Energy Storage Science and Technology ›› 2014, Vol. 3 ›› Issue (4): 353-359.doi: 10.3969/j.issn.2095-4239.2014.04.009

• Chemical energy storage • Previous Articles     Next Articles

Activated carbons derived from fly ash and their electorchemical performances in supercapacitors

ZHANG Yafei1, ZHANG Chuanxiang1, WANG Li1, XING Baolin1, HUANG Guangxu1, DUAN Yuling2   

  1. 1School of Materials Science and Engineering,Henan Polytechnic University,Jiaozuo 454003,Henan,China;
    2School of Energy Science and Engineering,Hennan Polytechnic,Jiaozuo 454003,Henan,China
  • Received:2013-02-15 Online:2014-07-01 Published:2014-07-01

Abstract: The gasification of coal can produce large amounts of fly ash, which still contains untapped charcoal. Fly ash was demineralized by flotation and activated carbons (ACs) were prepared by activation using KOH. The effect of preparation conditions on the performance of ACs was analyzed. The results show that: ① Total pore volume and micropore volume increased with the alkali-carbon ratio, while the content of mesopores decreased; ②The capacitance increased with the alkali-carbon ratio, but become stable after 2∶1; ③The electrochemical performance was improved by demineralizion; ④Activated carbon electrode shows a high capacitance at high current density and excellent cycling performance.

Key words: fly ash, alkali-carbon ratio, activated carbon, electrochemical performance

CLC Number: