Fundamentals of electrochemistry(Ⅴ)--Electrochemical kinetic and charge-transfer process for electrochemical reaction

doi:10.3969/j.issn.2095-4239.2013.04.008

Abstract

Abstract: The charge-transfer process is the basis of an electrochemical reaction. The knowledge about charge-transfer processes can help us to recognize to the inherent nature through the electrochemical reaction representation, and to achieve the control in the electrochemical industry and the electrochemical reaction design. In this paper, we reviewed the scientific background of electrochemical kinetic and development of the charge-transfer process, and rethought about their scientific idea. We believe that a historical review can be very helpful for our future research.

Key words: electrochemistry, charge transfer, Tafel equation, Bulter-Volmer equation, quantum mechanism

CLC Number:

N092

JIA Zhijun, MA Hongyun, WU Xuran, LIAO Sida, WANG Baoguo. Fundamentals of electrochemistry(Ⅴ)--Electrochemical kinetic and charge-transfer process for electrochemical reaction[J]. Energy Storage Science and Technology, 2013, 2(4): 402-409.

References

[1] http://www.pep.com.cn/czwl/jszx/tbjx/tb8s/tb8s5/jc5/201008/t20100824_ 717292.htm.
[2] http://www.docin.com/p-139952780.html.
[3] Dai Nianzu(戴念祖). The recognition development of electricity in ancient China[J]. History of Physics ,1976,5:280-284.
[4] Ma Hongyun(马洪运),Jia Zhijun(贾志军),Wu Xuran(吴旭冉),Liao Sida(廖斯达),Wang Baoguo(王保国). Mass conservation and Faraday's law One of fundamental theories of electrochemistry (Ⅰ)[J]. Energy Storage Science and Technology (储能科学与技术),2012,1(2):139-143.
[5] Conway B E. Historical Development of the Understanding of Charge-Transfer Process in Electrochemistry[M]. Electrochemistry Past and Present,American Chemical Society,1989.
[6] Lu Yunwen(卢运雯). The introduction of the solution electrolysis theory[J]. J ournal of Qujing Narmal College (曲靖师专学报),1998,17(5-6):64-66.
[7] Liao Sida(廖斯达),Jia Zhijun(贾志军),Ma Hongyun(马洪运),Wu Xuran(吴旭冉),Wang Baoguo(王保国). Fundamentals of electrochemistry(Ⅱ) Thermodynamic equilibrium and Nernst equation[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(1):63-68.
[8] Burstein G T. A hundred years of Tafel's equation:1905-2005[J]. Corro. Sci. ,2005(47):2858-2870.
[9] Müller K. Who was Tafel?[J]. J ournal of the Research Institute for Catalysis Hokkaido University ,1969,17(1):54-75.
[10] Butler J A V. The kinetic interpretation of the Nernst theory of electromotive force[J]. Trans. Faraday Soc. ,1924,19:729-734.
[11] Butler J A V. Hydrogen overvoltage and the reversible hydrogen electrode[J]. Proceedings of the Royal Society : A ,1936,157:423-433.
[12] Wu Xuran(吴旭冉),Jia Zhijun(贾志军),Ma Hongyun(马洪运),Liao Sida(廖斯达),Wang Baoguo(王保国). Fundamentals of electrochemistry(Ⅲ) Electrical double layer model and its development[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(2):152-156.
[13] Li Di(李荻). Electrochemistry Theory(电化学原理)[M]. Beijing:Beihang University Press,1999.
[14] Pletcher D,Walsh F C. Industrial Electrochemistry[M]. 2nd ed. New York:Chapman and Hall,1990:1-18.
[15] Bockris J M,Khan S U M. Quantum Electrochemistry[M]. New York:Dlenum Press,1987:273-446.
[16] Bowden F P,Rideal E K. The electrolytic behavior of thin films PartⅠ:Hydrogen[J]. Proceedings of the Royal Society : A ,1928,120:59-79.
[17] Gurney R W. The quantum mechanics of electrolysis[J]. Proceedings of the Royal Society : A ,1931,134:137-154.
[18] Oliphant M L E,Moon P B. The liberation of electrons from metal surfaces by positive ions PartⅡ:Theoretical[J]. Proceedings of the Royal Society : A ,1930,127:388-406.
[19] http://wenku.baidu.com/view/c7e82b2fbd64783e09122b55.html.
[20] Wang Shizhong(王世忠),Liu Xuan(刘旋). Kinetics of oxygen reduction over Sm 0.5 Sr 0.5 CoO 3 [J]. Acta Physico-Chimica Sinica (物理化学学报),2004,20(5):472-477.