高首效长寿命硅碳复合材料的制备及其电化学性能

doi:10.19799/j.cnki.2095-4239.2020.0086

储能科学与技术 ›› 2020, Vol. 9 ›› Issue (3): 826-830.doi: 10.19799/j.cnki.2095-4239.2020.0086

高首效长寿命硅碳复合材料的制备及其电化学性能

张刚¹(), 刘兴稳¹, 张帆¹, 陈至炜²

^1.中天超容科技有限公司，江苏南通 226009
^2.中天储能科技有限公司，江苏南通 226009

收稿日期:2020-02-28 修回日期:2020-03-30 出版日期:2020-05-05 发布日期:2020-05-11
作者简介:张刚（1978—），男，高级工程师，研究方向为锂离子电池材料、超级电容器材料及储能器件，E-mail: zhangg@chinaztt.com。

Preparation and electrochemical performance of high initial coulombic efficiency and long life Si/C composite material

ZHANG Gang¹(), LIU Xingwen¹, ZHANG Fan¹, CHEN Zhiwei²

^1.Zhongtian Supercapacitor Technology Co. Ltd. , Nangtong 226009, Jiangsu, China
^2.Zhongtian Energy Storage Technology Co. Ltd. , Nangtong 226009, Jiangsu, China

Received:2020-02-28 Revised:2020-03-30 Online:2020-05-05 Published:2020-05-11

摘要/Abstract

摘要：

本工作以氧化亚硅（SiO）、沥青、硝酸铝和氢化锂为主要原料，通过层-层包覆和一系列化学反应，制备了SiO@C@Al₂O₃和Li-Si-O@C@LiAlO₂的三明治结构的硅碳复合材料。采用SEM、TEM、XRD和激光粒度分析仪等对制备样品进行了微观形貌表征和物相结构分析，采用CR2032扣电评估不同材料的可逆比容量、首效和循环性能，结果表明，相比于普通SiO@C，改性后的SiO@C@Al₂O₃和Li-Si-O@C@LiAlO₂复合材料在首效和循环性能上提升明显，呈现出优异的电化学性能。本工作制备方法操作简单、成本低，适合工业化生产。

关键词: 硅碳, Al₂O₃包覆, LiAlO₂, 预锂化, 锂离子电池

Abstract:

Through layer-layer coating and series chemical reaction, the sandwich structure of SiO@C@Al₂O₃and Li-Si-O@C@LiAlO₂ was prepared by using SiO, pitch, aluminum nitrate and LiH as the main raw materials. The morphology and the phase structure of the samples were characterized by SEM, TEM, XRD and laser particle size analyzer. It was adopted by CR2032 cell to evaluate the reversible capacity, initial coulombic efficiency and capacity retention of different products. The results showed that compared with the common SiO@C, the modified SiO@C@Al₂O₃and Li-Si-O@C@LiAlO₂ composites had excellent electrochemical performance in initial Coulombic efficiency and capacity retention. This preparation was simple operation, low cost and suitable for industrial production.

Key words: SiO@C, Al₂O₃ coating, LiAlO₂, pre-lithiated, lithium ion battery

张刚, 刘兴稳, 张帆, 陈至炜. 高首效长寿命硅碳复合材料的制备及其电化学性能[J]. 储能科学与技术, 2020, 9(3): 826-830.

ZHANG Gang, LIU Xingwen, ZHANG Fan, CHEN Zhiwei. Preparation and electrochemical performance of high initial coulombic efficiency and long life Si/C composite material[J]. Energy Storage Science and Technology, 2020, 9(3): 826-830.

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参考文献 11

1	LIU X, ZHAO H L, XIE J Y, et al. SiO_x（0≤x≤2） based anode materials for lithium-ion batteries[J]. Progress in Chemistry, 2015, 27(4): 336-348.
2	WOO J, BAEK S H, PARK J S, et al. Improved electrochemical performance of boron-doped SiO negative electrode materials in lithium-ion batteries[J]. Journal of Power Sources, 2015, 299: 25-31.
3	刘伯男, 徐泉, 褚赓, 等. 锂离子电池高容量硅碳负极材料研究进展[J]. 储能科学与技术, 2016, 5(4): 417-421.
	LIU Bonan, XU Quan, CHU Geng, et al. Research progress of high capacity silicon carbon anode materials for lithium ion batteries[J]. Energy Storage Science and Technology, 2016, 5(4): 417-421.
4	鲁豪祺, 林少雄, 陈伟伦, 等. 锂离子电池硅碳复合材料研究进展[J]. 储能科学与技术, 2018, 7(4): 595-606.
	LU Haoqi, LIN Shaoxiong, CHEN Weilun, et al. Research progress of SiO_x/C composites for Li-ion batteries[J]. Energy Storage Science and Technology, 2018, 7(4): 595-606.
5	XU Q, SUN J K, YIN Y X, et al. Facile synthesis of blocky SiO_x/C with graphite-like structure for high-performance lithium-ion battery anodes[J]. Advanced Functional Materials, 2018, doi: 10.1002/adfm.201705235. doi: 10.1002/adfm.201705235
6	SEPEHR H, OHKUBO H, KODZUKA M, et al. Evidence for nano-Si clusters in amorphous SiO anode materials for rechargeable Li-ion batteries[J]. Scripta Materialia, 2013, 69: 92-95.
7	YANG X L, WEN Z Y, XU X X, et al. Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries[J]. Journal of Power Sources, 2007, 164: 880-884.
8	曹志颖, 孙红亮, 杨亚洲, 等. 锂离子电池硅碳复合负极材料研究进展[J]. 电源技术, 2018, 42(5): 722-724.
	CAO Zhiyin, SUN Hongliang, YANG Yazhou, et al. Research progress of SiO_x/C composite anode materials for lithium ion batteries[J]. Chinese Journal of Power Sources, 2018, 42(5): 722-724.
9	ZHANG M, ZHANG T F, MA Y F, et al. Latest development of nanostructured Si/C materials for lithium anode studies and applications[J] . Energy Storage Materials, 2016, 4: 1-14.
10	沈晓辉, 范瑞娟, 田占元, 等. 锂离子电池硅碳负极材料研究进展[J]. 硅酸盐学报, 2017, 45(10): 1530-1538.
	SHEN Xiaohui, FAN Ruijuan, TIAN Zhanyuan, et al. Research progress of SiO_x/C anode materials for lithium ion batteries[J]. Journal of Chinese Ceramic Society, 2017, 45(10): 1530-1538.
11	HOU G L, CHENG B L, YANG Y J, et al. Multiscale buffering engineering in silicon-carbon anode for ultrastable Li-ion storage[J]. ACS Nano, 2019, 13: 10179-10190.

不同样品	D10/μm	D50/μm	D90/μm	D99/μm
SiO	2.77	5.96	8.58	11.37
SiO@C	3.93	7.94	14.61	21.22
SiO@C@Al₂O₃	4.81	8.36	14.58	20.98

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高首效长寿命硅碳复合材料的制备及其电化学性能

Preparation and electrochemical performance of high initial coulombic efficiency and long life Si/C composite material

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