Engineering pseudocapacitive lithium storage based on ultra-fine SnS2-carbon3D microstructure

doi:10.19799/j.cnki.2095-4239.2020.0118

Abstract

Abstract:

A nanostructured coating with conductive carbon is an effective way to improve the electrochemical performance of conversion-type materials. In this study, a three-dimensional porous sandwich-type structure constructed using interconnected two-dimensional N,P-co-doped carbon sheets with a composite of SnS₂ nanoparticles embedded in a carbon matrix is proposed. The resulting unique porous structure with large specific surface and structural stability is capable of facilitating ion/electron transportation and providing more active sites to adsorb more Na⁺, while the ultra-fine SnS₂ nanoparticles can accommodate the stress change accompanying the volume expansion and contribute to reducing the Na⁺ diffusion length. The composite electrode demonstrates superior stability, as well as an excellent rate capability. A kinetic analysis demonstrates enhanced surface pseudocapacitive behavior benefiting from the structural design and ultra-fine nanoparticles, which are the two main factors leading to its outstanding performance.

Key words: lithium ion batteries, anode, high performance, pseudocapacitive

CLC Number:

TQ 028.8

Xingang MA, Yuwei ZANG, Lianke XIE, Jianguang YIN, Guoying ZHANG, Rongchun MA, Xianzheng YUAN. Engineering pseudocapacitive lithium storage based on ultra-fine SnS₂-carbon3D microstructure[J]. Energy Storage Science and Technology, 2020, 9(5): 1467-1471.

Figures/Tables 3

References 21

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Engineering pseudocapacitive lithium storage based on ultra-fine SnS₂-carbon3D microstructure

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