一种新型水系锌离子电池正极材料NiCo2O4 的制备和电化学性能

doi:10.19799/j.cnki.2095-4239.2021.0542

摘要/Abstract

摘要：

水系锌离子电池的能量密度高、稳定性好、安全系数高。NiCo₂O₄材料作为双过渡金属氧化物，其导电性能和电化学活性都很出色，本工作首次采用NiCo₂O₄材料作为水系锌离子电池的正极。采取了溶胶-凝胶法加煅烧热方法制备出立体尖晶石状的NiCo₂O₄材料，借助扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能谱分析技术(EDS)和电化学技术等表征测试手段，分析这种新型水系锌离子电池正极材料的形貌和电化学性能。结果表明，立体尖晶石状的NiCo₂O₄材料有着优良的纯度和结晶性，颗粒分散均匀，没有团聚，无杂质且具有良好稳定的充放电性能。电极在100 mA/g电流密度下，首次放电比容量为92 mA·h/g，100圈充放电测试后放电比容量为60 mA·h/g，200圈后，放电比容量保持在44 mA·h/g。但在循环倍率测试中发现，当电流密度较大时，NiCo₂O₄电极产生了27 mA·h/g的衰减，在一定程度上有着不可逆的冲击破坏。本研究有助于推动水性锌离子电池电极的应用，为高性能水性锌离子电池电极材料的研发提供实验依据。

关键词: 水系锌离子电池, 正极材料, NiCo₂O₄, 溶胶凝胶法

Abstract:

Aqueous zinc-ion batteries have a high energy density, good stability, and high safety factor; as a double transition metal oxide, NiCo₂O₄ has excellent electrical conductivity and electrochemical activity. Therefore, herein, NiCo₂O₄ was novelly used as a novel cathode material for aqueous zinc-ion batteries. The solid spinel NiCo₂O₄ material was prepared by the sol-gel and calcination heat methods. Using scanning electron microscopy, transmission electron microscope, energy dispersive spectroscopy, and electrochemical technology, the morphology and electrochemical properties of the cathode material of the new aqueous zinc-ion batteries were analyzed. The results show that the spinel NiCo₂O₄ material has excellent purity and crystallinity, and the particles are evenly dispersed without agglomeration and impurity. Moreover, it has good and stable charge-discharge performance. At a current density of 100 mA·g^-1, the initial specific discharge capacity of the electrode is 92 mA·h·g^-1, 60 mA·h·g^-1 after 100 cycles, and 44 mA·h·g^-1 after 200 cycles. However, when the current density is high, the specific capacitance of the NiCo₂O₄ electrode decreases by 27 mA·h·g^-1, which has irreversible impact damage to a certain extent. This study highlights that NiCo₂O₄ material improves the performance of aqueous zinc-ion batteries, which can guide the future design of aqueous zinc-ion batteries.

Key words: aqueous zinc-ion battery, cathode material, NiCo₂O₄, sol-gel method

中图分类号:

TQ 138

吴渺, 赵贵青, 仇中柱, 王保峰. 一种新型水系锌离子电池正极材料NiCo₂O₄ 的制备和电化学性能[J]. 储能科学与技术, 2022, 11(3): 1019-1025.

Miao WU, Guiqing ZHAO, Zhongzhu QIU, Baofeng WANG. Preparation and electrochemical properties of NiCo₂O₄ as a novel cathode material for aqueous zinc-ion batteries[J]. Energy Storage Science and Technology, 2022, 11(3): 1019-1025.

图/表 8

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一种新型水系锌离子电池正极材料NiCo₂O₄ 的制备和电化学性能

Preparation and electrochemical properties of NiCo₂O₄ as a novel cathode material for aqueous zinc-ion batteries

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