Electrochemical thermal stability of the LiFePO4/LiNi0.8Co0.15Al0.05O2 blend cathode material for lithium ion batteries

doi:10.12028/j.issn.2095-4239.2016.00.010

Energy Storage Science and Technology ›› 2016, Vol. 5 ›› Issue (4): 478-485.doi: 10.12028/j.issn.2095-4239.2016.00.010

Previous Articles Next Articles

Electrochemical thermal stability of the LiFePO₄/LiNi_0.8Co_0.15Al_0.05O₂ blend cathode material for lithium ion batteries

ZHU Lei, JIA Di, YU Chao, WU Yongmin, WU Xiaomeng, TANG Weiping

Shanghai Institute of Space Power Sources , Shanghai 200245, China

Received:2015-12-31 Revised:2016-01-24 Online:2016-07-01 Published:2016-07-01

Abstract

Abstract:

The LiFePO₄/LiNi_0.8Co_0.15Al_0.05O₂ blend cathode material for lithium ion batteries was prepared by ball-milling to improve the electrochemical thermal stability of LiNi_0.8Co_0.15Al_0.05O₂. The crystalline structure, morphology and electrochemical performance were characterized by X-ray diffraction, scanning electron microscopy and electrochemical tests. The results showed that LiNi_0.8Co_0.15Al_0.05O₂ was coated by the LiFePO4 nanoparticals. LiFePO₄/LiNi_0.8Co_0.15Al_0.05O₂ blend cathode material exhibited an excellent electrochemical thermal stability with 82.0% capacity retention after 100 cycles at 50oC, which was is much better than 72.9% of the pristine LiNi_0.8Co_0.15Al_0.05O₂.

Key words: LiNi_0.8Co_0.15Al_0.05O₂, LiFePO₄, blend cathode material, lithium ion battery, thermal stability

ZHU Lei, JIA Di, YU Chao, WU Yongmin, WU Xiaomeng, TANG Weiping. Electrochemical thermal stability of the LiFePO₄/LiNi_0.8Co_0.15Al_0.05O₂ blend cathode material for lithium ion batteries[J]. Energy Storage Science and Technology, 2016, 5(4): 478-485.

[1]	Haitao LI, Lingli KONG, Xin ZHANG, Chuanjun YU, Jiwei WANG, Lin XU. The effects of N/P design on the performances of Ni-rich NCM/Gr lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(7): 2040-2045.
[2]	Sida HUO, Wendong XUE, Xinli LI, Yong LI. Visualization analysis of composite electrolytes for lithium battery based on CiteSpace [J]. Energy Storage Science and Technology, 2022, 11(7): 2103-2113.
[3]	XIN Yaoda, LI Na, YANG Le, SONG Weili, SUN Lei, CHEN Haosen, FANG Daining. Integrated sensing technology for lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(6): 1834-1846.
[4]	LIU Hangxin, CHEN Xiantao, SUN Qiang, ZHAO Chenxi. Cycle performance characteristics of soft pack lithium-ion batteries under vacuum environment [J]. Energy Storage Science and Technology, 2022, 11(6): 1806-1815.
[5]	Biao MA, Chunjing LIN, Lei LIU, Xiaole MA, Tianyi MA, Shiqiang LIU. Venting characteristics and flammability limit of thermal runaway gas of lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(5): 1592-1600.
[6]	Luyu GAN, Rusong CHEN, Hongyi PAN, Siyuan WU, Xiqian YU, Hong LI. Multiscale research strategy of lithium ion battery safety issue： Experimental and simulation methods [J]. Energy Storage Science and Technology, 2022, 11(3): 852-865.
[7]	Pengchao HUANG, Jiaqiang E. State estimation of lithium-ion battery based on dual adaptive Kalman filter [J]. Energy Storage Science and Technology, 2022, 11(2): 660-666.
[8]	Shanshan MA, Tingting FANG, Liuqian YANG, Shuwan HU. Application of chromatography-mass spectrometry in study of lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(1): 60-65.
[9]	Jinhui GAO, Yinglong CHEN, Fanhui MENG, Meichao DING, Li WANG, Gang XU, Xiangming HE. Research on in-situ optical microscopic observation in lithium-ion batteries [J]. Energy Storage Science and Technology, 2022, 11(1): 53-59.
[10]	Tianyi MA, Weizhe WANG, Chunjing LIN, Guangli BAI, Zhen WEI, Shiqiang LIU. Feasibility of the multistage reuse of commercial LiFePO₄/C batteries [J]. Energy Storage Science and Technology, 2022, 11(1): 119-126.
[11]	Zeng'ang JIA, Zhibin LING, Xuguang LI. Thermal characteristics of lithium-ion battery with sinusoidal charge and discharge pulsating current [J]. Energy Storage Science and Technology, 2021, 10(6): 2260-2268.
[12]	Kuining LI, Yuncheng XIE, Yi XIE, Qinghua BAI, Jintao ZHENG. Analysis of heat production of nickel-rich lithium-ion battery based on electrochemical thermal coupling model [J]. Energy Storage Science and Technology, 2021, 10(3): 1153-1162.
[13]	Jinhui GAO, Yunzhu CHEN, Yang YANG, Fanhui MENG, Hong XU, Li WANG, Jiang ZHOU, Xiangming HE. Research progress of reference electrode for lithium-ion batteries [J]. Energy Storage Science and Technology, 2021, 10(3): 987-994.
[14]	Li WANG, Jianhong LIU, Xiangming HE. Research progress on the practical applications of red phosphorus composite anodes [J]. Energy Storage Science and Technology, 2021, 10(2): 425-431.
[15]	Rongyan WEN, Zhihao GAO, Shulin MEN, Zuoqiang DAI, Jianmin ZHANG. Research progress of polyvinylidene fluoride based gel polymer electrolyte [J]. Energy Storage Science and Technology, 2021, 10(1): 40-49.

Electrochemical thermal stability of the LiFePO₄/LiNi_0.8Co_0.15Al_0.05O₂ blend cathode material for lithium ion batteries

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments