Simulation of the effects of electrode parameters on all-vanadium redox flow battery performance
LIAO Sida, SONG Shiqiang, ZHANG Jianbo, WANG Baoguo
2014, 3 (4):
395-405.
doi: 10.3969/j.issn.2095-4239.2014.04.013
In order to study the all-vanadium redox flow battery (VFB), a mechanistic model is developed based on the transport and reactions to simulate the effects of various electrode parameters on the battery's overall performance and internal polarizations for a VFB charged at isothermal and steady state. The parameters included the carbon felt's geometry structure parameters (thickness Lt, Compression ratio CR), electrical parameters (specific surface area a, electric conductivity) and operating parameter (charging current density i). Numerical simulations showed that when Lt increased from 1.5 mm to 3.5 mm, the terminal voltage drop is 3 mV only; when CR increased from 0.1 to 0.5, the terminal voltage drop is 16 mV; when a increased from 3.5×104 m2·m-3 to 3.5×106 m2·m-3, the terminal voltage drop is 30 mV; when increased from 18.9 S·m-1 to 164.4 S·m-1, the terminal voltage drop is 87 mV, and results also showed different two-dimensional over-potential distribution characteristics under different; when i increased from 100 mA·cm-2 to 150 mA·cm-2, the terminal voltage increase is 57 mV, if proportionally increased a, the terminal voltage increase is 46 mV only. Based on the terminal voltage and the over-potential distribution, the reasons for the effects of various parameters on the battery performance are discussed. The experimental validation showed similar results, which proved the reliability of the numerical simulation. Increasing CR, a and will significantly improve the battery performance. This should provide guidance to parameter design and to improve the performance of electrode material, and the improving of battery performances.
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