钠离子电池层状氧化物正极：层间滑移，相变与性能

doi:10.19799/j.cnki.2095-4239.2020.0123

摘要/Abstract

摘要：

由于钠资源丰富，钠离子电池（SIB）作为二次离子电池已经受到越来越多地关注，特别是对于大规模储能而言。但是，由于缺乏合适的宿主材料可逆地脱/嵌Na离子，其发展受到了极大限制。层状过渡金属氧化物（Na_xMO₂，M=Fe、Mn、Ni、Co、Cr及其组合）是一类重要的SIB正极材料。由于其理论容量高、结构简单等优势，因而具有良好的发展前景。与锂的层状过渡金属氧化物不同，钠层状过渡金属氧化物易发生层间滑移以及相变。本文总结了Na_xMO₂正极材料的结构演变、电化学性能的最新进展。旨在阐明结构演变与电池性能(循环性能、倍率性能和能量效率)的关联。此外，本文还提出了几种策略来缓解这种问题。

关键词: 正极材料, 相变, 层间滑移, 钠离子电池, 层状氧化物

Abstract:

Due to the abundance of sodium resources, sodium-ion batteries (SIBs), as rechargeable batteries, have received increasing attention, especially for large-scale energy storage systems. However, the development of SIBs is hindered by the lack of suitable host materials to reversibly insert/extract Na ions. Layered transition metal oxides (Na_xMO₂, M = Fe, Mn, Ni, Co, Cr and their combinations) are promising cathode materials for SIBs due to their high theoretical capacity and simple structure. Interlayer glide and phase transitions are more prone to occur in sodium transition metal layered oxides than in their lithium counterparts. In this review, recent progress on the structural evolution and electrochemical performance of Na_xMO₂ materials are summarized. The dependence of the battery performance (the cycle performance, rate performance, and energy efficiency) on the structural evolution are discussed. In addition, this review presents several strategies to alleviate this problem and points to next generation electrode materials for SIBs.

Key words: cathode material, phase transition, interlayer glide, sodium ion battery, layered oxide

中图分类号:

TK 02

刘欢庆, 高旭, 陈军, 尹首懿, 邹康宇, 徐来强, 邹国强, 侯红帅, 纪效波. 钠离子电池层状氧化物正极：层间滑移，相变与性能[J]. 储能科学与技术, 2020, 9(5): 1327-1339.

Huanqing LIU, Xu GAO, Jun CHEN, Shouyi YIN, Kangyu ZOU, Laiqiang XU, Guoqiang ZOU, Hongshuai HOU, Xiaobo JI. Layered oxide cathode for sodium ion batteries: Interlayer glide, phase transition and performance[J]. Energy Storage Science and Technology, 2020, 9(5): 1327-1339.

图/表 8

参考文献 90

1	ARMAND M, TARASCON J M. Building better batteries[J]. Nature, 2008, 451(7179): 652-657.
2	MAITRA U, HOUSE R A, SOMERVILLE J W, et al. Oxygen redox chemistry without excess alkali-metal ions in Na_2/3[Mg_0.28Mn_0.72]O₂[J]. Nature Chemistry, 2018, 10(3): 288-295.
3	WANG S, SUN C, WANG N, et al. Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: Status, challenges and countermeasures[J]. Journal of Materials Chemistry A, 2019, 7(17): 10138-10158.
4	GUO S, LIU P, YU H, et al. A layered P2- and O3-type composite as a high-energy cathode for rechargeable sodium-ion batteries[J]. Angewandte Chemie-International Edition, 2015, 127(20): 1-7.
5	YAN P, ZHENG J, LIU J, et al. Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries[J]. Nature Energy, 2018, 3(7): 600-605.
6	LIU H, ZOU J, DING Y, et al. Flute-like Fe₂O₃ nanorods with modulating porosity for high performance anode materials in lithium ion batteries[J]. Chemistryselect, 2019, 4(13): 3681-3689.
7	YANG L, LIAO H, TIAN Y, et al. Rod‐like Sb₂MoO₆: Structure evolution and sodium storage for sodium‐ion batteries[J]. Small Methods, 2019, 3(5): doi: 10.1002/Smtd. 201800533.
8	GE P, LI S J, SHUAI H L, et al. Ultrafast sodium full batteries derived from X-Fe (X=Co, Ni, Mn) prussian blue analogs[J]. Advanced Materials, 2019, 31(3): 1806092-1806098.
9	GAO S, ZHAN X, CHENG Y T. Structural, electrochemical and Li-ion transport properties of Zr-modified LiNi_0.8Co_0.1Mn_0.1O₂ positive electrode materials for Li-ion batteries[J]. Journal of Power Sources, 2019, 410: 45-52.
10	LIU T, ZHANG Y, JIANG Z, et al. Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage[J]. Energy & Environmental Science, 2019, 12(5): 1512-1533.
11	LIU Q, HU Z, CHEN M, et al. Recent progress of layered transition metal oxide cathodes for sodium-ion batteries[J]. Small, 2019, 15(32): 1805381-1805324.
12	HUANG M, LI M, NIU C, et al. Recent advances in rational electrode designs for high-performance alkaline rechargeable batteries[J]. Advanced Functional Materials, 2019, 29(11): doi: 10.1002/adfm. 201807847.
13	NAYAK P K, YANG L, BREHM W, et al. From lithium-ion to sodium-ion batteries: Advantages, challenges, and surprises[J]. Angewandte Chemie-International Edition, 2018, 57(1): 102-120.
14	ISLAM M S, FISHER C A J. Lithium and sodium battery cathode materials: Computational insights into voltage, diffusion and nanostructural properties[J]. Chemical Society Reviews, 2014, 43(1): 185-204.
15	DE LA LLAVE E, BORGEL V, PARK K J, et al. Comparison between Na-ion and Li-ion cells: Understanding the critical role of the cathodes stability and the anodes pretreatment on the cells behavior[J]. ACS Applied Materials & Interfaces, 2016, 8(3): 1867-1875.
16	CHEN M, CHOU S L, DOU S X. Understanding challenges of cathode materials for sodium‐ion batteries using synchrotron‐based X‐ray absorption spectroscopy[J]. Batteries & Supercaps, 2019, 2(10): 842-851.
17	SONG W, JI X, PAN C, et al. A Na₃V₂(PO₄)₃ cathode material for use in hybrid lithium ion batteries[J]. Physical Chemistry Chemical Physics, 2013, 15(34): 14357-14363.
18	CHEN M, HUA W, XIAO J, et al. NASICON-type air-stable and all-climate cathode for sodium-ion batteries with low cost and high-power density[J]. Nature Communications, 2019, 10(1): doi: 10.1038/s41467-019-09170-5.
19	QIAN J F, WU C, CAO Y L, et al. Prussian blue cathode materials for sodium-ion batteries and other ion batteries[J]. Advanced Energy Materials, 2018, 8(17): doi: 10.1002/aenm.201702619.
20	GE P, LI S J, XU L Q, et al. Hierarchical hollow-microsphere metal-selenide@carbon composites with rational surface engineering for advanced sodium storage[J]. Advanced Energy Materials, 2019, 9(1): 1803035-1803013.
21	JO M R, KIM Y, YANG J, et al. Triggered reversible phase transformation between layered and spinel structure in manganese-based layered compounds[J]. Nature Communications, 2019, 10(1): 3385-3389.
22	KONG W, GAO R, LI Q, et al. Simultaneously tuning cationic and anionic redox in a P2-Na_0.67Mn_0.75Ni_0.25O₂ cathode material through synergic Cu/Mg co-doping[J]. Journal of Materials Chemistry A, 2019, 7(15): 9099-9109.
23	ORTIZ-VITORIANO N, DREWETT N E, GONZALO E, et al. High performance manganese-based layered oxide cathodes: Overcoming the challenges of sodium ion batteries[J]. Energy & Environmental Science, 2017, 10(5): 1051-1074.
24	FANG Y, CHEN Z, XIAO L, et al. Recent progress in iron-based electrode materials for grid-scale sodium-ion batteries[J]. Small, 2018, 14(9): 1703116-1703119.
25	HWANG J Y, MYUNG S T, SUN Y K. Sodium-ion batteries: Present and future[J]. Chemical Society Reviews, 2017, 46(12): 3529-3614.
26	LI Y M, LU Y X, ZHAO C L, et al. Recent advances of electrode materials for low-cost sodium-ion batteries towards practical application for grid energy storage[J]. Energy Storage Materials, 2017, 7: 130-151.
27	HONG S Y, KIM Y, PARK Y, et al. Charge carriers in rechargeable batteries: Na ions vs. Li ions[J]. Energy & Environmental Science, 2013, 6(7): 2067-2081.
28	DELMAS C. Sodium and sodium-ion batteries: 50 years of research[J]. Advanced Energy Materials, 2018, 8(17): 1703137-1703139.
29	DIDIER C, GUIGNARD M, SUCHOMEL M R, et al. Thermally and electrochemically driven topotactical transformations in sodium layered oxides Na_xVO₂[J]. Chemistry of Materials, 2016, 28(5): 1462-1471.
30	SUN Y, GUO S, ZHOU H. Adverse effects of interlayer-gliding in layered transition-metal oxides on electrochemical sodium-ion storage[J]. Energy & Environmental Science, 2019, 12(3): 825-840.
31	KOMABA S. Layered oxides as positive electrode materials for Na-ion batteries[J]. MRS Bulletin, 2014, 39: 416-422.
32	YANG L, LI X, LIU J, et al. Lithium-doping stabilized high-performance P2-Na_0.66Li_0.18Fe_0.12Mn_0.7O₂ cathode for sodium ion batteries[J]. Journal of the American Chemical Society, 2019, 141(16): 6680-6689.
33	DELMAS CC.F, P. H. Structural classification and properties of the layered oxides[J]. Physica99B, 1980: 81-85.
34	XU W, ZOU G, HOU H, et al. Single particle electrochemistry of collision[J]. Small, 2019, doi: 10.1002/smll.201804908. doi: 10.1002/smll.201804908
35	NAYAK P K, ERICKSON E M, SCHIPPER F, et al. Review on challenges and recent advances in the electrochemical performance of high capacity Li- and Mn-rich cathode materials for Li-ion batteries[J]. Advanced Energy Materials, 2018, 8(8): doi: 10.1002/aenm.201702397.
36	GAO X, JIANG F, YANG Y, et al. Chalcopyrite-derived Na_xMO₂ (M=Cu, Fe, Mn) cathode: Tuning impurities for self-doping[J]. ACS Applied Materials & Interfaces, 2019, 12(2): 2432-2444.
37	DE BOISSE B M, CHENG J H, CARLIER D, et al. O3-Na_xMn_1/3Fe_2/3O₂ as a positive electrode material for Na-ion batteries: Structural evolutions and redox mechanisms upon Na⁺(de) intercalation[J]. Journal of Materials Chemistry A, 2015, 3(20): 10976-10989.
38	JUNG Y H, CHRISTIANSEN A S, JOHNSEN R E, et al. In situ X-ray diffraction studies on structural changes of a P2 layered material during electrochemical desodiation/sodiation[J]. Advanced Functional Materials, 2015, 25(21): 3227-3237.
39	YABUUCHI N, HARA R, KAJIYAMA M, et al. New O2/P2-type Li-excess layered manganese oxides as promising multi-functional electrode materials for rechargeable Li/Na batteries[J]. Advanced Energy Materials, 2014, 4(13): doi: 10.1002/aenm.201301453.
40	BUCHER N, HARTUNG S, FRANKLIN J B, et al. P2-Na_xCo_yMn_1-_yO₂ (y=0, 0.1) as cathode materials in sodium-ion batteries-effects of doping and morphology to enhance cycling stability[J]. Chemistry of Materials, 2016, 28(7): 2041-2051.
41	CLéMENT R J, BRUCE P G, GREY C P. Review-manganese-based P2-type transition metal oxides as sodium-ion battery cathode materials[J]. Journal of the Electrochemical Society, 2015, 162(14): A2589-A2604.
42	WANG P F, YOU Y, YIN Y X, et al. Layered oxide cathodes for sodium-ion batteries: Phase transition, air stability, and performance[J]. Advanced Energy Materials, 2018, 8(8): doi: 10.1002/aenm.201701912.
43	KOMABA S, YABUUCHI N, NAKAYAMA T, et al. Study on the reversible electrode reaction of Na_1-_xNi_0.5Mn_0.5O₂ for a rechargeable sodium-ion battery[J]. Inorganic Chemistry, 2012, 51(11): 6211-6220.
44	TALAIE E, DUFFORT V, SMITH H L, et al. Structure of the high voltage phase of layered P2-Na_2/3-_zMn_1/2Fe_1/2O₂ and the positive effect of Ni substitution on its stability[J]. Energy & Environmental Science, 2015, 8(8): 2512-2523.
45	YUAN D D, WANG Y X, CAO Y L, et al. Improved electrochemical performance of Fe-substituted NaNi_0.5Mn_0.5O₂ cathode materials for sodium-ion batteries[J]. ACS Applied Materials & Interfaces, 2015, 7(16): 8585-8591.
46	CLÉMENT R J, BILLAUD J, ROBERT ARMSTRONG A, et al. Structurally stable Mg-doped P2-Na_2/3Mn_1-_yMg_yO₂ sodium-ion battery cathodes with high rate performance: Insights from electrochemical, NMR and diffraction studies[J]. Energy & Environmental Science, 2016, 9(10): 3240-3251.
47	MA H, SU H, AMINE K, et al. Triphase electrode performance adjustment for rechargeable ion batteries[J]. Nano Energy, 2018, 43: 1-10.
48	BRACONNIER J J, DELMAS C, HAGENMULLER P. Etude par desintercalation electrochimique des systemes Na_xCrO₂ et Na_xNiO₂[J]. Materials Research Bulletin, 1982, 17: 993-1000.
49	YABUUCHI N, YANO M, YOSHIDA H, et al. Synthesis and electrode performance of O3-Type NaFeO₂-NaNi_1/2Mn_1/2O₂ solid solution for rechargeable sodium batteries[J]. Journal of the Electrochemical Society, 2013, 160(5): A3131-A3137.
50	YOSHIDA H, YABUUCHI N, KOMABA S. NaFe_0.5Co_0.5O₂ as high energy and power positive electrode for Na-ion batteries[J]. Electrochemistry Communications, 2013, 34: 60-63.
51	XIE Y, WANG H, XU G, et al. In operando XRD and TXM study on the metastable structure change of NaNi_1/3Fe_1/3Mn_1/3O₂ under electrochemical sodium-ion intercalation[J]. Advanced Energy Materials, 2016, 6(24): doi: 10.1002/aenm.201601306.
52	SATHIYA M, HEMALATHA K, RAMESHA K, et al. Synthesis, structure, and electrochemical properties of the layered sodium insertion cathode material: NaNi_1/3Mn_1/3Co_1/3O₂[J]. Chemistry of Materials, 2012, 24(10): 1846-1853.
53	YAO H R, WANG P F, WANG Y, et al. Excellent comprehensive performance of Na-based layered oxide benefiting from the synergetic contributions of multimetal ions[J]. Advanced Energy Materials, 2017, 7(15): doi: 10.1002/aenm.201700189.
54	VITOUX L, GUIGNARD M, SUCHOMEL M R, et al. The Na_xMoO₂ phase diagram (1/2≤x<1): An electrochemical devil's staircase[J]. Chemistry of Materials, 2017, 29(17): 7243-7254.
55	WANG X, TAMARU M, OKUBO M, et al. Electrode properties of P2-Na_2/3Mn_yCo_1-yO₂ as cathode materials for sodium-ion batteries[J]. Journal of Physical Chemistry C, 2013, 117: 15545-15551.
56	SHI Y, LI S, GAO A, et al. Probing the structural transition kinetics and charge compensation of the P2-Na_0.78Al_0.05Ni_0.33Mn_0.60O₂ cathode for sodium ion batteries[J]. ACS Applied Materials & Interfaces, 2019, 11(27): 24122-24131.
57	LU Z H, DAHN J R. In situ X-ray diffraction study of P2-Na_2/3Ni_1/3Mn_2/3O₂[J]. Journal of the Electrochemical Society, 2001, 148(11): A1225-A1229.
58	YABUUCHI N, KAJIYAMA M, IWATATE J, et al. P2-type Na_xFe_1/2Mn_1/2O₂ made from earth-abundant elements for rechargeable Na batteries[J]. Nature Materials, 2012, 11(6): 512-517.
59	SOMERVILLE J W, SOBKOWIAK A, TAPIA-RUIZ N, et al. Nature of the “Z”-phase in layered Na-ion battery cathodes[J]. Energy & Environmental Science, 2019, 12(7): 2223-2232.
60	TALAIE E, KIM S Y, CHEN N, et al. Structural evolution and redox processes involved in the electrochemical cycling of P2-Na_0.67Mn_0.66Fe_0.20Cu_0.14O₂[J]. Chemistry of Materials, 2017, 29(16): 6684-6697.
61	DU K, ZHU J, HU G, et al. Exploring reversible oxidation of oxygen in a manganese oxide[J]. Energy & Environmental Science, 2016, 9(8): 2575-2577.
62	RONG X, LIU J, HU E, et al. Structure-induced reversible anionic redox activity in Na layered oxide cathode[J]. Joule, 2018, 2(1): 125-140.
63	LI Q, QIAO Y, GUO S, et al. Both cationic and anionic Co-(de)intercalation into a metal-oxide material[J]. Joule, 2018, 2(6): 1134-1145.
64	MALETTI S, GIEBELER L, OSWALD S, et al. Irreversible made reversible: Increasing the electrochemical capacity by understanding the structural transformations of Na_xCo_0.5Ti_0.5O₂[J]. ACS Applied Materials & Interfaces, 2018, 10(42): 36108-36119.
65	RISTHAUS T, CHEN L, WANG J, et al. P3 Na_0.9Ni_0.5Mn_0.5O₂ cathode material for sodium ion batteries[J]. Chemistry of Materials, 2019, 31: 5376-5383.
66	SONG B, HU E, LIU J, et al. A novel P3-type Na_2/3Mg_1/3Mn_2/3O₂ as high capacity sodium-ion cathode using reversible oxygen redox[J]. Journal of Materials Chemistry A, 2019, 7(4): 1491-1498.
67	RADIN M D, VAN DER VEN A. Stability of prismatic and octahedral coordination in layered oxides and sulfides intercalated with alkali and alkaline-earth metals[J]. Chemistry of Materials, 2016, 28(21): 7898-7904.
68	GUO S, SUN Y, LIU P, et al. Cation-mixing stabilized layered oxide cathodes for sodium-ion batteries[J]. Science Bulletin, 2018, 63(6): 376-384.
69	ONG S P, CHEVRIER V L, HAUTIER G, et al. Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials[J]. Energy & Environmental Science, 2011, 4(9): 3680-3688.
70	YAN P, ZHENG J, GU M, et al. Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries[J]. Nature Communications, 2017, 8: 14101-14109.
71	KUMAKURA S, TAHARA Y, SATO S, et al. P'2-Na_2/3Mn_0.9Me_0.1O₂ (Me=Mg, Ti, Co, Ni, Cu, and Zn): Correlation between orthorhombic distortion and electrochemical property[J]. Chemistry of Materials, 2017, 29(21): 8958-8962.
72	WANG L, SHI J L, SU H, et al. Composite-structure material design for high-energy lithium storage[J]. Small, 2018, 14(34): doi: 10.1002/smll.201800887.
73	ZHOU Y N, WANG P F, NIU Y B, et al. A P2/P3 composite layered cathode for high-performance Na-ion full batteries[J]. Nano Energy, 2019, 55: 143-150.
74	SU H, YU H. Composite‐structure materials for Na‐ion batteries[J]. Small Methods, 2018, 3(4): 1800205-1800215.
75	SINGH G, TAPIA-RUIZ N, LOPEZ DEL AMO J M, et al. High voltage Mg-doped Na_0.67Ni_0.3-_xMg_xMn_0.7O₂ (x=0.05, 0.1) Na-ion cathodes with enhanced stability and rate capability[J]. Chemistry of Materials, 2016, 28(14): 5087-5094.
76	TAPIA-RUIZ N, DOSE W M, SHARMA N, et al. High voltage structural evolution and enhanced Na-ion diffusion in P2-Na_2/3Ni_1/3-_xMg_xMn_2/3O₂ (0≤x≤0.2) cathodes from diffraction, electrochemical and ab initio studies[J]. Energy & Environmental Science, 2018, 11(6): 1470-1479.
77	WANG Q C, MENG J K, YUE X Y, et al. Tuning P2-structured cathode material by Na-site Mg substitution for Na-ion batteries[J]. Journal of the American Chemical Society, 2019, 141(2): 840-848.
78	LIU X, ZUO W, ZHENG B, et al. P2-Na_0.67Al_xMn_1-_xO₂: Cost-effective, stable and high-rate sodium electrodes by suppressing phase transitions and enhancing sodium cation mobility[J]. Angewandte Chemie-International Edition, 2019, 58: 2-12.
79	WANG Y, WANG L, ZHU H, et al. Ultralow‐strain Zn‐substituted layered oxide cathode with suppressed P2-O2 transition for stable sodium ion storage[J]. Advanced Functional Materials, 2020: doi： 10.1002/adfm.201910327.
80	WANG Q, MARIYAPPAN S, VERGNET J, et al. Reaching the energy density limit of layered O3‐NaNi_0.5Mn_0.5O₂ electrodes via dual Cu And Ti substitution[J]. Advanced Energy Materials, 2019, 9(36): doi： 10.1002/aenm.201901785
81	DING F, ZHAO C, ZHOU D, et al. A novel Ni-rich O3-Na[Ni_0.60Fe_0.25Mn_0.15]O₂ cathode for Na-ion batteries[J]. Energy Storage Materials, 2020, 30: 420-430.
82	ZHAO C, YAO Z, WANG Q, et al. Revealing high Na-content P2-type layered oxides as advanced sodium-ion cathodes[J]. Journal of the American Chemical Society, 2020, 142(12): 5742-5750.
83	LI Y, YANG Z, XU S, et al. Air-stable copper-based P2-Na_7/9Cu_2/9Fe_1/9Mn_2/3O₂ as a new positive electrode material for sodium-ion batteries[J]. Advanced Science, 2015, 2(6): doi： 10.1002/adus.201500031.
84	MU L Q, XU S Y, LI Y M, et al. Prototype sodium-ion batteries using an air-stable and Co/Ni-free O3-layered metal oxide cathode[J]. Advanced Materials, 2015, 27(43): 6928-6933.
85	XIAO Y, ZHU Y F, YAO H R, et al. A stable layered oxide cathode material for high-performance sodium‐ion battery[J]. Advanced Energy Materials, 2019, 9(19): doi： 10.1002/aenm.201803978.
86	CHEN T, LIU W, LIU F, et al. Benefits of copper and magnesium cosubstitution in Na_0.5Mn_0.6Ni_0.4O₂ as a superior cathode for sodium ion batteries[J]. ACS Applied Energy Materials, 2019, 2(1): 844-851.
87	ZHAO C, DING F, LU Y, et al. High-entropy layered oxide cathodes for sodium-ion batteries[J]. Angewandte Chemie-International Edition, 2019, 58: 1-7.
88	CHEN X, ZHOU X, HU M, et al. Stable layered P3/P2 Na_0.66Co_0.5Mn_0.5O₂ cathode materials for sodium ion batteries[J]. Journal of Materials Chemistry A, 2015, 3: 20708-20714
89	XU G L, AMINE R, XU Y F, et al. Insights into the structural effects of layered cathode materials for high voltage sodium-ion batteries[J]. Energy & Environmental Science, 2017, 10(7): 1677-1693.
90	QI X, LIU L, SONG N, et al. Design and comparative study of O3/P2 hybrid structures for room temperature sodium-ion batteries[J]. ACS Applied Materials & Interfaces, 2017, 9(46): 40215-40223.

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[14]	周新宇, 栾道成, 胡志华, 凌俊华, 文科林, 刘浪, 阴志铭, 米书恒, 王正云. 含碳二元系相变储热材料储热性能分析选择[J]. 储能科学与技术, 2022, 11(4): 1175-1183.
[15]	刘倩楠, 胡伟平, 轷喆. 钠离子电池磷基负极材料研究进展[J]. 储能科学与技术, 2022, 11(4): 1201-1210.