Research progress of Li3PS4 solid electrolyte

doi:10.19799/j.cnki.2095-4239.2021.0513

Abstract

Abstract:

All-solid-state lithium battery has become one of the most promising candidates to replace the traditional lithium battery utilizing liquid organic electrolytes due to its high safety and high energy density. The solid electrolyte is the crucial component of all-solid-state lithium battery, and sulfide electrolytes are attractive among solid electrolytes due to their high ionic conductivities and good mechanical ductility. Li₃PS₄ solid electrolyte with high ionic conductivity, wide electrochemical windows and low cost has been attracted significant attention in recent years. However, its poor air/moisture stability and low compatibility towards cathode/anode materials limit its large-scale application in high-performance all-solid-state lithium batteries. In this paper, the structural mechanism and preparation route of Li₃PS₄ solid electrolyte were reviewed by discussing the recent literature on Li₃PS₄ solid electrolyte. Then, the strategies applied to enhance the ionic conductivity, improve the chemical/electrochemical stability, and strengthen the mechanical properties of Li₃PS₄ are summarized, and the applications of Li₃PS₄ electrolytes in solid-state batteries combined with different kinds of electrode materials are reviewed. Based on the above analysis, this paper also pointed out the shortcomings of the current Li₃PS₄ solid electrolyte and prospected the research focus and development direction of Li₃PS₄ and other sulfide electrolytes in the future.

Key words: solid electrolyte, Li₃PS₄, all-solid-state battery, electrochemical performance, solid state lithium sulfur battery, conductivity

CLC Number:

TM 911

Chaochao WEI, Chuang YU, Zhongkai WU, Linfeng PENG, Shijie CHENG, Jia XIE. Research progress of Li₃PS₄ solid electrolyte[J]. Energy Storage Science and Technology, 2022, 11(5): 1368-1382.

Figures/Tables 8

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Composition	Conductivity(RT)/(S/cm)	Ref.
β-Li₃PS₄	1.60×10^-4	[54]
Li_3.06P_0.98Zn_0.02S_3.98O_0.02	1.12×10^-3	[54]
75Li₂S·(23)P₂S₅-2P₂O₅	2.53×10^-4	[56]
75Li₂S·23P₂S₅-2P₂Se₅	6.00×10^-4	[55]
90Li₃PS₄-10LLZO 98Li₃PS₄-2Al₂O₃ 98Li₃PS₄-2SiO₂ 86.9Li₃PS₄-13.1LiAlS₂ 2Li₃PS₄-LiI	2.40×10^-4 2.28×10^-4 1.84×10^-4 6.00×10^-4 6.30×10^-4	[57] [57] [57] [58] [59]

Sample	Conductivity(RT)/(S/cm)	E/GPa
Li₃PS₄	2.4×10^-4	23
95 Li₃PS₄-5LiI	2.9×10^-4	21
90 Li₃PS₄-10LiI	4.7×10^-4	21
80 Li₃PS₄-20LiI	1.1×10^-3	20
70 Li₃PS₄-30LiI	1.5×10^-3	19

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Research progress of Li₃PS₄ solid electrolyte

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