共轭羰基化合物作为钠/钾离子电池电极材料的研究进展

doi:10.12028/j.issn.2095-4239.2018.0098

摘要/Abstract

摘要： 钠（钾）离子电池资源丰富、成本低廉，是极具大规模应用潜力的新型电池体系。然而，受制于较大的钠（钾）离子半径，这两类电池电极材料的选择受到了极大的限制。以共轭羰基化合物为代表的有机电极材料具有柔性的骨架结构，对阳离子半径选择性小，且结构多样、理论比容量高、环境友好，基于有机共轭羰基化合物构建的钠（钾）离子电池是未来“绿色电池”发展的重要方向。本文介绍了共轭羰基化合物的分类、储钠/钾性能及机理，重点探讨了羰基化合物作为储钠（钾）材料存在的问题和改进方法。最后，总结了羰基化合物作为钠钾离子电池电极材料存在的基础科学问题、技术挑战以及竞争力，同时进一步展望了有机共轭羰基化合物的发展方向以及大规模储能领域的应用前景。

关键词: 钠离子电池, 钾离子电池, 有机电极材料, 共轭羰基化合物

Abstract: Sodium (Potassium)-ion batteries are promising battery systems for large-scale energy storage applications owning to the low cost and resource abundance. However, the relatively larger radius of sodium (potassium) ions hinders the development of Na (K)-host materials. The organic electrode materials, especially carbonyl compounds, have been considered as one of the most promising electrode materials for SIBs and KIBs due to the structural diversity, high theoretical specific capacity and environmental friendliness. Moreover, the flexible frameworks demonstrate less restriction on the cation sizes. Therefore, constructing sodium (potassium) ion batteries based on organic carbonyl compounds are highly desirable for the next generation of "green batteries". This review offers an introduction on the classification, Na/K-storage performances and mechanisms of the organic carbonyl compounds, emphasizing on the existing problems and resolution strategies. Finally, the basic scientific problems, technical challenges and competitiveness of carbonyl compounds as electrode materials for Sodium (Potassium)-ion batteries are summarized, and the application of carbonyl-based organic electrode materials for large-scale energy storage applications are also forecasted.

Key words: sodium-ion batteries, potassium-ion batteries, organic electrode materials, conjugated carbonyl compounds

中图分类号:

TM911

刘梦云, 谷天天, 周敏, 王康丽, 程时杰, 蒋凯. 共轭羰基化合物作为钠/钾离子电池电极材料的研究进展[J]. 储能科学与技术, 2018, 7(6): 1171-1181.

LIU Mengyun, GU Tiantian, ZHOU Min, WANG Kangli, CHENG Shijie, JIANG Kai. Conjugated carbonyl compounds as electrode materials for sodium-ion/potassium-ion batteries[J]. Energy Storage Science and Technology, 2018, 7(6): 1171-1181.

参考文献

[1] 王松岑, 来小康, 程时杰. 大规模储能技术在电力系统中的应用前景分析[J]. 电力系统自动化, 2013, 37 (1):3-8. WANG C, LAI X, CHENG S. An analysis of prospects for application of large-scale energy storage technology in power systems[J]. Automation of Electric Power Systems, 2013, 37 (1):3-8.
[2] OWENS B. Batteries[J]. Nature, 2015, 526 (7575):S89.
[3] CHOU S L, DOU S X. Next-generation batteries[J]. Advanced Materials, 2017, 29 (48):1705871.
[4] HWANG J Y, MYUNG S T, SUN Y K. Sodium-ion batteries:Present and future[J]. Chemical Society Reviews, 2017, 46 (12):3529-3614.
[5] ZOU X, XIONG P, ZHAO J, et al. Recent research progress in non-aqueous potassium-ion batteries[J]. Physical Chemistry Chemical Physics, 2017, 19 (39):26495-26506.
[6] 李文挺, 安胜利, 邱新平. 钾离子电池关键材料的研究进展[J]. 储能科学与技术, 2018, 7 (3):365-375. LI W, AN S, QIU X. Research on key materials for potassium ion batteries[J]. Energy Storage Science and Technology, 2018, 7 (3):365-375.
[7] SCHON T B, MCALLISTER B T, LI P F, et al. The rise of organic electrode materials for energy storage[J]. Chemical Society Reviews, 2016, 45 (22):6345-6404.
[8] ZHAO Q, LU Y, CHEN J. Advanced organic electrode materials for rechargeable sodium-ion batteries[J]. Advanced Energy Materials, 2017, 7 (8):1601792.
[9] SANO H, SENOH H, YAO M, et al. Mg²⁺ storage in organic positive-electrode active material based on 2, 5-dimethoxy-1, 4-benzoquinone[J]. Chemistry Letters, 2012, 41 (12):1594-1596.
[10] HÄUPLER B, WILD A, SCHUBERT U S. Carbonyls:Powerful organic materials for secondary batteries[J]. Advanced Energy Materials, 2015, 5 (11):1402034.
[11] ZHAO Q, ZHU Z, CHEN J. Molecular engineering with organic carbonyl electrode materials for advanced stationary and redox flow rechargeable batteries[J]. Advanced Materials, 2017, 29 (48):1607007.
[12] HUSKINSON B, NAWAR S, GERHARDT M R, et al. Novel quinone-based couples for flow batteries[J]. ECS Transactions, 2013, 53 (7):101-105.
[13] 卢勇, 赵庆, 梁静, 等. 可充锂电池醌类化合物电极材料[J]. 物理化学学报, 2016, 32 (7):1593-1603. LU Y, ZHAO Q, LIANG J, TAO Z, et al J. Quinones as electrode materials for rechargeable lithium batteries[J]. Acta Physico-Chimica Sinica, 2016, 32 (7):1593-1603.
[14] WILLIAMS D L, BYRNE J J, DRISCOLL J S. A high energy density lithium/dichloroisocyanuric acid battery system[J]. J. Electrochem. Soc., 1969, 116:2-4
[15] GUO C, ZHANG K, ZHAO Q, et al. High-performance sodium batteries with the 9, 10-anthraquinone/CMK-3 cathode and an ether-based electrolyte[J]. Chemical Communications, 2015, 51 (50):10244-10247.
[16] ZHANG K, GUO C, ZHAO Q, et al. High-performance organic lithium batteries with an ether-based electrolyte and 9, 10-anthraquinone (AQ)/CMK-3 cathode[J]. Advanced Science, 2015, 2 (5):1500018.
[17] WANG H, HU P, YANG J, et al. Renewable-juglone-based high-performance sodium-ion batteries[J]. Advanced Materials, 2015, 27 (14):2348-2354.
[18] KIM H, KWON J E, LEE B, et al. High energy organic cathode for sodium rechargeable batteries[J]. Chemistry of Materials, 2015, 27 (21):7258-7264.
[19] ZHAO J, YANG J, SUN P, et al. Sodium sulfonate groups substituted anthraquinone as an organic cathode for potassium batteries[J]. Electrochemistry Communications, 2018, 86:34-37.
[20] WU X, JIN S, ZHANG Z, et al. Unraveling the storage mechanism in organic carbonyl electrodes for sodium-ion batteries[J]. Science Advances, 2015, 1 (8):1500330.
[21] WU X, MA J, MA Q, et al. A spray drying approach for the synthesis of a Na₂C₆H₂O₄/CNT nanocomposite anode for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2015, 3 (25):13193-13197.
[22] WANG C, FANG Y, XU Y, et al. Manipulation of disodium rhodizonate:Factors for fast-charge and fast-discharge sodium-ion batteries with long-term cyclability[J]. Advanced Functional Materials, 2016, 26 (11):1777-1786.
[23] WANG Y, DING Y, PAN L, et al. Understanding the size-dependent sodium storage properties of Na₂C₆O₆-based organic electrodes for sodium-ion batteries[J]. Nano Letters, 2016, 16 (5):3329-3334.
[24] ZHAO Q, WANG J, LU Y, et al. Oxocarbon salts for fast rechargeable batteries[J]. Angewandte Chemie International Edition, 2016, 55 (40):12528-12532
[25] WANG H, YUAN S, SI Z, et al. Multi-ring aromatic carbonyl compounds enabling high capacity and stable performance of sodium-organic batteries[J]. Energy & Environmental Science, 2015, 8 (11):3160-3165.
[26] LUO W, ALLEN M, RAJU V, et al. An organic pigment as a high-performance cathode for sodium-ion batteries[J]. Advanced Energy Materials, 2014, 4 (15):1400554.
[27] XING Z, JIAN Z, LUO W, et al. A perylene anhydride crystal as a reversible electrode for K-ion batteries[J]. Energy Storage Materials, 2016, 2:63-68.
[28] CHEN Y, LUO W, CARTER M, et al. Organic electrode for non-aqueous potassium-ion batteries[J]. Nano Energy, 2015, 18:205-211.
[29] RENAULT S, MIHALI V A, EDSTRÖM K, et al. Stability of organic Na-ion battery electrode materials:The case of disodium pyromellitic diimidate[J]. Electrochemistry Communications, 2014, 45:52-55.
[30] KIM D J, JUNG Y H, BHARATHI K K, et al. An aqueous sodium ion hybrid battery incorporating an organic compound and a Prussian blue derivative[J]. Advanced Energy Materials, 2014, 4 (12):1400133.
[31] DENG W, SHEN Y, QIAN J, et al. A perylene diimide crystal with high capacity and stable cyclability for Na-ion batteries[J]. ACS Applied Materials & Interfaces, 2015, 7 (38):21095-21099.
[32] PARK Y, SHIN D S, WOO S H, et al. Sodium terephthalate as an organic anode material for sodium ion batteries[J]. Advanced Materials, 2012, 24 (26):3562-3567.
[33] LEI K, LI F, MU C, et al. High K-storage performance based on the synergy of dipotassium terephthalate and ether-based electrolytes[J]. Energy & Environmental Science, 2017, 10 (2):552-557.
[34] CHOI A, KIM Y K, KIM T K, et al. 4, 4'-Biphenyldicarboxylate sodium coordination compounds as anodes for Na-ion batteries[J]. Journal of Materials Chemistry A, 2014, 2 (36):14986-14993.
[35] ABOUIMRANE A, WENG W, ELTAYEB H, et al. Sodium insertion in carboxylate based materials and their application in 3.6 V full sodium cells[J]. Energy & Environmental Science, 2012, 5 (11):9632-9638.
[36] WANG S, WANG L, ZHU Z, et al. All organic sodium-ion batteries with Na₄C₈H₂O₆[J]. Angewandte Chemie, 2014, 126 (23):6002-6006.
[37] DENG Q, PEI J, FAN C, et al. Potassium salts of para-aromatic dicarboxylates as the highly efficient organic anodes for low-cost K-ion batteries[J]. Nano Energy, 2017, 33:350-355.
[38] SONG Z, QIAN Y, ZHANG T, et al. Poly (benzoquinonyl sulfide) as a high-energy organic cathode for rechargeable Li and Na batteries[J]. Advanced Science, 2015, 2 (9):1500124.
[39] DENG W, LIANG X, WU X, et al. A low cost, all-organic Na-ion battery based on polymeric cathode and anode[J]. Scientific Reports, 2013, 3:2671.
[40] JIAN Z, LIANG Y, RODRÍGUEZ-PÉREZ I A, et al. Poly (anthraquinonyl sulfide) cathode for potassium-ion batteries[J]. Electrochemistry Communications, 2016, 71:5-8.
[41] QIN H, SONG Z P, ZHAN H, et al. Aqueous rechargeable alkali-ion batteries with polyimide anode[J]. Journal of Power Sources, 2014, 249:367-372.
[42] WANG H, YUAN S, MA D, et al. Tailored aromatic carbonyl derivative polyimides for high-power and long-cycle sodium-organic batteries[J]. Advanced Energy Materials, 2014, 4 (7):1301651.
[43] BANDA H, DAMIEN D, NAGARAJAN K, et al. A polyimide based all-organic sodium ion battery[J]. Journal of Materials Chemistry A, 2015, 3 (19):10453-10458.
[44] GU T, ZHOU M, LIU M, et al. A polyimide-MWCNTs composite as high performance anode for aqueous Na-ion batteries[J]. RSC Advances, 2016, 6 (58):53319-53323.
[45] XU F, XIA J, SHI W. Anthraquinone-based polyimide cathodes for sodium secondary batteries[J]. Electrochemistry Communications, 2015, 60:117-120.
[46] XU F, WANG H, LIN J, et al. Poly (anthraquinonyl imide) as a high capacity organic cathode material for Na-ion batteries[J]. Journal of Materials Chemistry A, 2016, 4 (29):11491-11497.
[47] LI Z, ZHOU J, XU R, et al. Synthesis of three dimensional extended conjugated polyimide and application as sodium-ion battery anode[J]. Chemical Engineering Journal, 2016, 287:516-522.
[48] ANDRZEJAK M, MAZUR G, PETELENZ P. Quantum chemical results as input for solid state calculations:Charge transfer states in molecular crystals[J]. Journal of Molecular Structure:Theochem, 2000, 527 (1/3):91-102.
[49] LIANG Y, ZHANG P, YANG S, et al. Fused heteroaromatic organic compounds for high-power electrodes of rechargeable lithium batteries[J]. Advanced Energy Materials, 2013, 3 (5):600-605.
[50] WU Y, ZENG R, NAN J, et al. Quinone electrode materials for rechargeable lithium/sodium ion batteries[J]. Advanced Energy Materials, 2017, 1700278.
[51] TANG M, LI H, WANG E, et al. Carbonyl polymeric electrode materials for metal-ion batteries[J]. Chinese Chemical Letters, 2018, 2 (29):232-244.
[52] 李文俊, 褚赓, 李泓. 锂离子电池基础科学问题 (Ⅻ)-表征方法[J]. 储能科学与技术, 2014, 3 (6):642-667. LI W, ZHU G, LI H, et al. Fundamental scientific aspects of lithium batteries (Ⅻ)-Characterization techniques[J]. Energy Storage Science and Technology, 2014, 3 (6):642-667.
[53] 凌仕刚, 吴娇杨, 李泓. 锂离子电池基础科学问题 (XⅢ)-电化学测量方法[J]. 储能科学与技术, 2015, 4 (1):83-103. LING S, WU J, LI H, et al. Fundamental scientific aspects of lithium batteries (XⅡ)-Electrochemical measurement[J]. Energy Storage Science and Technology, 2015, 4 (1):83-103.
[54] 黄杰, 凌仕刚, 李泓. 锂离子电池基础科学问题 (ⅩⅣ)-计算方法[J]. 储能科学与技术, 2015, 4 (2):216-230. HUANG J, LING S, LI H. Fundamental scientific aspects of lithium batteries (ⅩⅣ)-Calculation methods[J]. Energy Storage Science and Technology, 2015, 4 (2):216-230.