等. 储热材料的研究进展[J]. 材料导报,2005,19(8):96-98.
[7] 张国才,徐哲,陈运法,等. 金属基相变材料的研究进展及应用[J]. 储能科学与技术,2012,1(1):74-81.
[8] Gluck A,Tamme R,Kalaf H,et al. Development and testing of advanced TES materials for solar thermal central receier plants[C]//Proceedings of Solar World Congress. Denver:Pergamon Press,1991:1943-1948.
[9] Hahne E,Taut U,Grob Y. Salt ceramic themral energy storage for solar thermal central receier plants[C]//Proceedings of Solar World Congress. Denver:Pergamon Press,1991:1937-1942.
[10] Steiner D,Wierse M,Groll M. Development and Investigation of Thermal Energy Storage Systems for the Media Temperature Range[C]//Proceedings of the 30 th IECEC. New York:American Society of Mechanical Engineers,1995:193-198.
[11] Schwerin M,Listle W. Development of a latent heat storage system with ceramic matrix for utilization of industrial waste heat[C]//Final Report. Germany:ALPHA Labor,GmbH,Ismaning,1995.
[12] Nomura T,Okinaka N,Akiyama T. Impregnation of porous material with phase change material for thermal energy storage[J]. Materials Chemistry and Physics ,2009,115(2-3):846-850.
[13] 张兴雪,王华,王胜林. MgO陶瓷基复合相变蓄热材料的制备和性能研究[J]. 工业加热,2006,35(1):7-9.
[14] 黄金. 融盐自发浸渗用微米级多孔陶瓷预制体的烧制[J].材料导报,2006,20(5):126-135.
[15] 王雪松,李朝祥,樊远,等.红柱石矽线石矿物陶瓷储热材料的性能[J]. 矿产综合利用,2006(2):21-25.
[16] Bejjaoui R,Benhammou A,Nibou L,et al. Synthesis and characterization of cordierite ceramic from Moroccan stevensite and andalusite [J]. Applied Clay Science ,2010,49(3):336-340.
[17] Butt D P,Mecholsky J J. Effects of sodium silicate exposure at high temperature on sintered α-silicon carbide and siliconized silicon carbide [J]. Journal of the American Ceramic Society ,1989,72(9):1628-1635.
[18] 王华,Ito Y,Nohira T,等. 新型陶瓷与熔融盐复合储热材料优化组合的数值模拟[J]. 中国有色金属学报,2002,12(3):550-555.
[19] 张仁元,柯秀芳,李爱菊. 无机盐/陶瓷基复合储能材料的制备和性能[J]. 材料研究学报,2000,14(6):652-656.
[20] Tamme R,Taut U,Streuber C,et al. Energy storage development for solar thermal process[J]. Solar Energy Materials ,1991,24(1-4):386-396.
[21] 李爱菊,王毅. Na 2 SO 4 /SiO 2 复合储能材料制备工艺和性能的研究[J]. 华南师范大学学报:自然科学版,2008(1):82-87.