Prototype all-solid-state battery electrodes preparation and assembly technology

doi:10.19799/j.cnki.2095-4239.2021.0090

Abstract

Abstract:

All-solid-state lithium batteries, with good safety, long life and high energy, are an emerging option for next-generation technologies on the road to a green energy storage device. All-solid-state lithium batteries are prepared with all-solid electrode and all-solid electrolyte without liquid additives. Therefore, the electrode preparation and assembly of all solid-state lithium batteries are quite different from those of existing liquid lithium batteries. Here we summarize the typical assembly approaches of prototype all-solid-state batteries using oxide, sulfide, or polymer as solid electrolytes, providing reference for all-solid-state battery researchers.In this paper, the electrode preparation and assembly technology with the corresponding performance characteristics of several typical all-solid-state lithium batteries are reviewed in detail. The structure, cathode preparation methods, anode modification methods and battery assembly methods of oxide, sulfide and polymer solid electrolyte are summarized and analyzed respectively. Finally, some suggestions on the laboratory development and assembly methods of all solid state lithium batteries are given.

Key words: all-solid-state lithium batteries, electrodes preparation, assembly technology, solid electrolyte, lithium batteries

CLC Number:

TM 911

Yanming CUI, Zhihua ZHANG, Yuanqiao HUANG, Jiu LIN, Xiayin YAO, Xiaoxiong XU. Prototype all-solid-state battery electrodes preparation and assembly technology[J]. Energy Storage Science and Technology, 2021, 10(3): 836-847.

Figures/Tables 13

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Table 1

References 58

1	李泓. 全固态锂电池: 梦想照进现实[J]. 储能科学与技术, 2018, 7(2): 188-193.LI H. All solid state battery: Dream into reality[J]. Energy Storage Science and Technology, 2018, 7(2): 188-193.
2	JANEK J, ZEIER W G. A solid future for battery development[J]. Nature Energy, 2016. 1(9): 16141-16144.
3	PALACÍN M R. Recent advances in rechargeable battery materials: A chemist's perspective[J]. Chemical Society Reviews, 2009, 38(9): 2565-2575.
4	许晓雄, 邱志军, 官亦标, 等. 全固态锂电池技术的研究现状与展望[J]. 储能科学与技术, 2013, 2(4): 331-340, 341.XU X X, QIU Z J, GUAN Y B, et al. All-solid-state lithium-ion batteries: State-of-the-art development and perspective[J]. Energy Storage Science and Technology, 2013, 2(4): 331-340, 341.
5	OHTA S, KOMAGATA S, SEKI J, et al. Short communication all-solid-state lithium ion battery using garnet-type oxide and Li₃BO₃ solid electrolytes fabricated by screen-printing[J]. Journal of Power Sources, 2013, 238: 53-56.
6	OKUMURA T, TAKEUCHI T, KOBAYASHI H. All-solid-state lithium-ion battery using Li_2.2C_0.8B_0.2O₃ electrolyte[J]. Solid State Ionics, 2016, 288: 248-252.
7	HAN F, YUE J, CHEN C, et al. Interphase engineering enabled all-ceramic lithium battery[J]. Joule, 2018, 2: 497-508.
8	OHTA S, SEKI J, YAGI Y, et al. Co-sinterable lithium garnet-type oxide electrolyte with cathode for all-solid-state lithium ion battery[J]. Journal of Power Sources, 2014, 265: 40-44.
9	LI F Z, LI J X, ZHU F. Atomically intimate contact between solid electrolytes and electrodes for Li batteries[J]. Matter, 2019, 1(4): 1001-1016.
10	ZHOU Q, MA J, DONG S M, et al. Intermolecular chemistry in solid polymer electrolytes for high-energy-density lithium batteries[J]. Advanced Materials, 2019, 31(50): doi: 10.1002/adma.201902029.
11	OHTA S, KOBAYASHI T, SEKI J, et al. Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte[J]. Journal of Power Sources, 2012, 202: 332-335.
12	YUBUCHI S, ITO Y, MATSUYAMA T, et al. 5 V class LiNi_0.5Mn_1.5O₄ positive electrode coated with Li₃PO₄ thin film for all-solid-state batteries using sulfide solid electrolyte[J]. Solid State Ionics, 2016, 285: 79-82.
13	ZHANG Z H, CHEN S J, YAO X Y, et al. Enabling high-areal-capacity all-solid-state lithium-metal batteries by tri-layer electrolyte architectures[J]. Energy Storage Materials, 2020, 24: 714-718.
14	FU K, GONG Y, HITZ G T, et al. Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal-sulfur batteries[J]. Energy & Environmental Science, 2017, 10(7): 1568-1575.
15	YI E, SHEN H, HEYWOOD S, et al. All-solid-state batteries using rationally designed garnet electrolyte frameworks[J]. ACS Applied Energy Materials, 2020, 3(1): 170-175.
16	SCROSATI B, GARCHE J. Lithium batteries: Status, prospects and future[J]. Journal of Power Sources, 2010, 195(9): 2419-2430.
17	ZHAMU A, CHEN G R, LIU C G, et al. Reviving rechargeable lithium metal batteries: Enabling next-generation high-energy and high-power cells[J]. Energy and Environmental Science, 2012, 5(2): 5701-5707.
18	SHEN Y B, ZHANG Y T, HAN S J, et al. Unlocking the energy capabilities of lithium metal electrode with solid-state electrolytes[J]. Joule, 2018, 2(9): 1674-1689.
19	XU W, WANG J L, DING F, et al. Lithium metal anodes for rechargeable batteries[J]. Energy and Environmental Science, 2014, 7(2): 513-537.
20	WEST W C, WHITACRE J F, LIM J R. Chemical stability enhancement of lithium conducting solid electrolyte plates using sputtered LiPON thin films[J]. Journal of Power Sources, 2004, 126(1/2): 134-138.
21	ZHAO S L, FU Z W, QIN Q Z. A solid-state electrolyte lithium phosphorus oxynitride film prepared by pulsed laser deposition[J]. Thin Solid Films, 2002, 415(1/2): 108-113.
22	LIU Y J, LI C, LI B J, et al. Germanium thin film protected lithium aluminum germanium phosphate for solid-state Li batteries[J]. Advanced Energy Materials, 2018, 8(16): doi: 10.1002/aenm. 201702374.
23	TANG W, YIN X, KANG S, et al. Lithium silicide surface enrichment: A solution to lithium metal battery[J]. Advanced Materials, 2018, doi: 10.1002/adma. 201801745.
24	DU M J, LIAO K M, LU Q, et al. Recent advances in the interface engineering of solid-state Li-ion batteries with artificial buffer layers: Challenges, materials, construction, and characterization[J]. Energy & Environmental Science, 2019, 12(6): 1780-1804.
25	ZHANG Z H, ZHAO Y R, CHEN S J, et al. An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life[J]. Journal of Materials Chemistry A, 2017, 5(32): 16984-16993.
26	ZHANG Z H, CHEN S H, YANG J, et al. Stable cycling of all-solid-state lithium battery with surface amorphized Li_1.5Al_0.5Ge_1.5(PO₄)₃ electrolyte and lithium anode[J]. Electrochimica Acta, 2019, 297: 281-287.
27	ZHAO C Z, ZHANG X Q, CHENG X B, et al. An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes[J]. Proceedings of the National Academy of Sciences of the United States of America, 2017, 114(42): 11069-11074.
28	ZHANG Z Z, SHAO Y J, LOTSCH B, et al. New horizons for inorganic solid state ion conductors[J]. Energy & Environmental Science, 2018, 11(8): 1945-1976.
29	KAMAYA N, HOMMA K, YAMAKAWA Y, et al. A lithium superionic conductor[J]. Nature Materials, 2011, 10(9): 682-686.
30	TAN D, WU E A, NGUYEN H, et al. Elucidating reversible electrochemical redox of Li₆PS₅Cl solid electrolyte[J]. ACS Energy Letters, 2019, 4(10): 2418-2427.
31	OH D Y, NAM Y J, PARK K H, et al. Slurry-fabricable Li⁺-conductive polymeric binders for practical all-solid-state lithium-ion batteries enabled by solvate ionic liquids[J]. Advanced Energy Materials, 2019, 9(16): doi: 10.1002/aenm.201802927.
32	ZHANG X, LIU T, ZHANG S F, et al. Synergistic coupling between Li_6.75La₃Zr_1.75Ta_0.25O₁₂ and poly(vinylidene fluoride) induces high ionic conductivity, mechanical strength, and thermal stability of solid composite electrolytes[J]. Journal of the American Chemical Society, 2017, 139(39): 13779-13785.
33	VAIL J R, KRICK B A, MARCHMAN K R, et al. Polytetrafluoroethylene (PTFE) fiber reinforced polyetheretherketone (PEEK) composites[J]. Wear, 2011, 270(11/12): 737-741.
34	HIPPAUF F, SCHUMM B, DOERFLER S, et al. Overcoming binder limitations of sheet-type solid-state cathodes using a solvent-free dry-film approach[J]. Energy Storage Materials, 2019, 21: 390-398.
35	DUONG H, SHIN J, YUDI Y. Dry electrode coating technology[C]//48th Power Sources Conference, 2018.
36	LEE Y G, FUJIKI S, JUNG C, et al. High-energy long-cycling all-solid-state lithium metal batteries enabled by silver-carbon composite anodes[J]. Nature Energy, 2020, 5: 299-308.
37	ZHU Y Z, HE X F, MO Y F. Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations[J]. ACS Applied Materials & Interfaces, 2015, 7(42): 23685-23693.
38	WAN H L, PENG G, YAO X Y, et al. Cu₂ZnSnS₄/graphene nanocomposites for ultrafast, long life all-solid-state lithium batteries using lithium metal anode[J]. Energy Storage Materials, 2016, 4: 59-65.
39	YAO X Y, HUANG N, HAN F D, et al. High-performance all-solid-state lithium-sulfur batteries enabled by amorphous sulfur-coated reduced graphene oxide cathodes[J]. Advanced Energy Materials, 2017, 7(17): doi: 10.1002/aenm201602923.
40	GAO Y, WANG D W, LI Y G, et al. Salt-based organic-inorganic nanocomposites: Towards a stable lithium metal/Li₁₀GeP₂S₁₂ solid electrolyte interface[J]. Angewandte Chemie, 2018, 57(41): 13608-13612.
41	CHIEN P H, FENG X Y, TANG M X, et al. Li distribution heterogeneity in solid electrolyte Li₁₀GeP₂S₁₂ upon electrochemical cycling probed by ⁷Li MRI[J]. The Journal of Physical Chemistry Letters, 2018, 9(8): 1990-1998.
42	WANG C H, ZHAO Y, SUN Q, et al. Stabilizing interface between Li₁₀SnP₂S₁₂ and Li metal by molecular layer deposition[J]. Nano Energy, 2018, 53: 168-174.
43	ZHAO Y R, WU C, PENG G, et al. A new solid polymer electrolyte incorporating Li₁₀GeP₂S₁₂ into a polyethylene oxide matrix for all-solid-state lithium batteries[J]. Journal of Power Sources, 2016, 301: 47-53.
44	KIM W, CHO J J, KANG Y K, et al. Study on cycling performances of lithium-ion polymer cells assembled by in situ chemical cross-linking with star-shaped siloxane acrylate[J]. Journal of Power Sources, 2008, 178(2): 837-841.
45	XU J J, YE H. Polymer gel electrolytes based on oligomeric polyether/cross-linked PMMA blends prepared viain situ polymerization[J]. Electrochemistry Communications, 2005, 7(8): 829-835.
46	WEI Z Y, CHEN S J, WANG J Y, et al. A large-size, bipolar-stacked and high-safety solid-state lithium battery with integrated electrolyte and cathode[J]. Journal of Power Sources, 2018, 394: 57-66.
47	ZHENG J, HU Y Y. New insights into the compositional dependence of Li-ion transport in polymer-ceramic composite electrolytes[J]. ACS Applied Materials & Interfaces, 2018, 10(4): 4113-4120.
48	CHEN L, LI Y T, LI S P, et al. PEO/garnet composite electrolytes for solid-state lithium batteries: From "ceramic-in-polymer" to "polymer-in-ceramic"[J]. Nano Energy, 2018, 46: 176-184.
49	张建军, 董甜甜, 杨金凤, 等. 全固态聚合物锂电池的科研进展、挑战与展望[J]. 储能科学与技术, 2018, 7(5): 861-868.ZHANG J J, DONG T T, YANG J F, et al. Research progress, challenge and perspective of all-solid-state polymer lithium batteries[J]. Energy Storage Science and Technology, 2018, 7(5): 861-868.
50	EBADI M, MARCHIORI C, MINDEMARK J, et al. Assessing structure and stability of polymer/lithium-metal interfaces from first-principles calculations[J]. Journal of Materials Chemistry A, 2019, 7(14): 8394-8404.
51	ZHOU W D, WANG Z X, PU Y, et al. Double-layer polymer electrolyte for high-voltage all-solid-state rechargeable batteries[J]. Advanced Materials, 2019, 31(4): doi: 10.1002/adma.201805574.
52	WANG C, WANG T, WANG L L, et al. Differentiated lithium salt design for multilayered PEO electrolyte enables a high-voltage solid-state lithium metal battery[J]. Advanced Science, 2019, 6(22): doi: 10.1002/advs. 201901036.
53	YANG H C, ZHANG Y M, TENNENBAUM M J, et al. Polypropylene carbonate-based adaptive buffer layer for stable interfaces of solid polymer lithium metal batteries[J]. ACS Applied Materials & Interfaces, 2019, 11(31): 27906-27912.
54	DUAN H, FAN M, CHEN W P, et al. Extended electrochemical window of solid electrolytes via heterogeneous multilayered structure for high-voltage lithium metal batteries[J]. Advanced Materials, 2019, 31(12): doi: 10. 1002/adma. 201807789.
55	WU N, LI Y T, DOLOCAN A, et al. In situ formation of Li₃P layer enables fast Li⁺ conduction across Li/solid polymer electrolyte interface[J]. Advanced Functional Materials, 2020, 30(22): doi:10.1002/adfm. 202000831.
56	LIU Q, CAI B Y, LI S, et al. Long-cycling and safe lithium metal batteries enabled by the synergetic strategy of ex situ anodic pretreatment and an in-built gel polymer electrolyte[J]. Journal of Materials Chemistry A, 2020, 8(15): 7197-7204.
57	JIANG T L, HE P G, WANG G X, et al. Solvent-free synthesis of thin, flexible, nonflammable garnet-based composite solid electrolyte for all-solid-state lithium batteries[J]. Advanced Energy Materials, 2020, 10(12): doi: 10.1002/aenm. 201903376.
58	CHENG X B, YAN C, CHEN X, et al. Implantable solid electrolyte interphase in lithium-metal batteries[J]. Chem, 2017, 2(2): 258-270.

电池	纽扣电池	软包电池	模具电池
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硫化物固体电解质基全固态锂电池	☆	☆	☆☆☆☆☆
聚合物固体电解质基全固态锂电池	☆☆☆☆☆	☆☆☆	☆

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