储能科学与技术 ›› 2022, Vol. 11 ›› Issue (1): 38-44.doi: 10.19799/j.cnki.2095-4239.2021.0559

• 储能材料与器件 • 上一篇    下一篇

Nb2C MXene衍生Nb2O5多层纳米片的快速合成及其在锂离子电容器中的性能

王鑫1,2(), 胡培1, 周远明1, 徐进霞1, 蒋妍1()   

  1. 1.湖北工业大学理学院,湖北 武汉 430068
    2.中石化江钻石油机械有限公司,湖北 武汉 430000
  • 收稿日期:2021-10-25 修回日期:2021-10-27 出版日期:2022-01-05 发布日期:2022-01-10
  • 通讯作者: 蒋妍 E-mail:815212957@qq.com;yanjiang@hbut.edu.cn
  • 作者简介:王鑫(1994—),女,硕士,研究方向为新型能源材料及器件,E-mail:815212957@qq.com
  • 基金资助:
    国家自然科学基金项目(51602099)

Fast synthesis of Nb2O5 nanosheets derived from Nb2C MXene for lithium ion capacitors

Xin WANG1,2(), Pei HU1, Yuanming ZHOU1, Jinxia XU1, Yan JIANG1()   

  1. 1.School of Science, Hubei University of Technology, Wuhan 430068, Hubei, China
    2.Sinopec Jiang Drilling Petroleum Machinery Co. Ltd. , Wuhan 430000, Hubei, China
  • Received:2021-10-25 Revised:2021-10-27 Online:2022-01-05 Published:2022-01-10
  • Contact: Yan JIANG E-mail:815212957@qq.com;yanjiang@hbut.edu.cn

摘要:

近年来,随着电动汽车和储能领域的快速发展,锂离子电容器(LICs)因其高功率密度和相对较高的能量密度而备受关注。五氧化二铌(Nb2O5)因具有高容量和优异的倍率性能等特点,而成为最重要的负极材料之一。然而,目前报道的Nb2O5基负极材料的合成均需要复杂的制造工艺或做特殊处理。因此,本工作开发了一种通过氧化多层Nb2C MXene材料快速合成多层Nb2O5纳米片的方法。借助X射线衍射谱(XRD)、扫描电子显微镜技术(SEM)、比表面积分析、X射线光电子能谱(XPS)和电化学技术等测试表征手段,对所制得的多层Nb2O5纳米片进行了表征。在高温煅烧的初始阶段,前驱体由Nb2C MXene材料转变为正交Nb2O5(T-Nb2O5),并保留了MXene材料的多层纳米片微结构。随着烧结时间的增加,转变为由伪六方Nb2O5(TT-Nb2O5)纳米颗粒组成的纳米片结构。与TT-Nb2O5纳米颗粒相比,多层T-Nb2O5纳米片电极显示出更高的比容量和更优异的倍率特性。同时,T-Nb2O5电极在半电池和锂离子混合电容器中都表现出优秀的循环性能。多层T-Nb2O5材料更加优异的储锂性能可能源于其多片层结构、准二维锂离子扩散通道和快速赝电容响应能力三者的协同作用。

关键词: 能量存储与转化, 锂离子电容器, Nb2O5, 快速合成

Abstract:

In recent years, lithium ion capacitors (LICs) attract much attention due to their high power density and relatively high energy density with rapid development of electric vehicles and energy storage. Niobium pentoxide (Nb2O5) is one of the most important anode materials owning to its high capacity and superior rate capability. However, complicated fabrication process or special treatments are required in the synthesis of Nb2O5 based anode material. Herein, a fast synthesis of multilayer Nb2O5 nanosheets by oxidizing the multilayer Nb2C MXene material is developed. The multilayer Nb2O5 nanosheets are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), specific surface area analysis, X-ray photoelectron spectroscopy (XPS) and electrochemical analysis. Initially, the precursor transform into orthorhombic Nb2O5 (T-Nb2O5) which inherit the multilayer nanosheet microstructure. With prolonged sintering time, the orthorhombic phase turns into pseudohexagonal Nb2O5 (TT-Nb2O5) nanoparticles. Compared with TT-Nb2O5 nanoparticles, multilayer T-Nb2O5 nanosheet electrode shows higher specific capacity and better rate capability. The T-Nb2O5 electrode also shows excellent cycle performances both in half-cells and LICs. The excellent lithium storage performances of the multilayer T-Nb2O5 material may be due to the synergistic effect of its multi-layer microstructure, inherent quasi-2D Li-ion channel and rapid pseudocapacitive response.

Key words: energy storage and conversion, LICs, Nb2O5, fast synthesis

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