微分电化学质谱:研究锂离子电池的一项关键技术

doi:10.12028/j.issn.2095-4239.2018.0131

储能科学与技术 ›› 2019, Vol. 8 ›› Issue (1): 1-13.doi: 10.12028/j.issn.2095-4239.2018.0131

微分电化学质谱:研究锂离子电池的一项关键技术

赵志伟^1,2, 彭章泉^1,2

1 中国科学院长春应用化学研究所电分析化学国家重点实验室, 吉林长春 130022;
2 中国科学技术大学, 安徽合肥 230026

收稿日期:2018-07-27 修回日期:2018-08-24 出版日期:2019-01-01 发布日期:2018-08-28
通讯作者: 彭章泉,研究员,主要研究方向为能源界面电化学(电极动力学,现场光/质谱电化学,电极反应的第一性原理计算)、金属-空气电池、锂离子电池,E-mail:zqpeng@ciac.ac.cn。
作者简介:赵志伟(1993-),男,硕士研究生,主要研究方向为电化学质谱在锂电池中的应用,E-mail:zwzhao@ciac.ac.cn
基金资助:
国家自然科学基金项目（21733012，21633008，21605136，91545129，21575135），中国科学院战略性先导科技专项项目（XDA09010 401），吉林省科技厅项目（20150623002TC，20160414034GH），国家重点研发计划项目（2016YFB0100100）。

Differential electrochemical mass spectroscopy: A pivotal technology for investigating lithium-ion batteries

ZHAO Zhiwei^1,2, PENG Zhangquan^1,2

1 State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University Chinese Academy of Sciences, Changchun 130022, Jilin, China;
2 University of Science and Technology of China, Hefei 230026, Anhui, China

Received:2018-07-27 Revised:2018-08-24 Online:2019-01-01 Published:2018-08-28

摘要/Abstract

摘要： 锂离子电池的安全性问题在很大程度上限制了其在纯电动汽车、规模储能等领域的广泛应用。电池材料|电解质界面副反应所产生的可燃性气体是锂离子电池安全隐患的首要原因。微分电化学质谱是解析锂离子电池产气副反应机制的强有力研究技术。本文综述了微分电化学质谱的发展历程、工作原理、技术要点及其在锂离子电池安全性研究中的应用，并展望了微分电化学质谱在储能领域的机遇、挑战和策略。

关键词: 微分电化学质谱, 锂离子电池, 安全

Abstract: Safety issues of lithium-ion batteries are becoming prominent with its application in electric vehicle and large-scale energy storage fields. Flammable gases evolved from electrode|electrolyte interface play an important role on the batteries' safety characteristics. Fortunately, differential electrochemical mass spectrometry (DEMS) as a powerful technology provides exploitable strategies for understanding the gas-related parasitic reaction mechanisms. The review covers the history, basics, know-how, and applications in safety researches of DEMS. In addition, emerging opportunities, critical challenges, future directions and strategies are particularly highlighted.

Key words: differential electrochemical mass spectrometry, lithium-ion battery, safety

中图分类号:

TM911

赵志伟, 彭章泉. 微分电化学质谱:研究锂离子电池的一项关键技术[J]. 储能科学与技术, 2019, 8(1): 1-13.

ZHAO Zhiwei, PENG Zhangquan. Differential electrochemical mass spectroscopy: A pivotal technology for investigating lithium-ion batteries[J]. Energy Storage Science and Technology, 2019, 8(1): 1-13.

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微分电化学质谱:研究锂离子电池的一项关键技术

Differential electrochemical mass spectroscopy: A pivotal technology for investigating lithium-ion batteries

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