钠离子电池层状正极材料研究进展

doi:10.19799/j.cnki.2095-4239.2020.0130

摘要/Abstract

摘要：

由于地球钠元素资源丰富、来源广泛，钠离子电池被认为是将来能够替代锂离子电池用于大规模储能的新型二次电池技术之一。正极材料作为钠离子电池的重要组成部分，决定了钠离子电池电化学性能的优劣。然而由于钠离子半径较大，开发结构稳定且具有快速钠离子扩散性能的正极材料是获得高性能钠离子电池的挑战之一。近年来，越来越多的层状正极材料体系被开发出来，并展现出良好的电化学性能，对于钠离子电池具有较好的应用前景。本文综述了目前常见的层状钠离子电池正极材料，重点分析和探讨了层状钠离子电池正极材料的储钠机制，并展望了未来钠离子电池正极材料的发展趋势及应用前景。

关键词: 钠离子电池, 正极材料, 层状过渡金属氧化物, 锰基体系

Abstract:

Na-ion batteries are regarded as a potential new rechargeable battery technology to replace lithium-ion batteries for large-scale energy storage applications in the future due to the rich abundance of Na sources and their low cost. Cathode materials, an important component of Na-ion batteries, determine the electrochemical performance of Na-ion batteries. Due to the large ionic radius of Na⁺ ions, developing cathode materials with stable structures and fast Na⁺ ion diffusion is still a significant challenge. Recently, many layered materials have been explored as cathodes with promising electrochemical performances, exhibiting great potential for application in Na-ion batteries. In this review, recently reported layered cathode materials are summarized and their Na storage mechanisms are carefully analyzed and discussed. Finally, perspectives on the future development of layered cathodes and their potential applications in Na-ion batteries are provided.

Key words: sodium-ion batteries, cathode material, layered transition metal oxides, Mn-based systems

中图分类号:

TM 912

朱晓辉, 庄宇航, 赵旸, 倪明珠, 徐璟, 夏晖. 钠离子电池层状正极材料研究进展[J]. 储能科学与技术, 2020, 9(5): 1340-1349.

Xiaohui ZHU, Yuhang ZHUANG, Yang ZHAO, Mingzhu NI, Jing XU, Hui XIA. Development of layered cathode materials for sodium-ion batteries[J]. Energy Storage Science and Technology, 2020, 9(5): 1340-1349.

图/表 2

参考文献 55

1	ARMAND M, TARASCON J M. Building better batteries[J]. Nature, 2008, 451: 652-657.
2	BLOMGREN G E. The development and future of lithium ion batteries[J]. Journal of the Electrochemical Society, 2017, 164: A5019-A5025.
3	BRACONNIER J J, DELMAS C, FOUASSIER C, et al. Electrochemical behavior of the phases Na_xCoO₂[J]. Materials Research Bulletin, 1980, 15: 1797-1804.
4	NAGELBERG A S, WORRELL W L. Thermodynamic study of sodium-intercalated TaS₂ and TiS₂[J]. Journal of Solid State Chemistry, 1979, 29: 345-354.
5	PARANT J P, OLAZCUAG R, DEVALETT M, et al. New phases of formula Na_xMnO₂ (x less than or equal to 1)[J]. Journal of Solid State Chemistry, 1971, 3: 1-5.
6	WHITTINGHAM M S. Chemistry of intercalation compounds: Metal guests in chalcogenide hosts[J]. Progress in Solid State Chemistry, 1978, 12: 41-99.
7	QIAN J F, ZHOU M, CAO Y L, et al. Nanosized Na₄Fe(CN)₆/C composite as a low-cost and high-rate cathode material for sodium-ion batteries[J]. Advanced Energy Materials, 2012, 2: 410-414.
8	KIM S W, SEO D H, MA X, et al. Electrode materials for rechargeable sodium-ion batteries: Potential alternatives to current lithium-ion batteries[J]. Advanced Energy Materials, 2012, 2: 710-721.
9	MENDIBOURE A, DELMAS C, HAGENMULLER P. Electrochemical intercalation and deintercalation of Na_xMnO₂ bronzes[J]. Journal of Solid State Chemistry, 1985, 57: 323-331.
10	DELMAS C, FOUASSIER C, HAGENMULLER P. Structural classification and properties of the layered oxides[J]. Physica B+C, 1980, 99: 81-85.
11	GUO S, YI J, SUN Y, et al. Recent advances in titanium-based electrode materials for stationary sodium-ion batteries[J]. Energy & Environmental Science, 2016, 9: 2978-3006.
12	DELMAS C, BRACONNIER J J, MAAZAZ A, et al. Soft chemistry in A_xMO₂ sheet oxides[J]. Revue de Chimie Minérale, 1982, 19: 343-351.
13	MAAZAZ A, DELMAS C, HAGENMULLER P. A study of the Na_xTiO₂ system by electrochemical deintercalation[J]. Journal of Inclusion Phenomena, 1983, 1: 45-51.
14	BRACONNIER J J, DELMAS C, HAGENMULLER P. Etude par desintercalation electrochimique des systemes Na_xCrO₂ et Na_xNiO₂[J]. Materials Research Bulletin, 1982, 17: 993-1000.
15	ZHAO J, ZHAO L W, DIMOV N, et al. Electrochemical and thermal properties of α-NaFeO₂ cathode for Na-ion batteries[J]. Journal of the Electrochemical Society, 2013, 160: A3077-A3081.
16	LI Y, GAO Y, WANG X, et al. Iron migration and oxygen oxidation during sodium extraction from NaFeO₂[J]. Nano Energy, 2018, 47: 519-526.
17	LEE E, BROWN D E, ALP E E, et al. New insights into the performance degradation of Fe-based layered oxides in sodium-ion batteries: Instability of Fe³⁺/Fe⁴⁺ redox in α-NaFeO₂[J]. Chemistry of Materials, 2015, 27: 6755-6764.
18	LI X, WANG Y, WU D, et al. Jahn-Teller assisted Na diffusion for high performance Na ion batteries[J]. Chemistry of Materials, 2016, 28: 6575-6583.
19	ZHOU Y N, DING J J, NAM K M, et al. Phase transition behavior of NaCrO₂ during sodium extraction studied by synchrotron-based X-ray diffraction and absorption[J]. Journal of Materials Chemistry A, 2013, 1: 11130-11134.
20	LEI Y, LI X, LIU L, et al. Synthesis and stoichiometry of different layered sodium cobalt oxides[J]. Chemistry of Materials, 2014, 26: 5288-5296.
21	WANG L, WANG J, ZHANG X, et al. Unravelling the origin of irreversible capacity loss in NaNiO₂ for high voltage sodium ion batteries[J]. Nano Energy, 2017, 34: 215-223.
22	KUBOTA K, IKEUCHI I, NAKAYAMA T, et al. New insight into structural evolution in layered NaCrO₂ during electrochemical sodium extraction[J]. The Journal of Physical Chemistry C, 2015, 119: 166-175.
23	KUBOTA K K, YABUUCHI N, YOSHIDA H, et al. Layered oxides as positive electrode materials for Na-ion batteries[J]. MRS Bulletin, 2014, 39: 416-422.
24	KUBOTA K, KUMAKURA S, YODA Y, et al. Electrochemistry and solid-state chemistry of NaMeO₂ (Me=3d transition metals)[J]. Advanced Energy Materials, 2018, 8: doi: 10.1002/aenm.201703415.
25	BILLAUD J, CLÉMENT R J, ARMSTRONG A R, et al. β-NaMnO₂: A high-performance cathode for sodium-ion batteries[J]. Journal of the American Chemical Society, 2014, 136: 17243-17248.
26	BERTHELOT R, CARLIER D, DELMAS C. Electrochemical investigation of the P2-Na_xCoO₂ phase diagram[J]. Nature Materials, 2011, 10: 74-80.
27	KUMAKURA S, TAHARA Y, KUBOTA K, et al. Sodium and manganese stoichiometry of P2-type Na_2/3MnO₂[J]. Angewandte Chemie International Edition, 2016, 128: 12952-12955.
28	CLÉMENT R J, BRUCE P G, GREY C P. Manganese-based P2-type transition metal oxides as sodium-ion battery cathode materials[J]. Journal of the Electrochemical Society, 2015, 162: A2589-A2604.
29	PARANT J P, OLAZCUAGA R, DEVALETTE M, et al. Sur quelques nouvelles phases de formule Na_xMnO₂ (x≤1)[J]. Journal of Solid State Chemistry, 1971, 3: 1-11.
30	TAPIA-RUIZ N, DOSE W M, SHARMA N, et al. High voltage structural evolution and enhanced Na-ion diffusion in P2-Na_2/3Ni_1/3-_xMg_xMn_2/3O₂ (0≤x≤0.2) cathodes from diffraction, electrochemical and ab initio studies[J]. Energy & Environmental Science, 2018, 11: 1470-1479.
31	SOMERVILLE J W, SOBKOWIAK A, TAPIA-RUIZ N, et al. Nature of the “Z”-phase in layered Na-ion battery cathodes[J]. Energy & Environmental Science, 2019, 12: 2223-2232.
32	WANG P F, YAO H R, LIU X Y, et al. Na⁺/vacancy disordering promises high-rate Na-ion batteries[J]. Science Advances, 2018, 4: doi: 10.1126/sciadv.aar6018.
33	ZHAO C, DING F, LU Y, et al. High-entropy chemistry stabilizing layered O3-type structure in Na-ion cathode[J]. Angewandte Chemie International Edition, 2019, 59: 1-7.
34	HOUSE R A, MAITRA U, PÉREZ-OSORIO M A, et al. Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes[J]. Nature, 2020, 577: 502-508.
35	MORTEMARD DE BOISSE B, NISHIMURA S I, WATANABE E, et al. Highly reversible oxygen-redox chemistry at 4.1 V in Na_4/7-_x[□_1/7Mn_6/7]O₂ (□: Mn vacancy)[J]. Advanced Energy Materials, 2018, 8: doi: 10.1002/aenm.201800409.
36	RONG X, HU E, LU Y, et al. Anionic redox reaction-induced high-capacity and low-strain cathode with suppressed phase transition[J]. Joule, 2019, 3: 503-517.
37	XIA H, ZHU X, LIU J, et al. A monoclinic polymorph of sodium birnessite for ultrafast and ultrastable sodium ion storage[J]. Nature Communications, 2018, 9: doi: 10.1038/s41467-018-07595-y.
38	ORTIZ-VITORIANO N, DREWETT N E, GONZALO E, et al. High performance manganese-based layered oxide cathodes: Overcoming the challenges of sodium ion batteries[J]. Energy & Environmental Science, 2017, 10: 1051-1074.
39	DOUBAJI S, PHILIPPE B, SAADOUNE I, et al. Passivation layer and cathodic redox reactions in sodium-ion batteries probed by HAXPES[J]. ChemSusChem, 2016, 9: 97-108.
40	MONYONCHO E, BISSESSUR R. Unique properties of α-NaFeO₂: De-intercalation of sodium via hydrolysis and the intercalation of guest molecules into the extract solution[J]. Materials Research Bulletin, 2013, 48: 2678-2686.
41	KOMABA S, YABUUCHI N, NAKAYAMA T, et al. Study on the reversible electrode reaction of Na_1-_xNi_0.5Mn_0.5O₂ for a rechargeable sodium-ion battery[J]. Inorganic Chemistry, 2012, 51: 6211-6220.
42	KUBOTA K, KOMABA S. Practical issues and future perspective for Na-ion batteries[J]. Journal of the Electrochemical Society, 2015, 162: A2538-A2550.
43	MYUNG S T, HITOSHI Y, SUN Y K. Electrochemical behavior and passivation of current collectors in lithium-ion batteries[J]. Journal of Materials Chemistry, 2011, 21: 9891-9911.
44	MU L, XU S, LI Y, et al. Prototype sodium-ion batteries using an air-stable and Co/Ni-free O3-layered metal oxide cathode[J]. Advanced Materials, 2015, 27: 6928-6933.
45	LI Y, YANG Z, XU S, et al. Air-stable copper-based P2-Na_7/9Cu_2/9Fe_1/9Mn_2/3O₂ as a new positive electrode material for sodium-ion batteries[J]. Advanced Science, 2015, 2: doi: 10.1002/advs.201500031.
46	YAO H R, WANG P F, GONG Y, et al. Designing air-stable O3-type cathode materials by combined structure modulation for Na-ion batteries[J]. Journal of the American Chemical Society, 2017, 139: 8440-8443.
47	MU L Q, HU Y S, CHEN L Q. New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries[J]. Chinese Physics B, 2015, 24: doi: 10.1088/1674-1056/24/3/038202.
48	HWANG J Y, MYUNG S T, CHOI J U, et al. Resolving the degradation pathways of the O3-type layered oxide cathode surface through the nano-scale aluminum oxide coating for high-energy density sodium-ion batteries[J]. Journal of Materials Chemistry A, 2017, 5: 23671-23680.
49	GUO S, LI Q, LIU P, et al. Environmentally stable interface of layered oxide cathodes for sodium-ion batteries[J]. Nature Communications, 2017, 8: doi: 10.1038/s41467-017-00157-8.
50	TSUCHIYA Y, TAKANASHI K, NISHINOBO T, et al. Layered NaxCr_xTi_1-_xO₂ as bifunctional electrode materials for rechargeable sodium batteries[J]. Chemistry of Materials, 2016, 28: 7006-7016.
51	LI W, YAO Z, ZHOU C A, et al. Boosting high-rate sodium storage performance of N-doped carbon-encapsulated Na₃V₂(PO₄)₃ nanoparticles anchoring on carbon cloth[J]. Small, 2019, 15: doi: 10.1002/smll.201902432.
52	ZHANG Y, DENG S, SHEN Y, et al. Construction of 1T-MoSe₂/TiC@C branch-core arrays as advanced anodes for enhanced sodium ion storage[J]. ChemSusChem, 2020, 13: 1575-1581.
53	CAO M H, WANG Y, SHADIKE Z, et al. Suppressing the chromium disproportionation reaction in O3-type layered cathode materials for high capacity sodium-ion batteries[J]. Journal of Materials Chemistry A, 2017, 5: 5442-5448.
54	SAHA S, ASSAT G, SOUGRATI M T, et al. Exploring the bottlenecks of anionic redox in Li-rich layered sulfides[J]. Nature Energy, 2019, 4: 977-987.
55	LIU Q, HU Z, CHEN M, et al. The cathode choice for commercialization of sodium-ion batteries: Layered transition metal oxides versus prussian blue analogs[J]. Advanced Functional Materials, 2020, 30: doi: 10.1002/adfm.201909530.

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