储能科学与技术 ›› 2023, Vol. 12 ›› Issue (12): 3709-3719.doi: 10.19799/j.cnki.2095-4239.2023.0685

• 复合储热专辑 • 上一篇    下一篇

碳捕捉对废弃混凝土复合相变储热材料性能的影响

田曦1(), 熊亚选1(), 任静2, 赵彦琦3, 晋世豪4, 李烁1, 杨洋1, 丁玉龙5   

  1. 1.北京建筑大学供热供燃气通风及空调工程北京市重点实验室,北京 100044
    2.北京中建建筑科学研究院有限公司,北京 100076
    3.南京工业大学能源科学与工程学院,江苏 南京 211816
    4.国家电网河南省禹州市供电公司,河南 许昌 461670
    5.伯明翰大学伯明翰储能中心,伯明翰 B15 2TT
  • 收稿日期:2023-09-30 修回日期:2023-10-11 出版日期:2023-12-05 发布日期:2023-12-09
  • 通讯作者: 熊亚选 E-mail:TX17731114603@163.com;xiongyaxuan@bucea.edu.cn
  • 作者简介:田曦(1998—),男,硕士研究生,主要从事固废储热方面的研究,E-mail:TX17731114603@163.com
  • 基金资助:
    国家自然科学基金(52006008);北京市教委科研项目(KM201910016011);北京建筑大学科学研究基金(Z13086)

Effect of carbon sequestration on the performance of waste concrete shape-stable phase change composites

Xi TIAN1(), Yaxuan XIONG1(), Jing REN2, Yanqi ZHAO3, Shihao JIN4, Shuo LI1, Yang YANG1, Yulong DING5   

  1. 1.Beijing Key Lab of Heating, Gas Supply, Ventilating and Air Conditioning Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
    2.Beijing Building Research Institute CO. , LTD. of CSCEC, Beijing 100076, China
    3.School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
    4.State Grid Henan Provincial Power Company Yuzhou Power Supply Company, Xuchang 461670, Henan, China
    5.Birmingham Center for Energy storage, University of Birmingham, Birmingham B15 2TT, UK
  • Received:2023-09-30 Revised:2023-10-11 Online:2023-12-05 Published:2023-12-09
  • Contact: Yaxuan XIONG E-mail:TX17731114603@163.com;xiongyaxuan@bucea.edu.cn

摘要:

为充分资源化利用废弃混凝土,捕捉和储存CO2,本工作利用废弃混凝土进行碳捕捉,分别采用经固碳和未固碳废弃混凝土为骨架材料,硝酸钠为相变材料,制备出了7种不同质量配比的复合相变储热材料。研究结果表明,废弃混凝土在最佳实验工况下固碳效率高达24.7%;在添加相同质量分数的相变材料情况下,固碳复合相变储热材料的熔化潜热高于未固碳复合相变储热材料;样品SS2的抗压强度高达121.54 MPa,固碳废弃混凝土及其复合相变储热材料的抗压强度均有较大提升,最高热导率[0.648 W/(m·K)]低于未固碳样品[0.884 W/(m·K)];固碳前后的废弃混凝土骨架材料均与相变材料颗粒结合致密,材料各组分间的化学相容性较好。

关键词: 废弃混凝土, 固碳, 骨架材料, 复合相变储热材料, 储热

Abstract:

In order to fully resource the use of waste concrete to capture and store CO2, this paper utilizes waste concrete for carbon capture, and seven composite phase change heat storage materials with different mass ratios were prepared by using carbon consolidated and unconsolidated waste. Results indicate that the carbon sequestration efficiency of the waste concrete was as high as 24.7% under the specific experimental conditions. The latent heat of melting of the shape-stable phase change composites prepared by carbon sequestration was higher than that before carbon sequestration after adding the same mass fraction of phase change material. The compressive strength of SS2 was as high as 121.54 MPa, and the compressive strengths of both the carbon sequestered waste concrete and shape-stable phase change composites were significantly increased, with the highest thermal conductivity [0.648 W/(m·K)] being lower than that of the un-sequestered sample [0.884 W/(m·K)]. The shape-stable phase change composites before and after carbon sequestration had good chemical compatibility among the components, and the phase change materials were densely bonded with the skeleton materials.

Key words: waste concrete, carbon sequestration, skeleton material, shape-stable phase change composites, energy storage

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