石油沥青基MoS2/多孔碳复合材料的制备及其锂存储性能

doi:10.19799/j.cnki.2095-4239.2021.0543

摘要/Abstract

摘要：

目前，对低成本石油沥青高附加值的利用仍面临着重大的挑战。鉴于其碳含量高，本工作利用NaHCO₃模板成功制备了一种掺硫多孔碳骨架(SPC)结构。随后，以低沸点的MoCl₅为钼源，升华硫为硫源，在SPC表层原位生长一层MoS₂纳米片，定向制备了一种三维复合结构。该材料实现了MoS₂和碳基底材料的良好接触，其相互交错的结构可以大大提高电子的传递速率，缩短了锂离子和电子传输路径。另外，该材料的多孔结构为锂离子提供了丰富的反应活性位点。当作为锂离子电池阳极进行测试时，该材料经过400圈的循环后，仍然维持着1069 mA·h/g的高比容量。这项工作可能为低成本石油沥青的高附加值利用提供一个崭新的思路。

关键词: 高附加值利用, 石油沥青, 三维结构, 锂离子电池阳极

Abstract:

Presently, the high value-added utilization of low-cost petroleum asphalt faces great challenges. Herein, based on the high carbon content of asphalt, an S-doping porous carbon (SPC) framework structure was successfully prepared using a NaHCO₃ template. Afterward, a three-dimensional structure was prepared by the in situ growth of MoS₂ nanosheets on the surface of the SPC using MoCl₅ and sublimated sulfur as the molybdenum and sulfur sources. The as-formed material achieves a good contact between MoS₂ and the carbon substrate, and its interlaced structure can greatly improve the electron transfer rate and shorten the transmission path of Li⁺ and e^-. Additionally, its porous structure provides abundant reactive sites for Li⁺. When tested as lithium anode, the material obtains a high specific capacity of 1069 mA·h·g^-1 after 400 cycles. This work may provide a new idea for the high value-added utilization of low-cost petroleum asphalt.

Key words: high value-added utilization, petroleum asphalt, three-dimensional structure, lithium anode

中图分类号:

TQ 028.8

李云, 杨旺, 李永峰. 石油沥青基MoS₂/多孔碳复合材料的制备及其锂存储性能[J]. 储能科学与技术, 2022, 11(3): 1026-1034.

Yun LI, Wang YANG, Yongfeng LI. Synthesis of petroleum asphalt-based MoS₂/porous carbon material and its Li-storage performance[J]. Energy Storage Science and Technology, 2022, 11(3): 1026-1034.

图/表 9

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碳材料	电流密度/(mA/g)	循环次数	容量/(mA·h/g)	参考文献
三维石墨烯@碳纳米管@二硫化钼杂化物	100	200	600	[27]
二硫化钼纳米片/碳材料	5000	1000	500	[28]
二硫化钼/碳材料	100	100	1129	[29]
二硫化钼/碳材料	1000	100	339	[29]
三维二硫化钼/碳纳米球	1000	—	612	[30]
二硫化钼/氮掺杂石墨烯	100	100	750	[31]
氮掺杂碳/二硫化钼纳米球	150	100	1055	[16]
MoS₂/SPC	500	400	1069	本工作

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石油沥青基MoS₂/多孔碳复合材料的制备及其锂存储性能

Synthesis of petroleum asphalt-based MoS₂/porous carbon material and its Li-storage performance

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