Fe3+ crosslinking reduced graphene oxides free-standing film by pre-encapsulated Fe3O4 nanospheres for lithium storage

doi:10.19799/j.cnki.2095-4239.2022.0644

Abstract

Abstract:

In this study, Fe³⁺ was used to modify the graphene oxide (GO) free-standing film containing GO pre-encapsulated Fe₃O₄ to prepare Fe³⁺ crosslinked with reduced graphene oxides free-standing film by pre-encapsulated Fe₃O₄ nanospheres (Fe^3+?@Fe₃O₄/rGO). Scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and other test techniques were used to characterize the composition, structure, and morphology, and to study Fe^3+?@Fe₃O₄/rGO free-standing film lithium storage performance as the cathode of lithium-ion batteries. The results reveal that spherical Fe₃O₄ nanoparticle are tightly wrapped by GO layers, and the stability of Fe³⁺@Fe₃O₄/rGO free-standing film crosslinked by Fe³⁺ is significantly improved. The electrochemical results demonstrate that after 100 cycles of constant current charge and discharge with a current density of 100 mA/g, the specific discharge capacity of Fe³⁺@Fe₃O₄/rGO is 545 mAh/g, which is considerably higher than that of Fe₃O₄/rGO free-standing film discharge ratio capacity of 452 mAh/g before Fe³⁺ crosslinking, which proves that the free-standing composite structure after Fe³⁺ crosslinking shows outstanding electrochemical cycle stability. Additionally, the quick and easy procedure for creating cation-induced GO free-standing film can be used to additional active electrode materials.

Key words: graphene, Fe₃O₄, cross-linked, free-standing, lithium storage performance

CLC Number:

TB 332

Panlei CAO, Linxiu SUI, Jingyun FENG, Weifu ZHANG, Chengcheng LUO, Xiaoya YUAN. Fe³⁺ crosslinking reduced graphene oxides free-standing film by pre-encapsulated Fe₃O₄ nanospheres for lithium storage[J]. Energy Storage Science and Technology, 2023, 12(3): 710-720.

Figures/Tables 9

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References 32

1	王艳坤. 四氧化三铁/石墨烯纳米复合材料的静电自组装制备及储锂性能[J]. 材料导报, 2021, 35(16): 16008-16014, 16020.
	WANG Y K. Colloid electrostatic self-assembly synthesis of ferroferric oxide/reduced graphene oxide nanocomposites for lithium storage[J]. Materials Reports, 2021, 35(16): 16008-16014, 16020.
2	焦丹花, 宋群, 蔡晓东. 氧化石墨烯在锂离子电池负极材料中的研究进展[J]. 广州化工, 2021, 49(14): 7-10.
	JIAO D H, SONG Q, CAI X D. Research progress on graphene oxide as anode materials for lithium ion batteries[J]. Guangzhou Chemical Industry, 2021, 49(14): 7-10.
3	李培. 石墨烯/四氧化三铁复合材料的制备及在锂离子电池中的应用研究[D]. 天津: 天津大学, 2014.
	LI P. The preparation of graphene/Fe₃O₄ composites and its application in anode materials for lithium ion batteries[D]. Tianjin: Tianjin University, 2014.
4	徐飞. 锂离子电池四氧化三铁负极材料的改性与研究[D]. 成都: 电子科技大学, 2020.
	XU F. Modification and research of Fe₃O₄ anode materials for lithium ion batteries[D]. Chengdu: University of Electronic Science and Technology of China, 2020.
5	HONG R Y, LI J H, ZHANG S Z, et al. Preparation and characterization of silica-coated Fe₃O₄ nanoparticles used as precursor of ferrofluids[J]. Applied Surface Science, 2009, 255(6): 3485-3492.
6	郭伟华, 黄德娟, 马建国, 等. NH₂-Fe₃O₄纳米粒子修饰电极测定水样中的微量铅和铜[J]. 分子科学学报, 2016, 32(6): 481-487.
	GUO W H, HUANG D J, MA J G, et al. Determination of trace lead and copper in water sample with NH₂-Fe₃O₄modified electrode[J]. Journal of Molecular Science, 2016, 32(6): 481-487.
7	WEI W, YANG S B, ZHOU H X, et al. 3D graphene foams cross-linked with pre-encapsulated Fe₃O₄ nanospheres for enhanced lithium storage[J]. Advanced Materials (Deerfield Beach, Fla), 2013, 25(21): 2909-2914.
8	李杨, 江连洲, 李丹丹, 等. 氨基硅烷修饰的磁性纳米粒子固定化碱性蛋白酶[J]. 食品科学, 2012, 33(9): 202-205.
	LI Y, JIANG L Z, LI D D, et al. Immobilization of alkaline protease with magnetic nanoparticles modified by amino-silane[J]. Food Science, 2012, 33(9): 202-205.
9	LEE B, MA Z, ZHANG Z T, et al. Influences of synthesis conditions and mesoporous structures on the gold nanoparticles supported on mesoporous silica hosts[J]. Microporous and Mesoporous Materials, 2009, 122(1/2/3): 160-167.
10	YANG S B, FENG X L, IVANOVICI S, et al. Fabrication of graphene-encapsulated oxide nanoparticles: Towards high-performance anode materials for lithium storage[J]. Angewandte Chemie, 2010, 49(45): 8408-8411.
11	ZHAO J P, YANG B J, ZHENG Z M, et al. Facile preparation of one-dimensional wrapping structure: Graphene nanoscroll-wrapped of Fe₃O₄ nanoparticles and its application for lithium-ion battery[J]. ACS Applied Materials & Interfaces, 2014, 6(12): 9890-9896.
12	王金星. 自支撑石墨烯基膜材料的制备及其电化学性能的研究[D]. 西安: 西北大学, 2016.
	WANG J X. Synthesis and electrochemical properties of free-standing graphene-based film materials[D]. Xi'an: Northwest University, 2016.
13	GONISZEWSKI S, GALLOP J, ADABI M, et al. Self-supporting graphene films and their applications[J]. IET Circuits, Devices & Systems, 2015, 9(6): 420-427.
14	杨俊松, 张晖, 王腾, 等. 水热体系中四氧化三铁与氧化石墨烯复合纳米颗粒的合成[J]. 硅酸盐通报, 2013, 32(1): 100-102.
	YANG J S, ZHANG H, WANG T, et al. Synthesis of Fe₃O₄/graphene oxide composite nanoparticles in hydrothermal system[J]. Bulletin of the Chinese Ceramic Society, 2013, 32(1): 100-102.
15	DENG H, LI X L, PENG Q, et al. Monodisperse magnetic single-crystal ferrite microspheres[J]. Angewandte Chemie, 2005, 44(18): 2782-2785.
16	张石磊. 四氧化三铁复合碳纳米材料制备及其锂空气电池性能研究[D]. 重庆: 重庆大学, 2018.
	ZHANG S L. Fe₃O₄-carbon nanomaterials compounds preparation and their properties as cathode for lithium air battery[D]. Chongqing: Chongqing University, 2018.
17	BEKETOV I V, SAFRONOV A P, MEDVEDEV A I, et al. Iron oxide nanoparticles fabricated by electric explosion of wire: Focus on magnetic nanofluids[J]. AIP Advances, 2012, 2(2): 022154.
18	PARK S, LEE K S, BOZOKLU G, et al. Graphene oxide papers modified by divalent ions-enhancing mechanical properties via chemical cross-linking[J]. ACS Nano, 2008, 2(3): 572-578.
19	HUANG L, ZHANG M, LI C, et al. Graphene-based membranes for molecular separation[J]. The Journal of Physical Chemistry Letters, 2015, 6(14): 2806-2815.
20	WAN S J, CHEN Y, FANG S L, et al. High-strength scalable graphene sheets by freezing stretch-induced alignment[J]. Nature Materials, 2021, 20(5): 624-631.
21	WAN S J, FANG S L, JIANG L, et al. Strong, conductive, foldable graphene sheets by sequential ionic and π bridging[J]. Advanced Materials, 2018: doi: 10.1002/adma.201802733.
22	ZHOU G M, WANG D W, LI F, et al. Graphene-wrapped Fe₃O₄ anode material with improved reversible capacity and cyclic stability for lithium ion batteries[J]. Chemistry of Materials, 2010, 22(18): 5306-5313.
23	SU J, CAO M H, REN L, et al. Fe₃O₄-graphene nanocomposites with improved lithium storage and magnetism properties[J]. The Journal of Physical Chemistry C, 2011, 115(30): 14469-14477.
24	ZHAO X J, JIA Y H, LIU Z H. GO-graphene ink-derived hierarchical 3D-graphene architecture supported Fe₃O₄ nanodots as high-performance electrodes for lithium/sodium storage and supercapacitors[J]. Journal of Colloid and Interface Science, 2019, 536: 463-473.
25	GUPTA P, GARKOTI C, SHABIR J, et al. Amine grafted Fe₃O₄ immobilized graphene oxide as a recyclable and effectual nanocomposite for the regioselective ring opening reaction[J]. Research on Chemical Intermediates, 2021, 47(10): 4013-4028.
26	NAZARI Y, SALEM S. Efficient photocatalytic methylene blue degradation by Fe₃O₄@TiO₂ core/shell linked to graphene by aminopropyltrimethoxysilane[J]. Environmental Science and Pollution Research, 2019, 26(24): 25359-25371.
27	LIU T, YANG B, GRAHAM N, et al. Trivalent metal cation cross-linked graphene oxide membranes for NOM removal in water treatment[J]. Journal of Membrane Science, 2017, 542: 31-40.
28	LI B J, CAO H Q, SHAO J, et al. Superparamagnetic Fe₃O₄ nanocrystals@graphene composites for energy storage devices[J]. Journal of Materials Chemistry, 2011, 21(13): 5069-5075.
29	LI J, WANG Y C, ZHOU T, et al. Nanoparticle superlattices as efficient bifunctional electrocatalysts for water splitting[J]. Journal of the American Chemical Society, 2015, 137(45): 14305-14312.
30	徐怀良. 四氧化三铁/还原氧化石墨烯复合材料的制备及其微波吸收性能和锂电性能研究[D]. 合肥: 安徽大学, 2012.
	XU H L. Preparation, microwave absorption and lithium ion batteries performance of Fe₃O₄/r-GO composites[D]. Hefei: Anhui University, 2012.
31	ZHOU G M, LI L, MA C Q, et al. A graphene foam electrode with high sulfur loading for flexible and high energy Li-S batteries[J]. Nano Energy, 2015, 11: 356-365.
32	YANG S B, FENG X L, WANG X C, et al. Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions[J]. Angewandte Chemie, 2011, 50(23): 5339-5343.

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Fe³⁺ crosslinking reduced graphene oxides free-standing film by pre-encapsulated Fe₃O₄ nanospheres for lithium storage

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